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Journals / Fırat Üniversitesi Mühendislik Bilimleri Dergisi / 2026 / Cilt: 31 Sayı: 1

Poly N-Aminorodaninin Elektrokimyasal Sentezi Ve Karakterizasyonu

Ece Altunbaş Şahin0000-0002-3201-0487
Ali Döner0000-0002-3403-5370
Gülfeza Kardaş0000-0002-7871-6303
Pages
231–240
Publication Date
2019-03-15
DOI
—
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AI Summary & Key Takeaways

AI Insight
⚡ TL;DR(Too Long; Didn't Read)

Polimer KOH ve dimetil sülfoksit çözeltileri içerisinde çözünmektedir.

📌 3 Key Takeaways

🎯
Objective & Hypothesis:Bu çalışmada, Poly-N-aminorodanin (pNAR) platin elektrot yüzeyine dönüşümlü voltametri tekniği kullanılarak sentezlenmiştir. pNAR’nin pembe renkli ve homojen yapıda olduğu tespit edilmiştir. pNAR’ın kimyasal yapısı ve oluşum mekanizması 13C-NMR, FT-Infrared spektrumları ve enerji dağılımlı X-ışını spektroskopisi (EDX) ile belirlenmiştir. pNAR’ın termal özellikleri termogravimetrik analiz (TGA), diferansiyel termal analiz ve diferansiyel taramalı kalorimetri (DSC) teknikleri kullanılarak araştırılmıştır.
📊
Key Findings & Data:Polimer filmin termal dayanıklılığını yüksek olduğu bulunmuştur.
💡
Conclusion & Impact:Polimer KOH ve dimetil sülfoksit çözeltileri içerisinde çözünmektedir.
🔬Design:Araştırma Makalesi
📍Scope:Comprehensive Sample
⚙️Variables:Elektrokimyasal polimerizasyon · N-aminorhodanine · poly-N-aminorhodanine

Özet

Bu çalışmada, Poly-N-aminorodanin (pNAR) platin elektrot yüzeyine dönüşümlü voltametri tekniği kullanılarak sentezlenmiştir. pNAR’nin pembe renkli ve homojen yapıda olduğu tespit edilmiştir. pNAR’ın kimyasal yapısı ve oluşum mekanizması 13C-NMR, FT-Infrared spektrumları ve enerji dağılımlı X-ışını spektroskopisi (EDX) ile belirlenmiştir. pNAR’ın termal özellikleri termogravimetrik analiz (TGA), diferansiyel termal analiz ve diferansiyel taramalı kalorimetri (DSC) teknikleri kullanılarak araştırılmıştır. Polimer filmin termal dayanıklılığını yüksek olduğu bulunmuştur. Polimer filmin yüzey morfolojisi taramalı elektron mikroskopu (SEM), ve atomik kuvvet mikroskopu (AFM) ile belirlenmiştir. Polimer KOH ve dimetil sülfoksit çözeltileri içerisinde çözünmektedir.

🔖

Cite This Article

Şahin, E. A., Döner, A., Kardaş, G. (2019). Poly N-Aminorodaninin Elektrokimyasal Sentezi Ve Karakterizasyonu. Fırat Üniversitesi Mühendislik Bilimleri Dergisi, Cilt: 31 Sayı: 1, 231–240. https://ajindex.com/articles/1268166

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  36. Somboonsub B, Srisuwan S, Invernale MA, Praserthdam SP, Scola DA, Sotzing GA.Comparison of the thermally stable conducting polymers PEDOT, PANi, and PPy using sulfonated poly(imide) templates. Polymer 2010;51:4472-4476
  37. David V, Vinas C, Teixidor F. Poly(3,4-ethylenedioxythiophene) doped with a non-extrudable metallacarborane anion electroactive during synthesis. Polymer 2006;47:4694–4702
  38. Arslan A, Türkaslan Ö, Tanyel C, Akhmedov IM, Toppare L.Electrochromic properties of a soluble conducting polymer: Poly(1-(4-fluorophenyl)-2,5-di(thiophen-2-yl)-1H-pyrrole. Mater. Chem. Phys. 2007;104:410-416
  39. Alvarez-Romero GA, Garfias-Garcia E, Ramirez-Silva MT, Galan-Vidal C, Romero-Romo M, Palomar-Pardave M. Electrochemical and AFM characterization of the electropolimerization of pyrrole over a graphite–epoxy resin solid composite electrode, in the presence of different anions. Appl. Surf. Sci. 2006; 252:5783–5792
  40. Jiang Y, Xu J, Yu J. Conducting polymeric nanoparticles synthesized in reverse micelles and their gas sensitivity based on quartz crystal microbalance. Polymer 2007;48:4459–4465
  41. Solmaz R. Electrochemical synthesis of poly-2-aminothiazole on mild steel and its corrosion inhibition performance. Prog. Org. Coat. 2011;70:122–126
  42. Diaz AF. Electrochemical preparation and characterization of conducting polymers. Chem. Scr., 1981;17:145-148
  43. Tourillon G, Garnier F. New Electrochemically generated organic conducting polymers. J. Electroanal. Chem.,1982;135:173-178
  44. Pringlea JM, Efthimiadisb J, Howletta PC, MacFarlanea DR, Chaplinc AB, Hallc SB, Officerc L, Wallaced GG, Forsyth M.Electrochemical synthesis of polypyrrole in ionic liquids. Polymer 2004;45:1447–1453
  45. Tüken T, Özyılmaz AT, Yazıcı B, Erbil M. Electrochemical synthesis of polyaniline on mild steel in acetonitrile–LiClO4 and corrosion performance. Appl. Surf. Sci. 2004;236:292–305
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  49. Inzelt G, Pineri M, Schultze JW, Vorotyntsev MA. Electron and proton conducting polymers: recent developments and prospects. Electrochim. Acta 2000;45:2403-2421
  50. Solmaz R, Kardaş G. Electrochemical synthesis and characterization of poly-2-aminothiazole. Prog. Org. Coat. 2009;64:81–88
  51. Kardaş G, Solmaz R.Electrochemical synthesis and characterization of a new conducting polymer: Polyrhodanine. Appl. Surf. Sci. 2007;253:3402–3407
  52. Cutshall NS, Oday C, Prezhdo M. Rhodanine derivatives as inhibitors of JSP-1 Bioorg. Med. Chem. Lett. 2005;15:3374-3379
  53. Mishra S, Srivastava SK, Srivastava SD. Synthesis of 5-arylidene-2-aryl-3-(phenothiazino/benzotriazoloacetamidyl)-1,3-thiazolidine-4-ones as antiinflammatory, anticonvulsant, analgesic and antimicrobial agents. Indian J. Chem. Sect. B 1997;36:826-830
  54. Foye WO, Tovivich P. N-Glucopyranosyl-5-aralkylidenerhodanines: Synthesis and antibacterial and antiviral activities. J. Pharm. Sci. 1977;66:1607-1611
  55. Momose Y, Meguro K, Ikeda H, Hatanaka C, Oi S, Sohda T. Studies On Antidiabetic Agents.10. Synthesis And Biological-Activities Of Pioglitazone And Related-Compounds. Chem. Pharm. Bull. 1991; 39:1440-1445
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  57. Habib NS, Rida SM, Badawey EAM, Fahmy HTY, Ghozlan HA. Synthesis and antimicrobial activity of rhodanine derivatives. Eur. J. Med. Chem. 1997;32:759-762
  58. Chandrakant GB, Gaikwad NJ. Synthesis and preliminary evaluation of some pyrazine containing thiazolines and thiazolidinones as antimicrobial agents. Bioorgan. Med. Chem. 2004;12:2151-2161
  59. Vittoria DM, Mazzoni O, Piscopo E, Caligmano A, Bolognese A.Synthesis and antihistaminic activity of some thiazolidin-4-ones. J.Med. Chem. 1992;35:2910-2912
  60. Sing W, Lee T, Yeo SL, Lim S, Sim P. Arylalkylidene rhodanine with bulky and hydrophobic functional group as selective HCV NS3 protease inhibitor. Bioorgan. Med. Chem. Lett. 2001;11:91-93
  61. Cutshall NS, O’Day C.Prezhdo Rhodanine derivatives as inhibitors of JSP-1. M. Bioorgan Med. Chem. Lett. 2005;15:3374–3379
  62. Altunbas E¸ Solmaz R, Kardas G. Corrosion behaviour of polyrhodanine coated copper electrode in 0.1 M H2SO4 solution. Mater. Chem. Phys. 2010;121:354–358
  63. Jabeen S, Rex A, Palmer BS, Potter M, Trevor JD, Babur ZC. Low Temperature Crystal Structures of Two Rhodanine Derivatives, 3-Amino Rhodanine and 3-Methyl Rhodanine: Geometry of the Rhodanine Ring. J Chem Crystallogr 2009;39:151–156
  64. Wessling B, Skotheim TA, Elsenbaumer RL, Reynolds JR. Editors, Handbook of conducting polymers, 2nd ed. New York: Marcel Dekker, 1998;p. 467
  65. Menon R, Yoon CO, Moses D, Heeger AJ. In: Skotheim TA, Elsenbaumer RL, Reynolds JR, editors. Handbook of conducting polymers,2nd ed. New York: Marcel Dekker,. 1998;p. 27
  66. Yuehong P, He X, Xiaoyu L, Hongliu D, Yuxiao C, Guoyue S. Electrochemical synthesis, characterization, and electrochromic properties of poly(3-chlorothiophene) and its copolymer with 3-methylthiophene in a room temperature ionic liquid. Electrochem. Commun. 2006;8:1757–1763
  67. Casas J, Castellano E, Macias A, Playa N, Sanchez A, Sordo J, Varela J, Lopez E. Methyl- and phenylmercury(II) complexes of 5-(4′-dimethylaminobenzylidene)rhodanine (HDABRd) and 5-(2′-thiophenomethylene)rhodanine (HTRd). The crystal and molecular structure of [HgPh(DABRd)] and [HgMe(TRd)]. Polyhedron 2001;20:1845-1850