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Dergiler / Hacettepe Journal of Biology and Chemistry / 2007 / Cilt: 35 - Sayı: 2

Synthesis of vic-Dioxime Derivatives with Semicarbazone Side Groups and Their Ni II Complexes

İlknur BABAHAN
Hüseyin ANIL
Nursabah SARIKAVAKLI
Sayfa
117–121
Yayın Tarihi
2007-04-01
DOI
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Structural assignments are supported by a combination of1H-NMR,13C-NMR, HMQC, FT-IR, UV,elemental analyses and magnetic susceptibility

📌 3 Maddede Bu Makale

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Amaç & Hipotez:In this work, two novel vic-dioxime L1H2, L2H2 compounds bearing semicarbazone side groups and their Ni II complexes were synthesized.
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Temel Bulgular & Veri:The vic-dioxime ligands of bearing semicarbazone side groups were synthesized by reactinganti-chloroglyoxime with semicarbazidehydrochloride, 4-aminoacetophenenone semicarbazone, respectively.
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Sonuç & Katkı:Structural assignments are supported by a combination of1H-NMR,13C-NMR, HMQC, FT-IR, UV,elemental analyses and magnetic susceptibility
🔬Tür:Araştırma Makalesi
📍Kapsam:Genişletilmiş Akademik Örneklem
⚙️Değişkenler:vic-Dioximes · Semicarbazones · Transition metal complexes

Abstract

In this work, two novel vic-dioxime L1H2, L2H2 compounds bearing semicarbazone side groups and their Ni II complexes were synthesized. The vic-dioxime ligands of bearing semicarbazone side groups were synthesized by reactinganti-chloroglyoxime with semicarbazidehydrochloride, 4-aminoacetophenenone semicarbazone, respectively. Ligands form mononuclear complexes [Ni LH 2] with a metal:ligand ratio of 1:2. The Ni II complexes are proposed tobe square planar. Structural assignments are supported by a combination of1H-NMR,13C-NMR, HMQC, FT-IR, UV,elemental analyses and magnetic susceptibility

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Bu Makaleye Atıf Yap

BABAHAN, İ., ANIL, H., SARIKAVAKLI, N. (2007). Synthesis of vic-Dioxime Derivatives with Semicarbazone Side Groups and Their Ni II Complexes. Hacettepe Journal of Biology and Chemistry, Cilt: 35 - Sayı: 2, 117–121. https://ajindex.com/articles/256278

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Kaynakça (11)

  1. Serin, S., New vic-dioxime transition metal com- plexes, Trans. Met. Chem., 26, 300, 2001.
  2. Schrauzer, G. N., Windgassen, R. J., and Kohnle, J., Die Konstitution von vitamin B12, Chem. Ber., 98, 3324, 1965.
  3. Chakrovorty, A., Structural chemistry of transition metal complexes. of oximes, Coor. Chem. Rev., 13, 1, 1974.
  4. Thomas, T. W., and Underhill, A. E., Metal-Metal in- teractions in transition-metal complexes containing infinite chains of metal atoms, Chem. Soc. Rev., 1, 99, 1972.
  5. Underhill, A. E., Watkins, D. W., Petring, R., Electri- cal conduction properties of Ni(dpg)2I, Ni(dpg)2Br, and Pd(dpg)2I (where DPG= diphenylglyoxime), Inorg. Nucl. Chem. Lett., 9, 1269, 1973.
  6. Saleh, A. A., Khalıl, S. M. E., Eıd, M. F., and El- ghamry, M. A. Synthesis, spectral and magnetic stud- ies of mononüclear and binüclear Mn(II, Co(II), Ni(II), and Cu(II) complexes with semicarbazone ligands derived from sülfonamide, J., Coord. Chem., 56(6), 467, 2003.
  7. Beraldo, H., Nacif, W. F., and West, D.X., Spectral studies of semicarbazones derived from 3- and 4- formylpyridine and 3-and 4-acetylpyridine: crystal and molecular structure of 3-formylpyridine semicar- bazone, Spectrochim. Acta A, 57, 1847, 2001.
  8. Pandeya, S. N., Sıngh, V. M. P. N., and Rupaınwar, D. C., Anticonculsant activity of thioureido deriva- tives of acetophenone semicarbazone, Pharm. Res., 37(1), 17, 1998. 9. Macit, M., Batı, H., and Batı, B., Synethesis of 4- Benzyl-1-piperazineglyoxime and its use in the spec- trophometric determination of nickel, Turk J. Chem., 24, 81, 2000.
  9. Canpolat, E., and Kaya, M., Synthesis and charac- terization of Ni(II), Cu(II), Zn(II) and Cd(II) complexes of a new vic-dioxime ligand, 55(12), 1419, 2002.
  10. J., Coord. Chem. Özcan, E., Karapınar, E., and Karapınar, N., The synthesis Ni(II), Co(II), and Zn(II) complexes of two new unsymmetrical vic- dioximes, Synt. React. Inorg. Met.-Org. Chem., 31(7), 1163, 2001.
  11. Güp, R., Alpgüz, H. K., and Bedük, A.D., Synthesis and extraction properties of 1,2-bis(amidoxime) de- rivatives, Collect. Czech. 209, 2002. Chem. Commun., 67 Ibrahim, G., Chebli, E., Khan, M. A., and Bouet, G. M., Metallic complexes from 2-furaldehyde semicar- bazone bazone, Trans. Met. Chem., 24, 294, 1999. semicar Ibrahim, G., Khan, M. A., Richomme, P., Benali- Baїtіch, O., and Bouet, G., Synthesis and acterization of metallic complexes of 3-(2-furyl)- 2-propenal semicarbazone with d element dihalides, Polyhedron, 16(19), 3455, 1997. c h a r Nigam, S., Patel, M. M., and Ray, A.,