Journals / JENAS Journal of Environmental and Natural Studies / 2026 / Cilt: 8 Sayı: 1

Sustainable Water Management: Chemical Methods And Green Chemistry Applications

Sürdürülebilir Su Yönetimi: Kimyasal Yöntemler ve Yeşil Kimya Uygulamaları

Mert Soysal(Aydın Adnan Menderes Üniversitesi)0000-0002-5685-0261
Pages
1–12
Publication Date
2026-06-30
🏛️Bibliographic metadata and full text access for this article are provided via DergiPark.
DergiPark Record ↗
✨

AI Summary & Key Takeaways

AI Insight
⚡ TL;DR(Too Long; Didn't Read)

This review critically examines current chemical approaches for improving water efficiency and highlights recent scientific advancements that incorporate green chemistry principles into sustainable water management strategies.

📌 3 Key Takeaways

🎯
Objective & Hypothesis:The sustainable management of water resources has emerged as one of the most pressing global challenges due to increasing water scarcity, rapid population growth, industrialization, climate change, and escalating environmental pollution.
📊
Key Findings & Data:Freshwater resources are under severe stress, making it imperative to develop adaptive and sustainable management strategies that ensure both water availability and quality.
💡
Conclusion & Impact:This review critically examines current chemical approaches for improving water efficiency and highlights recent scientific advancements that incorporate green chemistry principles into sustainable water management strategies.
🔬Design:Review & Systematic Survey
📍Scope:Comprehensive Sample
⚙️Variables:Sürdürülebilir Su Yönetimi · Yeşil Kimya · Su Verimliliği

Abstract

The sustainable management of water resources has emerged as one of the most pressing global challenges due to increasing water scarcity, rapid population growth, industrialization, climate change, and escalating environmental pollution. Freshwater resources are under severe stress, making it imperative to develop adaptive and sustainable management strategies that ensure both water availability and quality. Within this framework, chemical-based water treatment and management approaches play a crucial role in enhancing water efficiency, reducing pollutant loads, and enabling the safe reuse of water in industrial, agricultural, and domestic applications. Various conventional and advanced chemical techniques, including coagulation–flocculation, ion exchange, adsorption, membrane-based processes, and advanced oxidation processes (AOPs), are extensively utilized to improve the physicochemical characteristics of water. These methods are effective in removing organic contaminants, heavy metals, nutrients, and emerging pollutants such as pharmaceuticals and endocrine-disrupting compounds. Despite their effectiveness, many of these processes rely on hazardous chemicals, generate secondary waste streams, or require high energy inputs, which can limit their long-term sustainability. To address these challenges, the integration of green chemistry principles into water treatment technologies has gained increasing attention. Green chemistry emphasizes the reduction or elimination of toxic reagents, the use of renewable and biodegradable materials, and the design of energy-efficient and environmentally benign processes. In this context, natural and bio-based adsorbents, biodegradable polymers, eco-friendly coagulants, and low-energy chemical treatment methods have emerged as promising alternatives. This review critically examines current chemical approaches for improving water efficiency and highlights recent scientific advancements that incorporate green chemistry principles into sustainable water management strategies.

Özet

Su kaynaklarının sürdürülebilir yönetimi; artan küresel su kıtlığı, hızlı nüfus artışı, sanayileşme, iklim değişikliği ve çevresel kirliliğin giderek şiddetlenmesi nedeniyle günümüzde en kritik çevresel sorunlardan biri hâline gelmiştir. Tatlı su kaynakları üzerindeki baskının artması hem suyun niceliğini hem de kalitesini koruyacak uyarlanabilir ve sürdürülebilir yönetim stratejilerinin geliştirilmesini zorunlu kılmaktadır. Bu bağlamda, kimyasal temelli su arıtma ve yönetim yaklaşımları; su verimliliğinin artırılması, kirletici yüklerin azaltılması ve suyun güvenli bir şekilde yeniden kullanımı açısından önemli bir rol oynamaktadır. Koagülasyon-flokülasyon, iyon değişimi, adsorpsiyon, membran prosesleri ve ileri oksidasyon prosesleri (AOP’ler) gibi geleneksel ve ileri kimyasal yöntemler; suyun fizikokimyasal özelliklerini iyileştirmek amacıyla yaygın olarak kullanılmaktadır. Bu yöntemler; ağır metallerin, besin elementlerinin, organik kirleticilerin ve farmasötikler gibi yeni ortaya çıkan kirleticilerin giderilmesinde oldukça etkilidir. Ancak söz konusu tekniklerin bir kısmı toksik kimyasalların kullanımını gerektirmekte, ikincil atık oluşumuna neden olmakta veya yüksek enerji tüketimiyle çalışmaktadır. Bu durum, uzun vadeli sürdürülebilirlik açısından önemli sınırlamalar doğurmaktadır. Bu sorunlara çözüm olarak, yeşil kimya ilkelerinin su arıtma teknolojilerine entegrasyonu, giderek daha fazla önem kazanmaktadır. Yeşil kimya; toksik maddelerin kullanımının azaltılmasını, yenilenebilir ve biyobozunur malzemelerin tercih edilmesini ve enerji verimliliği yüksek süreçlerin tasarlanmasını hedeflemektedir. Bu kapsamda doğal adsorbanlar, biyobozunur polimerler, çevre dostu koagülantlar ve düşük enerji tüketimli kimyasal arıtma yöntemleri; sürdürülebilir su yönetimi için umut vadeden alternatifler olarak öne çıkmaktadır. Bu derleme çalışması, su verimliliğini artırmaya yönelik mevcut kimyasal yöntemleri ele almakta ve yeşil kimya yaklaşımlarının su yönetimi stratejilerine entegrasyonuna ilişkin güncel bilimsel gelişmeleri kapsamlı bir şekilde tartışmaktadır.

🔖

Cite This Article

Soysal, M. (2026). Sustainable Water Management: Chemical Methods And Green Chemistry Applications. JENAS Journal of Environmental and Natural Studies, Cilt: 8 Sayı: 1, 1–12. https://doi.org/10.53472/jenas.1863818

📄 Full Text PDF Viewer

📄

PDF görüntüleyici hazırlanıyor...

References (64)

  1. Abou-Shady, A., Siddique, M. S., & Yu, W. (2023). A critical review of recent progress in global water reuse during 2019-2021 and perspectives to overcome future water crisis. Environments, 10(9), 159. https://doi.org/10.3390/environments10090159
  2. Adamovic, S., Milosevic, R., & Prica, M. (2025). Optimizing batch electrocoagulation-flotation for emerging industrial wastewaters: A review on the state-of-the-art. Desalination and Water Treatment, 321, 100982.
  3. Alaoui, S. B., Achak, M., & Lamy, E. (2023). Hydrodynamic behavior of natural adsorbents filters for water treatment technology. Chemical Engineering & Technology, 46(6), 1235-1240. https://doi.org/10.1002/ceat.202200542
  4. Al-Gethami, W., Qamar, M. A., Shariq, M., Alaghaz, A. N. M. A., Farhan, A., Areshi, A. A., Alnasir, M. H. (2024). Emerging environmentally friendly bio-based nanocomposites for the efficient removal of dyes and micropollutants from wastewater by adsorption: a comprehensive review. RSC Advances, 4, 2804-2834. http://doi.org/10.1039/D3RA06501D
  5. Ali, M. E., Hoque, M. E., Hossain, S. K. S., Biswas, M. C. (2020). Nano adsorbents for wastewater treatment: next generation biotechnological solution. International Journal of Environmental Science, 17, 4095-4132. http://doi.org/10.1007/s13762-020-02755-4
  6. Ameta, R.K., Chohadia, A., Jain, A., Punjabi, P.B. (2018). Fenton and photo-fenton processes. Advanced oxidation processes for wastewater treatment. Elsevier, Armsterdam, pp49-87. http://doi.org/10.1016/B978-0-12-810499-6.00003-6
  7. Anastas, P.T., & Warner, J.C. (1998). Green Chemistry:Theory and Practice.Oxford University Press. https://doi.org/10.1093/oso/9780198506980.001.0001
  8. Arshad, R., Bokhari, T. H., Javed, T., Bhatti, I. A., Rasheed, S., Iqbal, M., Nazir, A., Naz, S., Khan, M. I., Khosa, M. K. K. (2020). Degradation product distribution of reactive red-147 dye treated by UV/H2O2/TiO2 advanced oxidation process. Journal of Materials Research and Technology, 9(3), 3168-3178. https://doi.org/10.1016/j.jmrt.2020.01.062
  9. Angelakis, A. N., Asano, T., Bahri, A., Jimenez, B. E., & Tchobanoglous, G. (2018). Water reuse: From ancient to modern times and the future. Frontiers in Environmental Science, 6, 26. https://doi.org/10.3389/fenvs.2018.00026
  10. Arzate, S., Campos-Manas, M.C., Miralles-Cuevas, S., Agüera, A., Garcia Sanchez, J.L., Sanchez Perez, J.A. (2020). Removal of contaminants of emerging concern by continuous flow solar photo-fenton process at neutral pH in open reactors. Journal of Environmental Management, 261, 110265. https://doi.org/10.1016/j.envman.2020.110265
  11. Ashraf, A., Ramamurthy, R., & Rene, E. R. (2021). Wastewater treatment and resource recovery technologies in the brewery industry: Current trends and emerging practices. Sustainable Energy Technologies and Assessments, 47, 101432.
  12. Aslam, A.A., Ul Hassan, S., Saeed, M.H., Kokab, O., Ali, Z., Nazir, M.S., Siddiqi, W., Aslam, A.A. (2023). Cellulose-based adsorbent materials for water remediation: Harnessing their potential in heavy metals and dyes removal. Journal of Cleaner Production, 421, 138555. https://doi.org/10.1016/j.clepro.2023.138555
  13. Bilal, M., Iqdal, H. M. N., Barcelo, D. (2020). Perspectives on the feasibility of using enzymes for pharmaceutical removal in wastewater. In: Rodriguez-Mozaz, S., Blanquez Cano, P., Sarra Adroguer, M. (eds) Removal and degradation of pharmaceutically active compounds in wastewater treatment. The handbook of Environmental Chemistry, 108, Springer, Cham. https://doi.org/10.1007/698_2020_661
  14. Brouillet, C., Gret-Regamery, A., Andriamanga, A. V., Martin, D. A., & Salliou, N. (2025). Soil extraction facilitates climate change adaptation and alters urban ecosystem services. Ecosystems and People, 21(1), 2469853. https://doi.org/10.1080/26395916.2025.2469853
  15. Dutta, A., Subramanian, A. S., Chakraborty, R., Erdogdu, F. (2020). Numerical modeling of water uptake in White rice (Oryza sativa L.) using variable diffusivity approach. Biosystems Engineering, 191, 116-128. https://doi.org/10.1016/j.biosystemseng.2020.01.011
  16. Eberle, S., Börnick, H., & Stolte, S. (2022). Granular natural zeolites: Cost-effective adsorbents for the removal of ammonium from drinking water. Water, 14(6), 939. https://doi.org/10.3390/w14060939
  17. Ferreira, L. C., Castro-Alferez, M., Nahim-Granados, S., polo-Lopez, M. I., Lucas, M. S. (2020). Inactivation of water pathogens with solar photo-activated persulfate oxidation. Chemical Engineering Journal, 381, 122275. https://doi.org/10.1016/j.cej.2019.122275
  18. Fu, Z. J., Jiang, S. K., Chao, X. Y., Zhang, C. X., Shi, Q., Wang, Z. Y., Liu, M. L., Sun, S. P. (2022). Removing miscellaneous heavy metals by all-in-one ion exchange-nanofiltration membrane. Water Research, 222, 118888. https://doi.org/10.1016/j.watres.2022.118888
  19. Iqbal, M., Nauman, S., Ghafari, M., Gomes, A., Gomes, C., Parnianifard, A. (2021). Treatment of wastewater for agricultural applications in regions of water scarcity. Biointerface Research in Applied Chemistry, 12(5), 6336-6360. https://doi.org/10.33263/briac125.63366360
  20. Iqbal, M.A., Akram, S., Khalid, S., Lal, B., Ul Hassan, S., Ashraf R., Kezembayeva, G., Mushtaq, M., Chinibayeva, N., Hosseini-Bandegharaei, A. (2024). Advanced photocatalysis as a viable and sustainable wastewater treatment process: A comprehensive review. Environmental Research, 253, 118947. https://doi.org/10.1016/j.envres.2024.118947
  21. Kaswan, V., & Kaur, H. (2023). A comparative study of advanced oxidation processes for wastewater treatment. Water Practice & Technology, 18(5), 1233. https://doi.org/10.2166/wpt.2023.061
  22. Kirhensteine, I., Cherrier, V., Jarritt, N., Farmer, A., De Paoli, G., Delacamara, G., & Psomas, A. (2016). EU-level instruments on water reuse. Final report to support the Commission’s impact assessment (pp. 1-292).
  23. Kumar, N. S. (2023). Smart and innovative nanotechnology applications for water purification. Hybrid Advances, 3, 100044. https://doi.org/10.1016/j.hybadv.2023.100044
  24. Kumar, M., Shekhar, S., Kumar, R., Kumar, P., Govarthanan, M., & Chaminda, T. (2023). Drinking water treatment and associated toxic byproducts: Concurrence and urgency. Environmental Pollution, 320, 121009. https://doi.org/10.1016/j.envpol.2023.121009
  25. Lazarova, V., Oelker, G., & Won, W. (2012). Production of custom-made recycled water for various reuse purposes: Lessons learned from one of the world’s largest recycling facilities. Water Practice & Technology, 7(3), 2012052. https://doi.org/10.2166/wpt.2012.052
  26. Liu, H., Wang, C., & Wang, G. (2020). Photocatalytic advanced oxidation processes for water treatment: Recent advances and perspective. Chemistry An Asian Journal, 15(20), 3239-3253. https://doi.org/10.1002/asia.202000895
  27. Machado, F., Teixeira, A.C.S.C., Ruotolo, L.A.M. (2023). Critical review of Fenton and photo-Fenton wastewater treatment processes over the last two decades. International Journal of Environmental Science and Technology, 20, 13995-14032. https://doi.org/10.1007/s13762-023-05015-3
  28. Mannina, G., Gulhan, H., & Ni, B. J. (2022). Water reuse from wastewater treatment: The transition towards circular economy in the water sector. Bioresource Technology, 363, 127951. https://doi.org/10.3390/environments11040081
  29. Mansouri, F., Chouchene, K., Roche, N., Ksibi, M. (2021). Removal of Pharmaceuticals from water by adsorption and advanced oxidation processes: state of the art and trends. Applied Sciences, 11(14), 6659. https://doi.org/10.3390/app11146659
  30. Martins, R. B., Jorge, N., Lucas, M. S., Raymundo, A., Barros, A. I. R. N. A., Peres, J. A. (2022). Food by-product valorization by using plant-based coagulants combined with AOPs for agro-industrial wastewater treatment. International Journal of Enviromental Research and Public Health, 19, 4134. https://doi.org/10.3390/ijerph19074134
  31. Mazumder, M. A. J. (2023). Polymeric adsorbents: Innovative materials for water treatments. Current Analytical Chemistry, 19, 105-110. https://doi.org/10.2174/1573411019666221103113309
  32. Meena, R. A. A., Kannah, R. Y., Sindhu, J., Ragavi, J., Kumar, G., Gunasekaran, M., & Banu, R. J. (2019). Trends and resource recovery in biological wastewater treatment systems. Bioresource Technology Reports, 7, 100235. https://doi.org/10.1016/j.biteb.2019.100235
  33. Nguyen V. T., Vo, T. D. H., Tran, T., Nguyen, T. N., Le, T. N. C., Bui, X. T., Bach, L. G. (2021). Biochar derived from the spent coffee ground for ammonium adsorption from aqueous solution. Case Studies in Chemical and Environmental Engineering, 4, 100141. https://doi.org/10.1016/j.cscee.2021.100141
  34. Olivera-Vargas, H., Pazos, M., Bustos, E., Deng, F.X., Salazar-Gonzalez, R., Oturan, M.A. (2025). Recent developments in (photo)electrocatalytic materials for wastewater treatment and resource recovery. Applied Catalysis O:Open, 202, 207033. https://doi.org/10.1016/j.apcato.2025.207033
  35. Papiri, S., Ciaponi, C., Capodaglio, A., Collivignarelli, C., Bertanza, G., Swartling, F., Crow, M., Fantozzi, M., & Valcher, P. (2003). Field monitoring and evaluation of innovative solutions for cleaning storm water runoff. Water Science & Technology, 47(7-8), 327-334. https://doi.org/10.2166/wst.2003.0706
  36. Procházková, M., Tous, M., Hornák, D., Miklas, V., Vondra, M., & Mása, V. (2023). Industrial wastewater in the context of European Union water reuse legislation and goals. Journal of Cleaner Production, 426, 139037. https://doi.org/10.1016/j.clepro.2023.139037
  37. Qiao, J., Xiong, Y.Z. (2021). Electrochemical oxidation technology: A review of its application in high-efficiency treatment of wastewater containing persistentorganic pollutants. Journal of Water Process Engineering, 44, 102308. https://doi.org/10.1016/j.wpe.2021.102308
  38. Qiu, Z., Shen, G.D., Yan, W.X., Zeng, X., Jiang, M.N., Li, Y.F., Xiang, H., Fu, H.L., Liu, C., Yu, B. (2025). A review of redox-active polymers for selective electrochemical removal of uncharged organic pollutants from water. Journal of Environmental Chemical Engineering, 13(2), 115774. https://doi.org/10.1016/j.jece.2025.115774
  39. Rao, G., Wells, E., Reynolds, C., Yoo, R., Kowalsky, E., DeFrance, J., Linden, K., Brown, J. (2025). Systematic review of the microbiological performance of household water treatment technologies. Environmental Science & Technology, xxx(xxx), xxx-xxx. https://doi.org/10.1021/acs.est.4c03494
  40. Renault, F., Sancey, B., Badot, P. M., & Crini, G. (2009). Chitosan for coagulation/flocculation processes—An eco-friendly approach. European Polymer Journal, 45(5), 1337-1348. https://doi.org/10.1016/j.eurpolymj.2008.12.027
  41. Rinisha Kartheeshwari, M., Sivaraj, K., Razi Sadath, P. V., & Elango, L. (2024). Innovative water management using abandoned quarries for urban water supply and flood mitigation. Environment, Development and Sustainability, 26, 31839-31857. https://doi.org/10.1007/s10668-024-04716-0
  42. Santana, A. H., Marquez-Gonzalez, M., Murillo, J. O., Guardado, W., & Sierra, D. (2023). Solar technology as an innovative alternative for quality water consumption: The Honduran experience in rural communities. Interciencia, 48(2), 83-87.
  43. Sarker, A., Al Masud, M.A., Deepo, D.M., Das, K., Nandi, R., Ansary, M.W.R., Islam, A.M.T., Islam, T. (2023). Biological and green remediation of heavy metal contaminated water and soils: A state-of-the-art review. Chemosphere332, 138861. https://doi.org/10.1016/j.chemosphere.2023.138861
  44. Shehbas, M. C., & Nampoothiri, M. (2025). A novel bioflocculant component of coagulating and flocculating the polystyrene from an Alcaligenes sp. Journal of Nanoparticle Research, 27, 99. https://doi.org/10.1007/s11051-025-06299-x
  45. Silva, J. A. (2023). Wastewater treatment and reuse for sustainable water resources management: A systematic literature review. Sustainability, 15(14), 10940. https://doi.org/10.3390/su151410940
  46. Silva, J. A. (2025). Advanced oxidation process in the sustainable treatment of refractory wastewater: a systematic literature review. Sustainability, 17, 3439. https://doi.org/10.3390/su17083439
  47. Su, R., Zhu, Y., Gao, B., & Li, Q. (2024). Progress on mechanism and efficacy of heterogeneous photocatalysis coupled oxidant activation as an advanced oxidation process for water decontamination. Water Research, 251, 121119. https://doi.org/10.1016/j.watres.2024.121119
  48. Tan, K. E. B., & Choi, A. E. Sy. (2025). Advancements in eco-friendly metal recovery: Chemical separation and fluidized bed reactor technology. South African Journal of Chemical Engineering, 52, 258-270. https://doi.org/10.1016/j.sajce.2025.03.003
  49. Terron, D., Sanroman, A., Pazos, M. (2025). Metal-Organic Frameworks: Next-Generation Materials for Environmental Remediation. Catalysis, 15(3), 244. https://doi.org/10.3390/catal15030244
  50. United Nations. (n.d.). Goal 6: Ensure availability and sustainable management of water and sanitation for all. Sustainable Development Goals Knowledge Platform. Retrieved April 7, 2025, from https://sustainabledevelopment.un.org/sdg6
  51. Velarde, L., Nabavi, M. S., Escalera, E., Antti, M. L., & Akhtar, F. (2023). Adsorption of heavy metals on natural zeolites: A review. Chemosphere, 328, 138508. https://doi.org/10.1016/j.chemosphere.2023.138508
  52. Villar, L. G. W., Garces-Porras, K. M., Zuniga, U. F. R., & Barreda, E. F. (2025). Extraction, chemical functionalization, and application of Stipa obtusa cellulose microfibers for lead ion adsorption. Journal of Natural Fibers, 22(1), 2476631. https://doi.org/10.1080/15440478.2025.2476631
  53. Wang, W., Wang, H., Li, G., An, T., Zhao, H., Wong, P.K. (2019). Catalyst-free activation of persulfate by visible light for water disinfection: Efficiency and mechanisms. Water Research, 157, 106-118. https://doi.org/10.1016/j.watres.2019.03.071
  54. Wolny, L., Zawieja, I., & Wlodarczyk, E. (2025). Chemical conditioning of sewage sludge in the environmental and sanitary aspect. Desalination and Water Treatment, 322, 101119. https://doi.org/10.1016/j.dwt.2025.101119
  55. Wu, W., Huang, Z.H., Lim, T.T. (2014). Recent development of mixed metal oxide anodes for electrochemical oxidation of organic pollutants in water. Applied Catalysis A: General, 480, 58-78. https://doi.org/10.1016/j.apcata.2014.04.035
  56. Xiong, J., Yi, J., Peng, S., Yang, Z., Wu, Y., Wang, W., Lv, S., Peng, J., Xue, C. Min, X., Li, M., Nakamura, T. (2022). Plant transpiration-inspired environmental energy-enhanced solar evaporator fabricated by polypyrrole decorated polyester fiber bundles for efficient water purification. Journal of Cleaner Production, 379(1), 134683. https://doi.org/10.1016/j.jclepro.2022.134683
  57. Yang, X.R., Chen, Z., Zhao, W., Liu, C.X., Qian, X.X., Zhang, M., Wei, G.Y., Khan, E., Ng, Y.H., Ok, Y.S. (2021). Recent advances in photodegradation of antibiotic residues in water. Chemical Engineering Journal, 405, 126806. https://doi.org/10.1016/j.cej.2020.126806
  58. Yenkie, K. M. (2019). Integrating the three E’s in wastewater treatment: Efficient design, economic viability, and environmental sustainability. Current Opinion in Chemical Engineering, 26, 131-138. https://doi.org/10.1016/j.coche.2019.09.002
  59. Yu, Y., Feng, X., Jian, Y., Shen, Y., Nie, X., Jia, W., Wang, Q., Qu, L., & Zhao, S. (2025). Mutual treatment of algae organic matters and heavy metal ions using a coagulation process: Processes and mechanism. Separation and Purification Technology, 362, 131900. https://doi.org/10.1016/j.seppur.2025.131900
  60. Yue, Q., Changshun, L., & Xiaohui, J. (2025). Institutionalized centralized management of large water network projects: An innovative solution to address water crisis. Water Policy, 27(2), 241-260. https://doi.org/10.2166/wp.2025.295
  61. Zhang, X. S., Liu, Z., Hu, N., Liu, M., Duan, C., Zhang, R., Quan, C. (2021b). Cellulose based cation-exchange fiber as filtration material fort he rapid removal of methylene blue from wastewater. Cellulose, 28, 9355-9367. https://doi.org/10.1007/s10570-021-04103-2
  62. Zhang, C., Wang, J., Chen, R. (2021). Water adsorption isotherms on soil external particle surface by molecular simulation. Computers and Geotechnics, 139, 104432. https://doi.org/10.1016/j.compgeo.2021.104432
  63. Zhuo, Q., Lu, J., Niu, J., Crittenden, J., Yu, G., Wang, S., Yang, B., & Chen, Z. (2022). Electrocatalytic oxidation processes for treatment of halogenated organic pollutants in aqueous solution: A critical review. ACS ES&T Engineering, 2(10), 1756–1775. https://doi.org/10.1021/acsestengg.1c00465
  64. Zhou, G., Chen, G., Tang, P., Li, X., Ma, J., & Liu, B. (2025). Revealing the removal behavior of five neglected microplastics in coagulation-ultrafiltration processes: Insights from experiments and predictive modeling. Journal of Hazardous Materials, 491, 137857. https://doi.org/10.1016/j.hazmat.2025.137857