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Journals / Turkish Journal of Chemistry / 2014 / Cilt: 38 - Sayı: 3

Deposition and characterization of Cu9S5 nanocrystals from unsymmetrical [(Hex)(Me)NC(S)NC(O)C6H3(NO2)2-3,5]2Cu(II) and [(Et)(Bu)NC(S)NC(O)C6H4-4-NO2]2Cu(II) complexes by colloidal thermolysis method

Sohail SAEED
Rizwan HUSSAIN
Pages
413–422
Publication Date
2014-05-18
DOI
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AI Summary & Key Takeaways

AI Insight
⚡ TL;DR(Too Long; Didn't Read)

The Cu9S5 nanocrystals were characterized by X-ray powder diffraction and transmission electron microscopy.

📌 3 Key Takeaways

🎯
Objective & Hypothesis:Cu9S5 nanocrystals were synthesized from unsymmetrical [(Hex)(Me)NC(S)NC(O)C6H3(NO2)2-3,5]2Cu(II) and [(Et)(Bu)NC(S)NC(O)C6H4-4-NO2]2 Cu(II) complexes by colloidal thermolysis in the presence of surfactant oleylamine.
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Key Findings & Data:The unsymmetrical copper complexes were synthesized by the reaction of copper(II) acetate with N-[hexyl(methyl)carbamothioyl]-3,5-dinitrobenzamide and N-[ethyl(butyl)carbamothioyl]-4-nitrobenzamide.
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Conclusion & Impact:The Cu9S5 nanocrystals were characterized by X-ray powder diffraction and transmission electron microscopy.
🔬Design:Research Article
📍Scope:Comprehensive Sample
⚙️Variables:Cu9S5 nanocrystals · p-XRD · crystallites

Abstract

Cu9S5 nanocrystals were synthesized from unsymmetrical [(Hex)(Me)NC(S)NC(O)C6H3(NO2)2-3,5]2Cu(II) and [(Et)(Bu)NC(S)NC(O)C6H4-4-NO2]2 Cu(II) complexes by colloidal thermolysis in the presence of surfactant oleylamine. The unsymmetrical copper complexes were synthesized by the reaction of copper(II) acetate with N-[hexyl(methyl)carbamothioyl]-3,5-dinitrobenzamide and N-[ethyl(butyl)carbamothioyl]-4-nitrobenzamide. The complexes were used as single-source precursors for the preparation of Cu9S5 nanocrsytals. The Cu9S5 nanocrystals were characterized by X-ray powder diffraction and transmission electron microscopy.

Özet

Cu9S5 nanocrystals were synthesized from unsymmetrical [(Hex)(Me)NC(S)NC(O)C6H3(NO2)2-3,5]2Cu(II) and [(Et)(Bu)NC(S)NC(O)C6H4-4-NO2]2 Cu(II) complexes by colloidal thermolysis in the presence of surfactant oleylamine. The unsymmetrical copper complexes were synthesized by the reaction of copper(II) acetate with N-[hexyl(methyl)carbamothioyl]-3,5-dinitrobenzamide and N-[ethyl(butyl)carbamothioyl]-4-nitrobenzamide. The complexes were used as single-source precursors for the preparation of Cu9S5 nanocrsytals. The Cu9S5 nanocrystals were characterized by X-ray powder diffraction and transmission electron microscopy.

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Cite This Article

SAEED, S., HUSSAIN, R. (2014). Deposition and characterization of Cu9S5 nanocrystals from unsymmetrical [(Hex)(Me)NC(S)NC(O)C6H3(NO2)2-3,5]2Cu(II) and [(Et)(Bu)NC(S)NC(O)C6H4-4-NO2]2Cu(II) complexes by colloidal thermolysis method. Turkish Journal of Chemistry, Cilt: 38 - Sayı: 3, 413–422. https://ajindex.com/articles/185403

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References (30)

  1. Monajjemi, M.; Baei, M. T.; Mollaamin, F. Russian J. Inorg. Chem. 2008, 53, 1430–1437.
  2. Monajjemi, M.; Mahdavian, L.; Mollaamin, F.; Khaleghian, M. Russian J. Inorg. Chem. 2009, 54, 1465–1473.
  3. Zare, K.; Daroule, M.; Mollaamin, F.; Monajjemi, M. Int. J. Phys. Sci. 2011, 6, 2536–2540.
  4. Sun, Y. G.; Xia, Y. N. Science 2002, 298, 2176–2179.
  5. Lee, H.; Yoon, S. W.; Kim, E. J.; Park, J. Nano Lett. 2007, 7, 778–784.
  6. Wu, Y.; Wadia, C.; Ma, W.; Sadtler, B.; Alivisatos, A. P. Nano Lett. 2008, 8, 2551–2555.
  7. Wadia, C.; Alivisatos, A. P.; Kammen, D. M. Environ. Sci. Technol. 2009, 43, 2072–2077.
  8. Sakamoto, T.; Sunamura, H.; Kawaura, H. Appl. Phys. Lett. 2003, 82, 3032–3034.
  9. Chung, J. S.; Sohn, H. J. J. Power Sources 2002, 108, 226–231.
  10. Vaughan, D. J.; Craig, J. R. Mineral Chemistry of Metal Sulfides, ed. W. B. Harland, S. O. Agrell, A. H. Cook and N. F. Hughes, Cambridge University Press,
  11. Cambridge, UK, 1978, pp. 290–292.
  12. Fleet, M. E. Rev. Mineral. Geochem. 2006, 61, 365–420.
  13. Koch, D. F. A.; McIntyre, R. J. Electroanal. Chem. 1976, 71, 285–296.
  14. He, Y. B.; Polity, A.; Osterreicher, I.; Pfisterer, D.; Gregor, R.; Meyer, B. K.; Hardt, M. Phys. B, 2001, 308–310, 1069–1073.
  15. Wang, S. Y.; Wang, W.; Lu, Z. H. Mater. Sci. Eng. B 2003, 103, 184–188.
  16. Sartale, S. D.; Lokhande, C. D. Mater. Chem. Phys. 2000, 65, 63–67.
  17. Hu, H.; Nair, P. K. Surf. Coat. Technol. 1996, 81, 183–189.
  18. Kemmler, K.; Lazell, M.; O’Brien, P.; Otway, D. J.; Park, J. H.; Walsh, J. R. J. Mater. Sci.: Mater. Electron. 2002, 13, 531–535.
  19. Moloto, M. J.; Revaprasadu, N.; O’Brien, P.; Malik, M. A. J. Mater. Sci. Mater. Electron. 2004, 15, 313–316.
  20. Arslan, H.; Fl¨ orke, U.; Kulcu, N.; Emen, M. F. J. Coord. Chem. 2006, 59, 223–228.
  21. Binzet, G.; Arslan, H.; Fl¨ orke, U.; Kulcu, N.; Duran, N. J. Coord. Chem. 2006, 59, 1395–1406.
  22. Bailey, R. A.; Peterson, T. R. Can. J. Chem. 1967, 45, 1135–1142.
  23. Saeed, S.; Rashid, N.; Jones, P. G.; Ali, M.; Hussain, R. Eur. J. Med. Chem. 2010, 45, 1323–1331.
  24. Saeed, S.; Rashid, N.; Jones, P. G.; Hussain, R.; Bhatti, M. H. Cent. Eur. J. Chem. 2010, 8, 550–558.
  25. Saeed, S.; Rashid, N.; Jones, P. G.; Tahir, A. J. Heterocyclic. Chem. 2011, 48, 74–82.
  26. Saeed, S.; Rashid, N.; Hussain, R.; Jones, P. G. Eur. J. Chem. 2011, 2, 77–82.
  27. Saeed, S.; Wong, W.-T. J. Heterocyclic. Chem. 2012, 49, 580–584.
  28. Saeed, S.; Rashid, N.; Bhatti, M. H.; Jones, P. G. Turk. J. Chem. 2010, 34, 761–770.
  29. Saeed, S.; Rashid, N.; Ali, M.; Hussain, R.; Jones, P. G. Eur. J. Chem. 2010, 1, 221–227.
  30. Saeed, S.; Rashid, N.; Ali, M.; Hussain,