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Journals / Hacettepe Journal of Biology and Chemistry / 2007 / Cilt: 35 - Sayı: 2

Synthesis of vic-Dioxime Derivatives with Semicarbazone Side Groups and Their Ni II Complexes

İlknur BABAHAN
Hüseyin ANIL
Nursabah SARIKAVAKLI
Pages
117–121
Publication Date
2007-04-01
DOI
—
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AI Summary & Key Takeaways

AI Insight
⚡ TL;DR(Too Long; Didn't Read)

Structural assignments are supported by a combination of1H-NMR,13C-NMR, HMQC, FT-IR, UV,elemental analyses and magnetic susceptibility

📌 3 Key Takeaways

🎯
Objective & Hypothesis:In this work, two novel vic-dioxime L1H2, L2H2 compounds bearing semicarbazone side groups and their Ni II complexes were synthesized.
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Key Findings & Data:The vic-dioxime ligands of bearing semicarbazone side groups were synthesized by reactinganti-chloroglyoxime with semicarbazidehydrochloride, 4-aminoacetophenenone semicarbazone, respectively.
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Conclusion & Impact:Structural assignments are supported by a combination of1H-NMR,13C-NMR, HMQC, FT-IR, UV,elemental analyses and magnetic susceptibility
🔬Design:Research Article
📍Scope:Comprehensive Sample
⚙️Variables:vic-Dioximes · Semicarbazones · Transition metal complexes

Abstract

In this work, two novel vic-dioxime L1H2, L2H2 compounds bearing semicarbazone side groups and their Ni II complexes were synthesized. The vic-dioxime ligands of bearing semicarbazone side groups were synthesized by reactinganti-chloroglyoxime with semicarbazidehydrochloride, 4-aminoacetophenenone semicarbazone, respectively. Ligands form mononuclear complexes [Ni LH 2] with a metal:ligand ratio of 1:2. The Ni II complexes are proposed tobe square planar. Structural assignments are supported by a combination of1H-NMR,13C-NMR, HMQC, FT-IR, UV,elemental analyses and magnetic susceptibility

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Cite This Article

BABAHAN, İ., ANIL, H., SARIKAVAKLI, N. (2007). Synthesis of vic-Dioxime Derivatives with Semicarbazone Side Groups and Their Ni II Complexes. Hacettepe Journal of Biology and Chemistry, Cilt: 35 - Sayı: 2, 117–121. https://ajindex.com/articles/256278

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