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Dergiler / Turkish Journal of Chemistry / 2014 / Cilt: 38 - Sayı: 3

Deposition and characterization of Cu9S5 nanocrystals from unsymmetrical [(Hex)(Me)NC(S)NC(O)C6H3(NO2)2-3,5]2Cu(II) and [(Et)(Bu)NC(S)NC(O)C6H4-4-NO2]2Cu(II) complexes by colloidal thermolysis method

Sohail SAEED
Rizwan HUSSAIN
Sayfa
413–422
Yayın Tarihi
2014-05-18
DOI
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The Cu9S5 nanocrystals were characterized by X-ray powder diffraction and transmission electron microscopy.

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Amaç & Hipotez:Cu9S5 nanocrystals were synthesized from unsymmetrical [(Hex)(Me)NC(S)NC(O)C6H3(NO2)2-3,5]2Cu(II) and [(Et)(Bu)NC(S)NC(O)C6H4-4-NO2]2 Cu(II) complexes by colloidal thermolysis in the presence of surfactant oleylamine.
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Temel Bulgular & Veri:The unsymmetrical copper complexes were synthesized by the reaction of copper(II) acetate with N-[hexyl(methyl)carbamothioyl]-3,5-dinitrobenzamide and N-[ethyl(butyl)carbamothioyl]-4-nitrobenzamide.
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Sonuç & Katkı:The Cu9S5 nanocrystals were characterized by X-ray powder diffraction and transmission electron microscopy.
🔬Tür:Araştırma Makalesi
📍Kapsam:Genişletilmiş Akademik Örneklem
⚙️Değişkenler:Cu9S5 nanocrystals · p-XRD · crystallites

Özet

Cu9S5 nanocrystals were synthesized from unsymmetrical [(Hex)(Me)NC(S)NC(O)C6H3(NO2)2-3,5]2Cu(II) and [(Et)(Bu)NC(S)NC(O)C6H4-4-NO2]2 Cu(II) complexes by colloidal thermolysis in the presence of surfactant oleylamine. The unsymmetrical copper complexes were synthesized by the reaction of copper(II) acetate with N-[hexyl(methyl)carbamothioyl]-3,5-dinitrobenzamide and N-[ethyl(butyl)carbamothioyl]-4-nitrobenzamide. The complexes were used as single-source precursors for the preparation of Cu9S5 nanocrsytals. The Cu9S5 nanocrystals were characterized by X-ray powder diffraction and transmission electron microscopy.

Abstract

Cu9S5 nanocrystals were synthesized from unsymmetrical [(Hex)(Me)NC(S)NC(O)C6H3(NO2)2-3,5]2Cu(II) and [(Et)(Bu)NC(S)NC(O)C6H4-4-NO2]2 Cu(II) complexes by colloidal thermolysis in the presence of surfactant oleylamine. The unsymmetrical copper complexes were synthesized by the reaction of copper(II) acetate with N-[hexyl(methyl)carbamothioyl]-3,5-dinitrobenzamide and N-[ethyl(butyl)carbamothioyl]-4-nitrobenzamide. The complexes were used as single-source precursors for the preparation of Cu9S5 nanocrsytals. The Cu9S5 nanocrystals were characterized by X-ray powder diffraction and transmission electron microscopy.

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Bu Makaleye Atıf Yap

SAEED, S., HUSSAIN, R. (2014). Deposition and characterization of Cu9S5 nanocrystals from unsymmetrical [(Hex)(Me)NC(S)NC(O)C6H3(NO2)2-3,5]2Cu(II) and [(Et)(Bu)NC(S)NC(O)C6H4-4-NO2]2Cu(II) complexes by colloidal thermolysis method. Turkish Journal of Chemistry, Cilt: 38 - Sayı: 3, 413–422. https://ajindex.com/articles/185403

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