Dergiler / Turkish Journal of Chemistry / 2009 / Cilt: 33 - Sayı: 5

Antioxidant galloylated flavonoids from Geranium tuberosum L. subsp. tuberosum

Sayfa
685–692
Yayın Tarihi
2009-05-01
DOI
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⚡ TL;DR(1 Cümlede Hızlı Çıkarım)

All the compounds tested showed antioxidant activity.

📌 3 Maddede Bu Makale

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Amaç & Hipotez:Phytochemical investigations on the most active EtOAc extract led to the isolation of 9 flavonoids [quercetin (1), quercetin 3-O-b-glucopyranoside (2), quercetin 3-O-b-galactopyranoside (3), quercetin 3-O-(2''-O-galloyl)-b-glucopyranoside (4), quercetin 3-O-(2''-O-galloyl)-b-galactopyranoside (5), quercetin 3-O-(6''-O-galloyl)-b-glucopyranoside (6), quercetin 3-O-(6''-O-galloyl)-b-galactopyranoside (7), quercetin-3-O-a -arabinofuranoside (8), and quercetin-3-O-a-rhamnopyranosyl-(1\to 6)-b-glucopyranoside (9)] and a simple phenolic compound (methyl gallate) (10).
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Temel Bulgular & Veri:The structures of the compounds were elucidated by 1- and 2-dimensional NMR techniques (1H, 13C, COSY, HMBC, and HMQC) and ESI-TOF-MS spectrometry.
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Sonuç & Katkı:All the compounds tested showed antioxidant activity.
🔬Tür:Araştırma Makalesi
📍Kapsam:Genişletilmiş Akademik Örneklem
⚙️Değişkenler:G. tuberosum L. subsp. tuberosum · flavonol gallate · flavonoids

Özet

Phytochemical investigations on the most active EtOAc extract led to the isolation of 9 flavonoids [quercetin (1), quercetin 3-O-b-glucopyranoside (2), quercetin 3-O-b-galactopyranoside (3), quercetin 3-O-(2''-O-galloyl)-b-glucopyranoside (4), quercetin 3-O-(2''-O-galloyl)-b-galactopyranoside (5), quercetin 3-O-(6''-O-galloyl)-b-glucopyranoside (6), quercetin 3-O-(6''-O-galloyl)-b-galactopyranoside (7), quercetin-3-O-a -arabinofuranoside (8), and quercetin-3-O-a-rhamnopyranosyl-(1\to 6)-b-glucopyranoside (9)] and a simple phenolic compound (methyl gallate) (10). The structures of the compounds were elucidated by 1- and 2-dimensional NMR techniques (1H, 13C, COSY, HMBC, and HMQC) and ESI-TOF-MS spectrometry. H2O2-induced lipid peroxidation inhibitor effects in human red blood cells of different extracts of G. tuberosum L. subsp. tuberosum aerial parts were also investigated. All the compounds tested showed antioxidant activity.

Abstract

Phytochemical investigations on the most active EtOAc extract led to the isolation of 9 flavonoids [quercetin (1), quercetin 3-O-b-glucopyranoside (2), quercetin 3-O-b-galactopyranoside (3), quercetin 3-O-(2''-O-galloyl)-b-glucopyranoside (4), quercetin 3-O-(2''-O-galloyl)-b-galactopyranoside (5), quercetin 3-O-(6''-O-galloyl)-b-glucopyranoside (6), quercetin 3-O-(6''-O-galloyl)-b-galactopyranoside (7), quercetin-3-O-a -arabinofuranoside (8), and quercetin-3-O-a-rhamnopyranosyl-(1\to 6)-b-glucopyranoside (9)] and a simple phenolic compound (methyl gallate) (10). The structures of the compounds were elucidated by 1- and 2-dimensional NMR techniques (1H, 13C, COSY, HMBC, and HMQC) and ESI-TOF-MS spectrometry. H2O2-induced lipid peroxidation inhibitor effects in human red blood cells of different extracts of G. tuberosum L. subsp. tuberosum aerial parts were also investigated. All the compounds tested showed antioxidant activity.

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Bu Makaleye Atıf Yap

ŞÖHRETOĞLU, D., SAKAR, M. K., SABUNCUOĞLU, S. A., ÖZGÜNEŞ, H., STERNER, O. (2009). Antioxidant galloylated flavonoids from Geranium tuberosum L. subsp. tuberosum. Turkish Journal of Chemistry, Cilt: 33 - Sayı: 5, 685–692. https://ajindex.com/articles/185098

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