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Journals / International Journal of Chemistry and Technology / 2017 / Volume: 1 Issue: 1

Synthesis, characterization and catalytic properties of some transition metal complexes of new phenoxy-imine ligand

Ali Çapan0000-0002-6477-6604
Gökhan Ceyhan0000-0002-9127-2348
Mehmet Sönmez(Gaziantep University)0000-0003-3127-666X
Pages
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Publication Date
2017-11-15
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AI Summary & Key Takeaways

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⚡ TL;DR(Too Long; Didn't Read)

It is suggested that Ru(III) complexes can be used in such catalysis reactions since they exhibit a high catalytic effect on cyclohexane oxidation.

📌 3 Key Takeaways

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Objective & Hypothesis:In this study a new Schiff base ligand was synthesized by the reaction of salicylaldehyde, 1,2-bis(bromomethyl)benzene and 4-nitrobenzenamine. [Cr(L)Cl 2 ]Cl·H 2 O, [Fe(L)Cl 2 ]Cl·2H 2 O and [Ru(L)Cl 2 ]Cl complexes were synthesized with this ligand and Cr(III), Fe(III) and Ru(III) chloride salts.
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Key Findings & Data:The structures of the ligand and the obtained complexes were characterized using Elemental Analysis, FT-IR, 1 H-NMR, 13 C-NMR, UV-Vis, Magnetic Susceptibility and Thermogravimetric Analysis.
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Conclusion & Impact:It is suggested that Ru(III) complexes can be used in such catalysis reactions since they exhibit a high catalytic effect on cyclohexane oxidation.
🔬Design:Research Article
📍Scope:Comprehensive Sample
⚙️Variables:Phenoxy-imine ligand · metal complexes · catalyst

Abstract

In this study a new Schiff base ligand was synthesized by the reaction of salicylaldehyde, 1,2-bis(bromomethyl)benzene and 4-nitrobenzenamine. [Cr(L)Cl 2 ]Cl·H 2 O, [Fe(L)Cl 2 ]Cl·2H 2 O and [Ru(L)Cl 2 ]Cl complexes were synthesized with this ligand and Cr(III), Fe(III) and Ru(III) chloride salts. The structures of the ligand and the obtained complexes were characterized using Elemental Analysis, FT-IR, 1 H-NMR, 13 C-NMR, UV-Vis, Magnetic Susceptibility and Thermogravimetric Analysis. The synthesized phenoxy-imine ligand is a ligand of the O 2 N 2 type. The resulting metal complexes are mononuclear and have octahedral geometry. Preliminary studies have also been carried out on the catalytic effects of complexes in cycloalkane oxidation and in cycloalkene epoxidation. In the general sense, the catalyst that triggers the highest product formation in the synthesized catalysts are the Ru(III) complex. It is suggested that Ru(III) complexes can be used in such catalysis reactions since they exhibit a high catalytic effect on cyclohexane oxidation.

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Cite This Article

Çapan, A., Ceyhan, G., Sönmez, M. (2017). Synthesis, characterization and catalytic properties of some transition metal complexes of new phenoxy-imine ligand. International Journal of Chemistry and Technology, Volume: 1 Issue: 1. https://doi.org/10.32571/ijct.345418

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References (41)

  1. Karaoglu, K.; Baran, T.; Serbest, K.; Er, M.; Degirmencioglu, I. J. Mol. Struct. 2009, 922, 39-45.
  2. Ekmekcioglu, P.; Karabocek, N.; Karabocek, S.; Emirik, M. J. Mol. Struct. 2015, 1099, 189-196.
  3. Er, M.; Sancak, K.; Değirmencioğlu, I., Serbest, K. J. Mol. Struct. 2008, 882, 35-46.
  4. Azadbakht, R.; Khanabadi, J. Inorg. Chem. Commun. 2013, 30, 21-25.
  5. Abbo, H. S.; Titinchi, S. J. J.; Prasad, R.; Chand, S. J. Mol. Catal. A: Chem. 2005, 225, 225¬232.
  6. Wang, Y.; Fu, Z.; Wen, X.; Rong, C,; Wu, W.; Zhang, Chao.; Deng, J.; Dai, B.; Kirk S.R.; Yin, D. J. Mol. Catal. A: Chem. 2014, 384, 46-52.
  7. Zoubi, W.A.L.; Kandil, F.; Chebani, M.K. Spectrochim. Acta Part A: Mol. Biomol. Spectrosc. 2011, 79(5), 1909-1914.
  8. Çolak, M.; Demirel, N. Tetrahedron: Asymmetry 2008, 19(5), 635-639.
  9. Temel, H.; Çakır, Ü.; Uğraş, H.İ.; Şekerci, M. J. Coord. Chem. 2003, 56, 943-951.
  10. Sönmez, M.; Çelebi, M. and Berber, İ. Eur. J. Med. Chem. 2010, 45, 1935-1940.
  11. Sivakumar, R.; Reena, V.; Ananthi N.; Babu, M.; Anandan, S.; Velmathi, S. Spectrochim. Acta Part A: Mol. Biomol. Spectrosc. 2010, 75(3), 1146-1151.
  12. Ceyhan, G.; Çelik, C.; Uruş, S.; Demirtaş, İ.; Elmastaş, M.; Tümer, M. Spectrochim Acta Part A: Mol. Biomol. Spectrosc. 2011, 81(1), 184-198. 13. Masih, I.; Fahmi, N. Spectrochim. Acta Part A: Mol. Biomol. Spectrosc. 2011, 79(5), 940-947.
  13. Rajsekhar, G.; Rao, C.P.; Saarenketo, P.; Nattinenb, K.; Rissanen, K. New J. Chem. 2004, 28, 75-84.
  14. Hailu, S. L,; Nair, B.U.; Redi‐Abshiro, M.; Diaz, I.; Aravindhan, R.; Tessema, M. Chinese J. Catal. 2016, 37(1), 135-145.
  15. Zhao, Y.; Tang, Y.; Liu, W.S.; Tang, Ning.; Tan, M.Y. Spectrochim. Acta Part A: Mol. Biomol. Spectrosc. 2006, 65(2), 372-377.
  16. Shoair, A.F,; El-Shobaky, A.R,. Azab, E.A. Spectrochim. Acta Part A: Mol. Biomol. Spectrosc. 2015, 151, 322-334.
  17. Baran, T.; Karaoglu, K.; Serbest, K.; Ağır, H.; Sandallı, C.; Değirmencioğlu, İ. Monatshefte für Chemie. 2013, 144, 1107-1115.
  18. El-Shobaky, A. R. Met-Org. Nano-Met. Chem. 2015, 45, 1481-1488.
  19. Yilmaz Obali,.A.; Ucan, H.I. J. Mol. Struct. 2015, 1081, 74-78.
  20. Karahan, A.; Yardan, A.; Yahsi, Y.; Kara, H.; Kurtaran, R. SDU J. Sci. (e-Journal). 2013, 8(2), 163-174.
  21. Naeimi, H.; Tarazian, R. J. Heterocyclic Chem. 2014, 51, 566.
  22. Kaya, İ.; Çulhaoğlu, S. Chinese J. Polym. Sci. 2012, 5, 682−693.
  23. Taşkın, O.K.; Öztürk, Ö.F.; Canpolat, E. BEÜ Fen Bilimleri Dergisi. 2012, 1, 34-39 (in Turkish).
  24. Canpolat, E.; Ağlamış, A., Şahal, H.; Kaya, M. Fen Bilimleri Dergisi (CFD), 2016, 37(1), 65-73.
  25. Serbest, K.; Karaoğlu, K.; Erman, M.; Er, M.; Değirmencioğlu, İ. Spectrochim. Acta Part A: Mol. Biomol. Spectrosc. 2010, 77(3), 643-651.
  26. Rajakumar, P.; Murali, V. Tetrahedron 2004, 60, 2351-2360.
  27. Rsmussen, J.C.; Toftlund, H.; Nivorzhkin, A.N.; Bourasse, J.; Ford, P.C. Inorg. Chim. Acta 1996, 251, 291-298.
  28. Islam, Sk.M.; Paul, S.; Roy A.S.; Banerjee, S.; Ghosh, K.; Dey, R.C.; Santra, S.C. Trans. Metal. Chem. 2013, 38(6), 675-682.
  29. Wang, Y.; Wen, X.; Rong, C.; Tang, S.; Wu, W.; Zhang, C.; Liu, Y.; Fu, Z. J. Mol. Catal. A: Chem. 2016, 411, 103-109.
  30. Pramanik, A.K.; Mondal, T.K. Inorg. Chim. Acta 2014, 411, 106-112.
  31. Dhara, P. K.; Drew, M. G. B.; Chattopadhyay P. Polyhedron 2006, 25, 1939-1945.
  32. Anastasiadis, N.; Bilis, G.; Plakatouras, J.C.; Raptopoulou, C.P.; Psycharis, V.; Beavers, C.; Teat, S.J.; Louloudi, M., Perlepes, S.P. Polyhedron 2013, 64, 189-202.
  33. Geary, W J. Coord. Chem. Rev. 1971, 7(1), 81-122.
  34. Manonmani, J.; Kandaswamy, M.; Narayanan, V.; Thirumurugan, R.; Shanmuga Sundura Raj, S.; Shanmugam, G., Ponnuswamy, M.N.; Fun, H.K. Polyhedron 2001, 20, 3039-3048.
  35. Abdel-Latif, S. A.; Hassib, H. B.; Issa, Y. M. Spectrochim Acta Part A: Mol. Biomol. Spectrosc. 2007, 67(3-4), 950-957.
  36. Urus, S.; Keles M.; Serindag, O. J. Inorg. Organometal Polym. 2010, 20, 152-160.
  37. Retcher, B.; Costa, J.S.; Tang, J.; Hage, R.; Gamez, P.; Reedijk, J. J. Mol. Catal. A: Chem. 2008, 286, 1-5.
  38. Luque R.; Badamali, S.K.; Clark, J.H.; Fleming, M.; Macquarrie, D.J. Appl. Catal. A: Gen. 2008, 341, 154-159.
  39. Azadbakht, R.; Khanabadi, J. Inorg. Chem. Commun. 2013, 30, 21-25.
  40. Yilmaz Obali,.A.; Ucan, H.I. J. Mol. Struct. 2015, 1081, 74-78.
  41. Taşkın, O.K.; Öztürk, Ö.F.; Canpolat, E. BEÜ Fen Bilimleri Dergisi. 2012, 1, 34-39 (in Turkish).