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Dergiler / Turkish Journal of Chemistry / 2016 / Cilt: 40 - Sayı: 5

Newly synthesized furanoside-based NHC ligands for the arylation of aldehydes

Fatma ÇETİN TELLİ
Selin YILDIRAN
Serpil DENİZALTI
Sayfa
689–697
Yayın Tarihi
2022-11-05
DOI
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The newly synthesized compounds were very efficient in terms of yield;nevertheless they did not exhibit a chiral induction.

📌 3 Maddede Bu Makale

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Amaç & Hipotez:New furanoside-based NHC precursor salts (2) were synthesized using amino alcohols from the chloralosederivatives of glucose (a), galactose (b), and mannose (c).
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Temel Bulgular & Veri:The novel compounds were fully characterized by1H NMR,13C NMR, and elemental analyses.
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Sonuç & Katkı:The newly synthesized compounds were very efficient in terms of yield;nevertheless they did not exhibit a chiral induction.
🔬Tür:Araştırma Makalesi
📍Kapsam:Genişletilmiş Akademik Örneklem
⚙️Değişkenler:Alan Parametreleri

Abstract

New furanoside-based NHC precursor salts (2) were synthesized using amino alcohols from the chloralosederivatives of glucose (a), galactose (b), and mannose (c). The novel compounds were fully characterized by1H NMR,13C NMR, and elemental analyses. The catalytic activities of these salts were tested in the arylation of aldehydes ascatalysts that were generated in situ from [RhCl(COD)]2. In addition,2awas converted to the rhodium complex3ainorder to compare the results obtained in situ. The newly synthesized compounds were very efficient in terms of yield;nevertheless they did not exhibit a chiral induction.

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Bu Makaleye Atıf Yap

TELLİ, F. Ç., YILDIRAN, S., DENİZALTI, S. (2022). Newly synthesized furanoside-based NHC ligands for the arylation of aldehydes. Turkish Journal of Chemistry, Cilt: 40 - Sayı: 5, 689–697. https://ajindex.com/articles/601975

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