Journals / Uluslararası Bilim Teknoloji ve Tasarım Dergisi / 2026 / Cilt: 6 Sayı: 1

Electrodeposited WO₃ on Stainless Steel as a High-Energy Supercapacitor Electrode

Hasan Emir Kirtay(BURSA ULUDAĞ ÜNİVERSİTESİ, FEN-EDEBİYAT FAKÜLTESİ, FİZİK BÖLÜMÜ)0009-0006-6140-2494
Semih İlkay Tezcan(BURSA ULUDAĞ ÜNİVERSİTESİ, FEN-EDEBİYAT FAKÜLTESİ, FİZİK BÖLÜMÜ)0009-0001-4789-6874
Seyit Rıza Tokgöz(BURSA ULUDAĞ ÜNİVERSİTESİ, FEN-EDEBİYAT FAKÜLTESİ, FİZİK BÖLÜMÜ)0000-0001-9135-1508
Ahmet Peksöz(BURSA ULUDAĞ ÜNİVERSİTESİ, FEN-EDEBİYAT FAKÜLTESİ, FİZİK BÖLÜMÜ)0000-0001-5730-9541
Pages
86–94
Publication Date
2025-06-30
DOI
—
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AI Summary & Key Takeaways

AI Insight
⚡ TL;DR(Too Long; Didn't Read)

These results demonstrate that the WO₃/SS electrode is a promising candidate for next-generation supercapacitor devices, offering both high energy and power densities along with long-term durability.

📌 3 Key Takeaways

🎯
Objective & Hypothesis:Tungsten oxide (WO₃) thin films were successfully deposited onto stainless steel (SS) substrates via an electrochemical deposition method.
📊
Key Findings & Data:Cyclic voltammetry (CV) measurements revealed that the electrode maintains a wide electrochemical stability window of approximately 1.2 V, indicative of its suitability for high-energy applications.
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Conclusion & Impact:These results demonstrate that the WO₃/SS electrode is a promising candidate for next-generation supercapacitor devices, offering both high energy and power densities along with long-term durability.
🔬Design:Araştırma Makalesi
📍Scope:Comprehensive Sample
⚙️Variables:Energy Storage · Specific Capacitance · Power Density

Abstract

Tungsten oxide (WO₃) thin films were successfully deposited onto stainless steel (SS) substrates via an electrochemical deposition method. The structural and electrochemical characteristics of the resulting WO₃/SS electrode were systematically investigated using a three-electrode configuration in an aqueous electrolyte. Cyclic voltammetry (CV) measurements revealed that the electrode maintains a wide electrochemical stability window of approximately 1.2 V, indicative of its suitability for high-energy applications. At a scan rate of 10 mV s⁻¹, the WO₃/SS electrode delivered a high specific capacitance of 652.9 F g⁻¹, reflecting excellent charge storage capability. Galvanostatic charge-discharge (GCD) tests performed at a current density of 1 A g⁻¹ yielded an impressive energy density of 139.9 Wh kg⁻¹ and a corresponding power density of 7160.6 W kg⁻¹. Moreover, the electrode retained a high Coulombic efficiency of 98.2% after 10,000 continuous GCD cycles, highlighting its outstanding cycling stability. These results demonstrate that the WO₃/SS electrode is a promising candidate for next-generation supercapacitor devices, offering both high energy and power densities along with long-term durability.

Özet

Tungsten oxide (WO₃) thin films were successfully deposited onto stainless steel (SS) substrates via an electrochemical deposition method. The structural and electrochemical characteristics of the resulting WO₃/SS electrode were systematically investigated using a three-electrode configuration in an aqueous electrolyte. Cyclic voltammetry (CV) measurements revealed that the electrode maintains a wide electrochemical stability window of approximately 1.2 V, indicative of its suitability for high-energy applications. At a scan rate of 10 mV s⁻¹, the WO₃/SS electrode delivered a high specific capacitance of 652.9 F g⁻¹, reflecting excellent charge storage capability. Galvanostatic charge-discharge (GCD) tests performed at a current density of 1 A g⁻¹ yielded an impressive energy density of 139.9 Wh kg⁻¹ and a corresponding power density of 7160.6 W kg⁻¹. Moreover, the electrode retained a high Coulombic efficiency of 98.2% after 10,000 continuous GCD cycles, highlighting its outstanding cycling stability. These results demonstrate that the WO₃/SS electrode is a promising candidate for next-generation supercapacitor devices, offering both high energy and power densities along with long-term durability.

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Cite This Article

Kirtay, H. E., Tezcan, S. İ., Tokgöz, S. R., Peksöz, A. (2025). Electrodeposited WO₃ on Stainless Steel as a High-Energy Supercapacitor Electrode. Uluslararası Bilim Teknoloji ve Tasarım Dergisi, Cilt: 6 Sayı: 1, 86–94. https://ajindex.com/articles/1623206

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References (13)

  1. González, A., Goikolea, E., Barrena, J.A., and Mysyk, R., Review on supercapacitors: Technologies and materials, Renewable and Sustainable Energy Reviews, 58, 1189–1206, (2016).
  2. Simon, P., and Gogotsi, Y., Materials for electrochemical capacitors, Nature Materials, 7, 845–854, (2008).
  3. Wang, Q., and O’Hare, D., Recent advances in the synthesis and application of layered double hydroxide (LDH) nanosheets, Chemical Reviews, 112, 4124–4155, (2012).
  4. Konar, R., and Nessim, G.D., A mini-review focusing on ambient-pressure chemical vapor deposition (AP-CVD) based synthesis of layered transition metal selenides for energy storage applications, Materials Advances, 3, 4471-4488, (2022).
  5. Lokhande, V.,, Lokhande, A., Namkoong, G., Hyeok, J.K., and Ji, T., Charge storage in WO3 polymorphs and their application as supercapacitor electrode material, Results in Physics, 12, 2012-2020, (2019).
  6. Schoetz, T., Gordon, L.W., Ivanov, S., Bund, A., Mandler, D., and Messinger, R.J., Disentangling faradaic, pseudocapacitive, and capacitive charge storage: A tutorial for the characterization of batteries, supercapacitors, and hybrid systems, Electrochimica Acta, 412, 140072, (2022).
  7. Li, W.J., and Fu, Z.W., Nanostructured WO3 thin film as a new anode material for lithium-ion batteries, Applied Surface Science, 256(8), 2447-2452, (2010).
  8. Omrani, M., Habibi, M., Amrollahi, R., and Khosravi, A., Improvement of corrosion and electrical conductivity of 316L stainless steel as bipolar plate by TiN nanoparticle implantation using plasma focus, International Journal of Hydrogen Energy, 37(19), 14676-14686, (2012).
  9. Patil, S.J., Dubal, D.P., and Lee, D.W., Gold nanoparticles decorated rGO-ZnCo2O4 nanocomposite: A promising positive electrode for high performance hybrid supercapacitors, Chemical Engineering Journal, 379, 122211, (2020).
  10. Torun, H., Tokgöz, S.R., Arslan Çarpan, M., Somay, M.H., Peksöz, A., Fabrication of a high-performance symmetrical supercapacitor based on electrochemically interconnected Cu:NiO@rGO:PANI/NF electrodes, Journal of Energy Storage, 88, 111462, (2024).
  11. Huo, W.C., Liu, X.L., Yuan, Y.S., Li, N., Lan, T., Liu, X.Y., Zhang, Y.X., Facile synthesis of manganese cobalt oxide/nickel cobalt oxide composites for high-performance supercapacitors, Frontiers in Chemistry, 6, 661, (2019).
  12. Yu, Y., Xu, A., Zhang, Y., Zhao, Z., Ye, S., Qin, Y., Construction of hierarchical graphene/polyaniline@polyaniline electrodes by chemical and electrochemical polymerization for high-energy supercapacitors, Electrochimica Acta, 454, 142414, (2023).
  13. Rani, R., Kumar, A., Sharma, M., Mohan, B., Kumar, R., Chandra, R., Malik, V.K., Investigation of electrochemical properties of Pt-WO3 nanocomposite thin films for supercapacitor applications, 197, 112428, (2025).