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Journals / Turkish Journal of Analytical Chemistry / 2023 / Cilt: 5 Sayı: 1

Electroanalytical characterization of chloroquinoline substituted redox-active phthalocyanines

Asiye NAS
Gülsev DİLBER
Zekeriya BIYIKLIOĞLU
Pages
25–31
Publication Date
2023-06-30
DOI
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AI Summary & Key Takeaways

AI Insight
⚡ TL;DR(Too Long; Didn't Read)

All in all, this study's results inevitably create a useful way to use them in possible future studies, which will particularly attempt to use the compound investigated in potential areas of use.

📌 3 Key Takeaways

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Objective & Hypothesis:In the first part of this study, the synthesis and characterization of organosoluble 5-chloroquinolin-8-yloxy substituted iron(II) (2) and oxo-titanium (IV) phthalocyanines (3) are reported for the first time.
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Key Findings & Data:These compounds have been characterized by elemental analysis, Fourier transform infrared, electronic spectroscopy, and mass spectra.
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Conclusion & Impact:All in all, this study's results inevitably create a useful way to use them in possible future studies, which will particularly attempt to use the compound investigated in potential areas of use.
🔬Design:Research Article
📍Scope:Comprehensive Sample
⚙️Variables:Iron · Titanium · Electrochemistry

Abstract

In the first part of this study, the synthesis and characterization of organosoluble 5-chloroquinolin-8-yloxy substituted iron(II) (2) and oxo-titanium (IV) phthalocyanines (3) are reported for the first time. These compounds have been characterized by elemental analysis, Fourier transform infrared, electronic spectroscopy, and mass spectra. Electrochemical behaviors of metal-free and cobalt phthalocyanines and further new types of iron and oxo-titanium phthalocyanines were investigated using electroanalytical methods, such as cyclic (CV) and square wave voltammetry (SWV). According to the electrochemical results, phthalocyanines by and large showed one-electron metal- and/or ligand-based reversible or quasi-reversible reduction and oxidation processes. All in all, this study's results inevitably create a useful way to use them in possible future studies, which will particularly attempt to use the compound investigated in potential areas of use.

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Cite This Article

NAS, A., DİLBER, G., BIYIKLIOĞLU, Z. (2023). Electroanalytical characterization of chloroquinoline substituted redox-active phthalocyanines. Turkish Journal of Analytical Chemistry, Cilt: 5 Sayı: 1, 25–31. https://ajindex.com/articles/946933

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References (9)

  1. A. Suzuki, H. Okumura, Y. Yamasaki, T. Oku, Fabrication and characterization of perovskite type solar cells using phthalocyanine complexes, Appl Surf Sci, 488, 2019, 586-596 (https://doi.org/10.1016/j.apsusc.2019.05.305)
  2. J. Xu, W. Yang, R. Chen, The photovoltaic performance of highly asymmetric phthalocyanine-sensitized brookite-based solar cells, Optik, 200, 2020, 163413. (https://doi.org/10.1016/j.ijleo.2019.163413)
  3. B. Yıldız, E. Güzel, D. Akyüz, B.S. Arslan, A. Koca, M.K. Şener, Unsymmetrically pyrazole-3-carboxylic acid substituted phthalocyanine-based photoanodes for use in water splitting photoelectrochemical and dye-sensitized solar cells, Sol Energy, 191, 2019, 654-662. (https://doi.org/10.1016/j.solener.2019.09.043)
  4. S. Kong, X. Wang, L. Bai, Y. Song, F. Meng, Multi-arm ionic liquid crystals formed by pyridine-mesophase and copper phthalocyanine, J Mol Liq, 288, 2019, 111012. (https://doi.org/10.1016/j.molliq.2019.111012) J.A. Jiménez-Tejada, A. Romero, J. González, N.B. Chaure, A.N. Cammidge, I. Chambrier, A.K. Ray, M.J. Deen, Evolutionary Computation for Parameter Extraction of Organic Thin-Film Transistors Using Newly Synthesized Liquid Crystalline Nickel Phthalocyanine, Micromachines, 10, 2019, 683. ( https://doi.org/10.3390/mi10100683)
  5. E.M. Bauer, T. De Caro, P. Tagliatesta, M. Carbone, Unraveling The Real pigment composition of tattoo inks: the case of bi-components phthalocyanine based greens, Dyes Pigments, 167, 2019, 225-235. ( http://dx.doi.org/10.1016/j.dyepig.2019.04.018)
  6. Y. Zhao, J. W. Ying, Q. Sun, M. R. Ke, B. Y. Zheng, J. D. Huang, A novel silicon(IV) phthalocyanine-oligopeptide conjugate as a highly efficient photosensitizer for photodynamic antimicrobial therapy, Dyes Pigments, 172, 2020, 107834. (https://doi.org/10.1016/j.dyepig.2019.107834)
  7. Q. Li, Z. Sun, Q. Liang, M. Zhou, D. Sun, Novel tetrasubstituted zinc phthalocyanine-attapulgite composites for efficient catalytic oxidation of styrene with tert-butyl hydroperoxide as oxidant, Solid State Sci, 97, 2019, 106010. (https://doi.org/10.1016/j.solidstatesciences.2019.106010)
  8. R. Bahluli, S. Keshipour, Microcrystalline cellulose modified with Fe(II)- and Ni(II)-phthalocyanines: Syntheses, characterizations, and catalytic applications, Polyhedron, 169, 2019, 176-182. ( https://doi.org/10.1016/j.poly.2019.05.010)
  9. H.S. Majumdar, A. Bandyopadhyay, A.J. Pal, Data-storage devices based on layer-by-layer self-assembled films of a phthalocyanine derivative, Org Electron, 4, 2003, 39. (http