SavedAdd your journal

Journals / Turkish Journal of Chemistry / 2016 / Cilt: 40 - Sayı: 5

Newly synthesized furanoside-based NHC ligands for the arylation of aldehydes

Fatma ÇETİN TELLİ
Selin YILDIRAN
Serpil DENİZALTI
Pages
689–697
Publication Date
2022-11-05
DOI
—
🏛️Bibliographic metadata and full text access for this article are provided via DergiPark.
DergiPark Record ↗
✨

AI Summary & Key Takeaways

AI Insight
⚡ TL;DR(Too Long; Didn't Read)

The newly synthesized compounds were very efficient in terms of yield;nevertheless they did not exhibit a chiral induction.

📌 3 Key Takeaways

🎯
Objective & Hypothesis:New furanoside-based NHC precursor salts (2) were synthesized using amino alcohols from the chloralosederivatives of glucose (a), galactose (b), and mannose (c).
📊
Key Findings & Data:The novel compounds were fully characterized by1H NMR,13C NMR, and elemental analyses.
💡
Conclusion & Impact:The newly synthesized compounds were very efficient in terms of yield;nevertheless they did not exhibit a chiral induction.
🔬Design:Research Article
📍Scope:Comprehensive Sample
⚙️Variables:Domain Parameters

Abstract

New furanoside-based NHC precursor salts (2) were synthesized using amino alcohols from the chloralosederivatives of glucose (a), galactose (b), and mannose (c). The novel compounds were fully characterized by1H NMR,13C NMR, and elemental analyses. The catalytic activities of these salts were tested in the arylation of aldehydes ascatalysts that were generated in situ from [RhCl(COD)]2. In addition,2awas converted to the rhodium complex3ainorder to compare the results obtained in situ. The newly synthesized compounds were very efficient in terms of yield;nevertheless they did not exhibit a chiral induction.

🔖

Cite This Article

TELLİ, F. Ç., YILDIRAN, S., DENİZALTI, S. (2022). Newly synthesized furanoside-based NHC ligands for the arylation of aldehydes. Turkish Journal of Chemistry, Cilt: 40 - Sayı: 5, 689–697. https://ajindex.com/articles/601975

📄 Full Text PDF Viewer

📄

PDF görüntüleyici hazırlanıyor...

References (1)

  1. Meguro, K.; Aizawa, M.; Sohda, T.; Kawamatsu, Y.; Nagaoka, A.Chem. Pharm. Bull.1985,33, 3787-3797. 2.Tada, F.; Tanaka, K.; Koshiro, K.Tetrahedron: Asymmetry1991,2, 873-874. 3.Bolm, C.; Hildebrand, J. P.; Mu~niz, K.; Hermanns, N.Angew. Chem. Int. Ed.2001,40, 3284-3308. 4.Fagnou, K.; Lautens, M.Chem. Rev.2003,103, 169-196. 5.Noyori, R.; Kitamura, M.Angew. Chem. Int. Ed.1991,30, 49-69. 6.Soai, K.; Niwa, S.Chem. Rev.1992,92, 833-856. 7.Weber, B.; Seebach, D.Tetrahedron1994,50, 7473-7484. 8.Zhang, W.; Qin, Y.; Zhang, S.; Luo, M.Arkivoc2005, 39-48. 9.Chen, J.; Zhang, X.; Feng, Q.; Luo, M.J. Organomet. Chem.2006,691, 470-474. 10.Zheng, H.; Zhang, Q.; Chen, J.; Liu, M.; Cheng, S.; Ding, J.; Wu, H.; Su, W.J. Org. Chem.2009,74, 943-945. 11.Furstner, A.; Krause, H.Adv. Synth. Catal.2001, 343-350. 12.Yigit, M.;Ozdemir,_I.; Cetinkaya, E.; Cetinkaya, B.Heteroatom Chem.2005,6, 461-465. 13.Ozdemir,_I.; Gurbuz, N.; Gok, Y.Trans. Metal. Chem.2005,30, 367-371. 14.Gois, P. M. P.; Trindade, A. F.; Veiros, L. F.; Andre, V.; Duarte, M. T.; Afonso, C. A. M.; Caddick, S.; Cloke, F.G. N.Angew. Chem. Int. Ed.2007,46, 5750-5753. 15.Turkmen, H.; Denizalt, S.;Ozdemir,_I.; Cetinkaya, E.; Cetinkaya, B.J. Organomet. Chem.2008,693, 425-434. 16.He, Y.; Cai, C.Chem. Commun.2011,47, 12319-12321. 17.Busetto, L.; Cassani, M. C.; Femoni, C.; Mancinelli, M.; Mazzanti, A.; Mazzoni, R.; Solinas, G.Organometallics2011,30, 5258-5272. 18.Wang, D.; Ma, Y.; He, F.; Duan, W.; Zhao, L.; Song, C.Synth. Commun.2013,43, 810-825. 19.Denizalt, S.; Turkmen, H.; Cetinkaya, B.Tetrahedron Lett.2014,55, 4129-4132. 20.Dez-Gonzalez, S.; Marion, N.; Nolan, S. P.Chem. Rev.2009,109, 3612-3676. 21.Hahn, F. E.; Jahnke, M. C.Angew. Chem. Int. Ed.2008,47, 3122-3172. 22.Denizalt, S.; Turkmen, H.; Cetinkaya, B.Turk. J. Chem.2014,38, 679-685. 23.Gurbuz, N.; Karaca, E.O.;Ozdemir,_I.; Cetinkaya, B.Turk. J. Chem.2015,39, 1115-1157. 24.Herrmann, W. A.Angew. Chem. Int. Ed.2002,41, 1290-1309. 25.Gunay, M. E.; Cogasloglu, G. G.; Frnc, R.Turk. J. Chem.2015,39, 1310-1316. 26.Shi, J. C.; Lei, N.; Tong, Q.; Peng, Y.; Wei, J.; Jia, L.Eur. J. Inorg. Chem.2007, 2221-2224. 27.Nishioka, T.; Shibata, T.; Kinoshita, I.Organometallics2007,26, 1126-1128. 28.Fremont, P.; Stevens, E. D.; Eelman, M. D.; Fogg, D. E.; Nolan, S. P.Organometallics2006,25, 5824-5828. 29.Shibata, T.; Ito, S.; Doe, M.; Tanaka, R.; Hashimoto, H.; Kinoshita, I.; Yanod, S.; Nishioka, T.Dalton Trans.2011,40, 6778-6784. 30.Shibata, T.; H