Structural assignments are supported by a combination of $^1H-NMR$, $^{13}C-NMR$, HMQC, FT-IR, UV, elemental analyses and magnetic susceptibility
📌 3 Key Takeaways
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Objective & Hypothesis:In this work, two novel vic-dioxime $(L^1H_2, L^2H_2)$ compounds bearing semicarbazone side groups and their Ni(II) complexes were synthesized.
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Key Findings & Data:The vic-dioxime ligands of bearing semicarbazone side groups were synthesized by reacting anti-chloroglyoxime with semicarbazidehydrochloride, 4-aminoacetophenenone semicarbazone, respectively.
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Conclusion & Impact:Structural assignments are supported by a combination of $^1H-NMR$, $^{13}C-NMR$, HMQC, FT-IR, UV, elemental analyses and magnetic susceptibility
🔬Design:Research Article
📍Scope:Comprehensive Sample
⚙️Variables:Domain Parameters
Abstract
In this work, two novel vic-dioxime $(L^1H_2, L^2H_2)$ compounds bearing semicarbazone side groups and their Ni(II) complexes were synthesized. The vic-dioxime ligands of bearing semicarbazone side groups were synthesized by reacting anti-chloroglyoxime with semicarbazidehydrochloride, 4-aminoacetophenenone semicarbazone, respectively. Ligands form mononuclear complexes $[Ni(LH)_2]$ with a metal:ligand ratio of 1:2. The Ni(II) complexes are proposed to be square planar. Structural assignments are supported by a combination of $^1H-NMR$, $^{13}C-NMR$, HMQC, FT-IR, UV, elemental analyses and magnetic susceptibility
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Cite This Article
BABAHAN, İ., SARIKAVAKLI, N., ANIL, H. (2022). Synthesis of vic-Dioxime derivatives with semicarbazone side groups and their Ni(II) complexes. Hacettepe Journal of Biology and Chemistry, Cilt: 35 - Sayı: 2, 117–121. https://ajindex.com/articles/529386
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