Journals / Journal of the Turkish Chemical Society Section B: Chemical Engineering / 2025 / Volume: 8 Issue: 2

Optimization of Removal Conditions for Basic Red 46 from Aqueous Solutions on Pinecone as an Eco-Friendly Adsorbent

Adnan Aldemir(Van Yüzüncü Yıl Üniversitesi)0000-0001-9884-0961
Ali Rıza Kul(VAN YÜZÜNCÜ YIL ÜNİVERSİTESİ)0000-0001-9331-775X
Pages
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Publication Date
2025-09-15
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AI Summary & Key Takeaways

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⚡ TL;DR(Too Long; Didn't Read)

The optimized conditions with DE program was obtained 55.20 mg L-1 initial BR 46 concentration, 151 min contact time and 314 K temperature for 74.15% removal percentage of BR 46.

📌 3 Key Takeaways

🎯
Objective & Hypothesis:Pinecone removal performance was investigated for Basic Red 46 (BR 46) adsorption and optimal removal conditions were determined with the response surface methodology (RSM).
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Key Findings & Data:Initial BR 46 concentration (20-60 mg L-1), temperature (298 K-318 K) and contact time (10-180 min) were selected as independent variables and removal percentage of BR 46 values were used as dependent variables.
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Conclusion & Impact:The optimized conditions with DE program was obtained 55.20 mg L-1 initial BR 46 concentration, 151 min contact time and 314 K temperature for 74.15% removal percentage of BR 46.
🔬Design:Modeling & Simulation
📍Scope:Comprehensive Sample
⚙️Variables:Adsorption · Basic Red 46 · Pinecone

Abstract

Pinecone removal performance was investigated for Basic Red 46 (BR 46) adsorption and optimal removal conditions were determined with the response surface methodology (RSM). Initial BR 46 concentration (20-60 mg L-1), temperature (298 K-318 K) and contact time (10-180 min) were selected as independent variables and removal percentage of BR 46 values were used as dependent variables. The quadratic model of the response to the independent variables was developed and 3D plots were interpreted as per selected variables. The selected model and terms presenting the p<0.05 are significant and they are considered to be statistically significant with the interaction of the initial BR 46 concentration and contact time. Analysis of variance was used to examine the interaction of response with independent variables and the results evidencing that the model regression was acceptable. The reliability of optimization studies was evaluated with R2, adjusted R2 and predicted R2 values which were obtained the 0.9792, 0.9604 and 0.8281, respectively. These determined R2 values were showed that high relationship between the predicted and calculated removal percentages. The removal percentage of BR 46 was obtained 64.43%, 70.78%, and 74.52% for 60 mg L-1 dye concentration at 298 K, 308 K and 318 K, respectively. The optimized conditions with DE program was obtained 55.20 mg L-1 initial BR 46 concentration, 151 min contact time and 314 K temperature for 74.15% removal percentage of BR 46.

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Cite This Article

Aldemir, A., Kul, A. R. (2025). Optimization of Removal Conditions for Basic Red 46 from Aqueous Solutions on Pinecone as an Eco-Friendly Adsorbent. Journal of the Turkish Chemical Society Section B: Chemical Engineering, Volume: 8 Issue: 2. https://doi.org/10.58692/jotcsb.1607300

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References (34)

  1. Aldemir, A., Turan, A., Kul, A.R., Koyuncu, H. (2023). Comprehensive investigation of Basic Red 46 removal by pinecone adsorbent: experimental, isotherm, kinetic and thermodynamic studies. International Journal of Environmental Science and Technology, 383(1):1-26. https://doi.org/10.1007/s13762-022-04456-6
  2. Aldemir, A., Kul, A.R., & Elik, H. (2019). Isotherm, kinetic and thermodynamic investigation into methylene blue adsorption onto pinecone powder. Journal of International Environmental Application and Science, 14(4), 183–192. Alipanahpour Dil, E., Ghaedi, M., Asfaram, A., Mehrabi, F., Bazrafshan, A.A., & Tayebi, L. (2019). Synthesis and application of Ce-doped TiO2 nanoparticles loaded on activated carbon for ultrasound-assisted adsorption of Basic Red 46 dye. Ultrasonics Sonochemistry, 58, 104702. https://doi.org/10.1016/j.ultsonch.2019.104702
  3. Almendros, A.I., Martín-Lara, M.A., Ronda, A., Pérez, A., Blázquez, G. & Calero, M. (2015). Physico-chemical characterization of pine cone shell and its use as biosorbent and fuel. Bioresource Technology, 196, 406-412. http://dx.doi.org/10.1016/j.biortech.2015.07.109
  4. Ayhan, N.N., Aldemir, A., Özgüven, A. (2024). Treatment of petroleum refinery wastewater by chemical coagulation method: determination of optimum removal conditions using experimental design. Brazilian Journal of Chemical Engineering, 41,121-137. https://doi.org/10.1007/s43153-023-00358-3
  5. Bayram, O., Köksal, E., Göde, F., & Pehlivan, E. (2021). Decolorization of water through removal of methylene blue and malachite green on biodegradable magnetic Bauhinia variagata fruits. International Journal of Phytoremediation. https://doi.org/10.1080/15226514.2021.1937931
  6. Bensalah, J., Berradi, M., Habsaoui, A., Allaoui, M., Essebaai, H., El Khattabi, O., … Rifi, E. H. (2021). Kinetic and thermodynamic study of the adsorption of cationic dyes by the cationic artificial resin Amberlite®IRC50. Materials Today: Proceedings, 45, 7468–7472. https://doi.org/10.1016/j.matpr.2021.02.028
  7. Bhowmik, S., Chakraborty, V., Das, P. (2021). Batch adsorption of indigo carmine on activated carbon prepared from sawdust: A comparative study and optimization of operating conditions using Response Surface Methodology, Results in Surfaces and Interfaces, 3(1), 100011. https://doi.org/10.1016/j.rsurfi.2021.100011
  8. Bouatay, F., Meksi, N., Adeel, S., Salah, F., & Mhenni, F. (2016). Dyeing behavior of the cellulosic and jute fibers with cationic dyes: process development and optimization using statistical analysis. Journal of Natural Fibers, 13(4), 423–436. https://doi.org/10.1080/15440478.2015.1043685
  9. De Gisi, S., Lofrano, G., Grassi, M., Notarnicola, M. (2016). Characteristics and adsorption capacities of low-cost sorbents for wastewater treatment: A review. Sustainable Materials and Technologies, 9(1), 10-40. http://dx.doi.org/10.1016/j.susmat.2016.06.002
  10. Deniz, F., & Karaman, S. (2011). Removal of Basic Red 46 dye from aqueous solution by pine tree leaves. Chemical Engineering Journal, 170(1), 67–74. https://doi.org/10.1016/j.cej.2011.03.029
  11. Deniz, F., & Saygideger, S.D. (2010). Investigation of adsorption characteristics of Basic Red 46 onto gypsum: Equilibrium, kinetic and thermodynamic studies. Desalination, 262(1–3), 161–165. https://doi.org/10.1016/j.desal.2010.05.062
  12. Deniz, F., & Saygideger, S.D. (2011). Removal of a hazardous azo dye (Basic Red 46) from aqueous solution by princess tree leaf. Desalination, 268(1–3), 6–11. https://doi.org/10.1016/j.desal.2010.09.043
  13. Dutta, S., Gupta, B., Srivastava, S.K., & Gupta, A.K. (2021). Recent advances on the removal of dyes from wastewater using various adsorbents: A critical review. Materials Advances, 2(14), 4497–4531. https://doi.org/10.1039/d1ma00354b
  14. Ergüt, M., & Özer, A. (2019). Green synthesis of pd/fe3o4 bimetallic nanoparticles: Catalytic in-situ generations of H2O2 for heterogeneous fenton-like decolorization of basic red 46 and direct red 23. Desalination and Water Treatment, 172, 115–124. https://doi.org/10.5004/dwt.2019.24972
  15. Ersingün, D., Aldemir, A. (2024). Design and two step process optimization of a reactive distillation column for improving production amount of ethyl acetate and water. Desalination Water Treatment, 317,100117. https://doi.org/10.1016/j.dwt.2024.100117
  16. Heydari, A., Asl, A.H., Asadollahzadeh, M., Torkaman, R. (2023). Optimization of synthesis conditions for preparation of radiation grafted polymeric fibers and process variables of adsorption with response surface methodology. Progress in Nuclear Energy, 155, 104468. https://doi.org/10.1016/j.pnucene.2022.104468
  17. Katheresan, V., Kansedo, J., Lau, S.Y. (2018). Efficiency of various recent wastewater dye removal methods: A review. Journal of Environmental Chemical Engineering, 6, 4676–4697. https://doi.org/10.1016/j.jece.2018.06.060
  18. Kopaç, T., & Sulu, E. (2019). Comparison of the adsorption behavior of Basic Red 46 textile dye on various activated carbons obtained from Zonguldak coal. Journal of the Faculty of Engineering and Architecture of Gazi University, 34(3), 1227–1240. https://doi.org/10.17341/gazimmfd.460518
  19. Kul, A.R., Koyuncu, H., Turan, A., Aldemir, A. (2023). Comparative research of isotherm, kinetic and thermodynamic studies for neutral red adsorption by activated carbon prepared from apple peel. Water Air Soil Pollution 383:1-26. https://doi.org/10.1007/s11270-023-06392-8
  20. Langeroodi, N.S., Farhadravesh, Z., & Khalaji, A.D. (2018). Optimization of adsorption parameters for Fe (III) ions removal from aqueous solutions by transition metal oxide nanocomposite. Green Chemistry Letters and Reviews, 11(4), 404–413. https://doi.org/10.1080/17518253.2018.1526329
  21. Mtshatsheni, K.N.G., Ofomaja, A.E., Naidoo, E.B. (2019). Synthesis and optimization of reaction variables in the preparation of pine-magnetite composite for removal of methylene blue dye. South African Journal of Chemical Engineering, 29(1), 33-41. https://doi.org/10.1016/j.sajce.2019.05.002
  22. Nguyen, D.T.C., Vo, D.V.N., Nguyen, T.T., Nguyen, T.T.T., Nguyen, L.T.T., Tran, T.V., (2022). Optimization of tetracycline adsorption onto zeolitic–imidazolate framework based carbon using response surface methodology. Surfaces and Interfaces 28, 101549. https://doi.org/10.1016/j.surfin.2021.101549.
  23. Özbay, N., Yargiç, A.Ş., Yarbay-Şahin, R.Z., & Önal, E. (2013). Full factorial experimental design analysis of reactive dye removal by carbon adsorption. Journal of Chemistry, 2013. https://doi.org/10.1155/2013/234904
  24. Paredes-Quevedo, L.C., González-Caicedo, C., Torres-Luna, J.A., & Carriazo, J.G. (2021). Removal of a Textile Azo-Dye (Basic Red 46) in Water by Efficient Adsorption on a Natural Clay. Water, Air, and Soil Pollution, 232(1). https://doi.org/10.1007/s11270-020-04968-2
  25. Raj, R.S., Krishnan, K.A. (2024). Multi-stage batch adsorption of acephate onto cauliflower like Fe3O4-MMT: Characterization and statistical optimization using response surface methodology. Environmental Nanotechnology, Monitoring & Management, 21, 100949. https://doi.org/10.1016/j.enmm.2024.100949
  26. Regti, A., Laamari, M.R., Stiriba, S.E., & El Haddad, M. (2017). Use of response factorial design for process optimization of basic dye adsorption onto activated carbon derived from Persea species. Microchemical Journal, 130, 129–136. https://doi.org/10.1016/j.microc.2016.08.012
  27. Salleh, M.A.M., Mahmoud, D.K., Karim, W.A.W.A., & Idris, A. (2011). Cationic and anionic dye adsorption by agricultural solid wastes: A comprehensive review. Desalination, 280(1–3), 1–13. https://doi.org/10.1016/j.desal.2011.07.019
  28. Shi, Y., Chang, Q., Zhang, T., Song, G., Sun, Y., Ding, G. (2022). A review on selective dye adsorption by different mechanisms. Journal of Environmental Chemical Engineering, 10(1), 108639. https://doi.org/10.1016/j.jece.2022.108639
  29. Sarioglu, M., & Bisgin, T. (2010). Decolorization of Basic Red 46 and Methylene Blue by anaerobic sludge: Biotic and abiotic processes. Desalination and Water Treatment, 23(1–3), 61–65. https://doi.org/10.5004/dwt.2010.1951
  30. Shoushtarian, F., Moghaddam, M.R.A., & Kowsari, E. (2020). Efficient regeneration/reuse of graphene oxide as a nanoadsorbent for removing basic Red 46 from aqueous solutions. Journal of Molecular Liquids, 312. https://doi.org/10.1016/j.molliq.2020.113386
  31. Umpuch, C., Fakthaisongdechakul, T. (2024). Application of response surface methodology for optimization of reactive black 5 removal by gelatin beads containing TTAB modified montmorillonite clay. Case Studies in Chemical and Environmental Engineering, 9, 100758. https://doi.org/10.1016/j.cscee.2024.100758
  32. Yagub, M.T., Sen, T.K., Afroze, S., & Ang, H.M. (2014). Dye and its removal from aqueous solution by adsorption: A review. Advances in Colloid and Interface Science, 209, 172–184. https://doi.org/10.1016/j.cis.2014.04.002
  33. Yang, X., Zhu, W., Song, Y., Zhuang, H., & Tang, H. (2021). Removal of cationic dye BR46 by biochar prepared from Chrysanthemum morifolium Ramat straw: A study on adsorption equilibrium, kinetics and isotherm. Journal of Molecular Liquids, 340, 116617. https://doi.org/10.1016/j.molliq.2021.116617
  34. Aldemir, A., Kul, A.R., & Elik, H. (2019). Isotherm, kinetic and thermodynamic investigation into methylene blue adsorption onto pinecone powder. Journal of International Environmental Application and Science, 14(4), 183–192.