Journals / Turkish Journal of Chemistry / 2009 / Cilt: 33 - Sayı: 5

Antioxidant galloylated flavonoids from Geranium tuberosum L. subsp. tuberosum

Pages
685–692
Publication Date
2009-05-01
DOI
—
🏛️Bibliographic metadata and full text access for this article are provided via DergiPark.
DergiPark Record ↗
✨

AI Summary & Key Takeaways

AI Insight
⚡ TL;DR(Too Long; Didn't Read)

All the compounds tested showed antioxidant activity.

📌 3 Key Takeaways

🎯
Objective & Hypothesis:Phytochemical investigations on the most active EtOAc extract led to the isolation of 9 flavonoids [quercetin (1), quercetin 3-O-b-glucopyranoside (2), quercetin 3-O-b-galactopyranoside (3), quercetin 3-O-(2''-O-galloyl)-b-glucopyranoside (4), quercetin 3-O-(2''-O-galloyl)-b-galactopyranoside (5), quercetin 3-O-(6''-O-galloyl)-b-glucopyranoside (6), quercetin 3-O-(6''-O-galloyl)-b-galactopyranoside (7), quercetin-3-O-a -arabinofuranoside (8), and quercetin-3-O-a-rhamnopyranosyl-(1\to 6)-b-glucopyranoside (9)] and a simple phenolic compound (methyl gallate) (10).
📊
Key Findings & Data:The structures of the compounds were elucidated by 1- and 2-dimensional NMR techniques (1H, 13C, COSY, HMBC, and HMQC) and ESI-TOF-MS spectrometry.
💡
Conclusion & Impact:All the compounds tested showed antioxidant activity.
🔬Design:Research Article
📍Scope:Comprehensive Sample
⚙️Variables:G. tuberosum L. subsp. tuberosum · flavonol gallate · flavonoids

Abstract

Phytochemical investigations on the most active EtOAc extract led to the isolation of 9 flavonoids [quercetin (1), quercetin 3-O-b-glucopyranoside (2), quercetin 3-O-b-galactopyranoside (3), quercetin 3-O-(2''-O-galloyl)-b-glucopyranoside (4), quercetin 3-O-(2''-O-galloyl)-b-galactopyranoside (5), quercetin 3-O-(6''-O-galloyl)-b-glucopyranoside (6), quercetin 3-O-(6''-O-galloyl)-b-galactopyranoside (7), quercetin-3-O-a -arabinofuranoside (8), and quercetin-3-O-a-rhamnopyranosyl-(1\to 6)-b-glucopyranoside (9)] and a simple phenolic compound (methyl gallate) (10). The structures of the compounds were elucidated by 1- and 2-dimensional NMR techniques (1H, 13C, COSY, HMBC, and HMQC) and ESI-TOF-MS spectrometry. H2O2-induced lipid peroxidation inhibitor effects in human red blood cells of different extracts of G. tuberosum L. subsp. tuberosum aerial parts were also investigated. All the compounds tested showed antioxidant activity.

Özet

Phytochemical investigations on the most active EtOAc extract led to the isolation of 9 flavonoids [quercetin (1), quercetin 3-O-b-glucopyranoside (2), quercetin 3-O-b-galactopyranoside (3), quercetin 3-O-(2''-O-galloyl)-b-glucopyranoside (4), quercetin 3-O-(2''-O-galloyl)-b-galactopyranoside (5), quercetin 3-O-(6''-O-galloyl)-b-glucopyranoside (6), quercetin 3-O-(6''-O-galloyl)-b-galactopyranoside (7), quercetin-3-O-a -arabinofuranoside (8), and quercetin-3-O-a-rhamnopyranosyl-(1\to 6)-b-glucopyranoside (9)] and a simple phenolic compound (methyl gallate) (10). The structures of the compounds were elucidated by 1- and 2-dimensional NMR techniques (1H, 13C, COSY, HMBC, and HMQC) and ESI-TOF-MS spectrometry. H2O2-induced lipid peroxidation inhibitor effects in human red blood cells of different extracts of G. tuberosum L. subsp. tuberosum aerial parts were also investigated. All the compounds tested showed antioxidant activity.

🔖

Cite This Article

ŞÖHRETOĞLU, D., SAKAR, M. K., SABUNCUOĞLU, S. A., ÖZGÜNEŞ, H., STERNER, O. (2009). Antioxidant galloylated flavonoids from Geranium tuberosum L. subsp. tuberosum. Turkish Journal of Chemistry, Cilt: 33 - Sayı: 5, 685–692. https://ajindex.com/articles/185098

📄 Full Text PDF Viewer

📄

PDF görüntüleyici hazırlanıyor...