KaydedilenlerDerginizi ekleyin

Dergiler / Fırat Üniversitesi Mühendislik Bilimleri Dergisi / 2026 / Cilt: 31 Sayı: 1

Poly N-Aminorodaninin Elektrokimyasal Sentezi Ve Karakterizasyonu

Ece Altunbaş Şahin0000-0002-3201-0487
Ali Döner0000-0002-3403-5370
Gülfeza Kardaş0000-0002-7871-6303
Sayfa
231–240
Yayın Tarihi
2019-03-15
DOI
—
🏛️Bu makalenin bibliyografik verileri ve tam metin bağlantısı DergiPark üzerinden sağlanmıştır.
DergiPark Kaydı ↗
✨

Yapay Zeka Hızlı Bakış & Çıkarımlar

AI Insight
⚡ TL;DR(1 Cümlede Hızlı Çıkarım)

Bu çalışmada, Poly-N-aminorodanin (pNAR) platin elektrot yüzeyine dönüşümlü voltametri tekniği kullanılarak sentezlenmiştir. pNAR’nin pembe renkli ve homojen yapıda olduğu tespit edilmiştir. pNAR’ın kimyasal yapısı ve oluşum mekanizması 13C-NMR, FT-Infrared spektrumları ve enerji dağılımlı X-ışını spektroskopisi (EDX) ile belirlenmiştir. pNAR’ın termal özellikleri termogravimetrik analiz (TGA), diferansiyel termal analiz ve diferansiyel taramalı kalorimetri (DSC) teknikleri kullanılarak araştırılmıştır.

📌 3 Maddede Bu Makale

🎯
Amaç & Hipotez:Bu çalışmada, Poly-N-aminorodanin (pNAR) platin elektrot yüzeyine dönüşümlü voltametri tekniği kullanılarak sentezlenmiştir. pNAR’nin pembe renkli ve homojen yapıda olduğu tespit edilmiştir. pNAR’ın kimyasal yapısı ve oluşum mekanizması 13C-NMR, FT-Infrared spektrumları ve enerji dağılımlı X-ışını spektroskopisi (EDX) ile belirlenmiştir. pNAR’ın termal özellikleri termogravimetrik analiz (TGA), diferansiyel termal analiz ve diferansiyel taramalı kalorimetri (DSC) teknikleri kullanılarak araştırılmıştır.
📊
Temel Bulgular & Veri:Polimer filmin termal dayanıklılığını yüksek olduğu bulunmuştur.
💡
Sonuç & Katkı:Polimer KOH ve dimetil sülfoksit çözeltileri içerisinde çözünmektedir.
🔬Tür:Araştırma Makalesi
📍Kapsam:Genişletilmiş Akademik Örneklem
⚙️Değişkenler:Elektrokimyasal polimerizasyon · N-aminorhodanine · poly-N-aminorhodanine

Özet

Bu çalışmada, Poly-N-aminorodanin (pNAR) platin elektrot yüzeyine dönüşümlü voltametri tekniği kullanılarak sentezlenmiştir. pNAR’nin pembe renkli ve homojen yapıda olduğu tespit edilmiştir. pNAR’ın kimyasal yapısı ve oluşum mekanizması 13C-NMR, FT-Infrared spektrumları ve enerji dağılımlı X-ışını spektroskopisi (EDX) ile belirlenmiştir. pNAR’ın termal özellikleri termogravimetrik analiz (TGA), diferansiyel termal analiz ve diferansiyel taramalı kalorimetri (DSC) teknikleri kullanılarak araştırılmıştır. Polimer filmin termal dayanıklılığını yüksek olduğu bulunmuştur. Polimer filmin yüzey morfolojisi taramalı elektron mikroskopu (SEM), ve atomik kuvvet mikroskopu (AFM) ile belirlenmiştir. Polimer KOH ve dimetil sülfoksit çözeltileri içerisinde çözünmektedir.

🔖

Bu Makaleye Atıf Yap

Şahin, E. A., Döner, A., Kardaş, G. (2019). Poly N-Aminorodaninin Elektrokimyasal Sentezi Ve Karakterizasyonu. Fırat Üniversitesi Mühendislik Bilimleri Dergisi, Cilt: 31 Sayı: 1, 231–240. https://ajindex.com/articles/1268166

📄 Tam Metin PDF Okuyucu

📄

PDF görüntüleyici hazırlanıyor...

Kaynakça (67)

  1. Shirakawa H. The discovery of polyacetylene film: The dawning of an era of conducting. Polymers Chem. Int. Ed. 2001; 40:2575-2580
  2. Hsiao S, Liou G, Kung Y, Lee Y. Synthesis and characterization of electrochromic poly(amide–imide)s based on the diimide-diacid from 4,4′-diamino-4″-methoxytriphenylamine and trimellitic anhydride. Eur. Polym J. 2010; 46:1355–1366
  3. Somboonsub B, Srisuwan S, Invernale MA, Praserthdam SP, Scola DA, Sotzing GA.Comparison of the thermally stable conducting polymers PEDOT, PANi, and PPy using sulfonated poly(imide) templates. Polymer 2010;51:4472-4476
  4. David V, Vinas C, Teixidor F. Poly(3,4-ethylenedioxythiophene) doped with a non-extrudable metallacarborane anion electroactive during synthesis. Polymer 2006;47:4694–4702
  5. Arslan A, Türkaslan Ö, Tanyel C, Akhmedov IM, Toppare L.Electrochromic properties of a soluble conducting polymer: Poly(1-(4-fluorophenyl)-2,5-di(thiophen-2-yl)-1H-pyrrole. Mater. Chem. Phys. 2007;104:410-416
  6. Alvarez-Romero GA, Garfias-Garcia E, Ramirez-Silva MT, Galan-Vidal C, Romero-Romo M, Palomar-Pardave M. Electrochemical and AFM characterization of the electropolimerization of pyrrole over a graphite–epoxy resin solid composite electrode, in the presence of different anions. Appl. Surf. Sci. 2006; 252:5783–5792
  7. Jiang Y, Xu J, Yu J. Conducting polymeric nanoparticles synthesized in reverse micelles and their gas sensitivity based on quartz crystal microbalance. Polymer 2007;48:4459–4465
  8. Solmaz R. Electrochemical synthesis of poly-2-aminothiazole on mild steel and its corrosion inhibition performance. Prog. Org. Coat. 2011;70:122–126
  9. Diaz AF. Electrochemical preparation and characterization of conducting polymers. Chem. Scr., 1981;17:145-148
  10. Tourillon G, Garnier F. New Electrochemically generated organic conducting polymers. J. Electroanal. Chem.,1982;135:173-178
  11. Pringlea JM, Efthimiadisb J, Howletta PC, MacFarlanea DR, Chaplinc AB, Hallc SB, Officerc L, Wallaced GG, Forsyth M.Electrochemical synthesis of polypyrrole in ionic liquids. Polymer 2004;45:1447–1453
  12. Tüken T, Özyılmaz AT, Yazıcı B, Erbil M. Electrochemical synthesis of polyaniline on mild steel in acetonitrile–LiClO4 and corrosion performance. Appl. Surf. Sci. 2004;236:292–305
  13. Lakard B, Herlem G, Fahys B. Electrochemical polymerization of 1,2-ethanedithiol as a new way to synthesize polyethylenedisulfide. Polymer 2008;49:1743-1747
  14. Inzelt G.Conducting Polymers: A New Erain Electrochemistry, Springer, Berlin, 1987 (Chapter4)
  15. Malinauskas A.Electrocatalysis at conducting polymers. Synth. Met 1999;107:75-83
  16. Inzelt G, Pineri M, Schultze JW, Vorotyntsev MA. Electron and proton conducting polymers: recent developments and prospects. Electrochim. Acta 2000;45:2403-2421
  17. Solmaz R, Kardaş G. Electrochemical synthesis and characterization of poly-2-aminothiazole. Prog. Org. Coat. 2009;64:81–88
  18. Kardaş G, Solmaz R.Electrochemical synthesis and characterization of a new conducting polymer: Polyrhodanine. Appl. Surf. Sci. 2007;253:3402–3407
  19. Cutshall NS, Oday C, Prezhdo M. Rhodanine derivatives as inhibitors of JSP-1 Bioorg. Med. Chem. Lett. 2005;15:3374-3379
  20. Mishra S, Srivastava SK, Srivastava SD. Synthesis of 5-arylidene-2-aryl-3-(phenothiazino/benzotriazoloacetamidyl)-1,3-thiazolidine-4-ones as antiinflammatory, anticonvulsant, analgesic and antimicrobial agents. Indian J. Chem. Sect. B 1997;36:826-830
  21. Foye WO, Tovivich P. N-Glucopyranosyl-5-aralkylidenerhodanines: Synthesis and antibacterial and antiviral activities. J. Pharm. Sci. 1977;66:1607-1611
  22. Momose Y, Meguro K, Ikeda H, Hatanaka C, Oi S, Sohda T. Studies On Antidiabetic Agents.10. Synthesis And Biological-Activities Of Pioglitazone And Related-Compounds. Chem. Pharm. Bull. 1991; 39:1440-1445
  23. Sudo K, Matsumoto Y, Matsushima M, Fujiwara M, Konno K, Shimotohno K, Shigeta S, Yokota T. Novel Hepatitis C Virus Protease Inhibitors: Thiazolidine Derivatives. Biochem. Biophys. Res. Commun. 1997;238:643-647
  24. Habib NS, Rida SM, Badawey EAM, Fahmy HTY, Ghozlan HA. Synthesis and antimicrobial activity of rhodanine derivatives. Eur. J. Med. Chem. 1997;32:759-762
  25. Chandrakant GB, Gaikwad NJ. Synthesis and preliminary evaluation of some pyrazine containing thiazolines and thiazolidinones as antimicrobial agents. Bioorgan. Med. Chem. 2004;12:2151-2161
  26. Vittoria DM, Mazzoni O, Piscopo E, Caligmano A, Bolognese A.Synthesis and antihistaminic activity of some thiazolidin-4-ones. J.Med. Chem. 1992;35:2910-2912
  27. Sing W, Lee T, Yeo SL, Lim S, Sim P. Arylalkylidene rhodanine with bulky and hydrophobic functional group as selective HCV NS3 protease inhibitor. Bioorgan. Med. Chem. Lett. 2001;11:91-93
  28. Cutshall NS, O’Day C.Prezhdo Rhodanine derivatives as inhibitors of JSP-1. M. Bioorgan Med. Chem. Lett. 2005;15:3374–3379
  29. Altunbas E¸ Solmaz R, Kardas G. Corrosion behaviour of polyrhodanine coated copper electrode in 0.1 M H2SO4 solution. Mater. Chem. Phys. 2010;121:354–358
  30. Jabeen S, Rex A, Palmer BS, Potter M, Trevor JD, Babur ZC. Low Temperature Crystal Structures of Two Rhodanine Derivatives, 3-Amino Rhodanine and 3-Methyl Rhodanine: Geometry of the Rhodanine Ring. J Chem Crystallogr 2009;39:151–156
  31. Wessling B, Skotheim TA, Elsenbaumer RL, Reynolds JR. Editors, Handbook of conducting polymers, 2nd ed. New York: Marcel Dekker, 1998;p. 467
  32. Menon R, Yoon CO, Moses D, Heeger AJ. In: Skotheim TA, Elsenbaumer RL, Reynolds JR, editors. Handbook of conducting polymers,2nd ed. New York: Marcel Dekker,. 1998;p. 27
  33. Yuehong P, He X, Xiaoyu L, Hongliu D, Yuxiao C, Guoyue S. Electrochemical synthesis, characterization, and electrochromic properties of poly(3-chlorothiophene) and its copolymer with 3-methylthiophene in a room temperature ionic liquid. Electrochem. Commun. 2006;8:1757–1763
  34. Casas J, Castellano E, Macias A, Playa N, Sanchez A, Sordo J, Varela J, Lopez E. Methyl- and phenylmercury(II) complexes of 5-(4′-dimethylaminobenzylidene)rhodanine (HDABRd) and 5-(2′-thiophenomethylene)rhodanine (HTRd). The crystal and molecular structure of [HgPh(DABRd)] and [HgMe(TRd)]. Polyhedron 2001;20:1845-1850 [1] Shirakawa H. The discovery of polyacetylene film: The dawning of an era of conducting. Polymers Chem. Int. Ed. 2001; 40:2575-2580
  35. Hsiao S, Liou G, Kung Y, Lee Y. Synthesis and characterization of electrochromic poly(amide–imide)s based on the diimide-diacid from 4,4′-diamino-4″-methoxytriphenylamine and trimellitic anhydride. Eur. Polym J. 2010; 46:1355–1366
  36. Somboonsub B, Srisuwan S, Invernale MA, Praserthdam SP, Scola DA, Sotzing GA.Comparison of the thermally stable conducting polymers PEDOT, PANi, and PPy using sulfonated poly(imide) templates. Polymer 2010;51:4472-4476
  37. David V, Vinas C, Teixidor F. Poly(3,4-ethylenedioxythiophene) doped with a non-extrudable metallacarborane anion electroactive during synthesis. Polymer 2006;47:4694–4702
  38. Arslan A, Türkaslan Ö, Tanyel C, Akhmedov IM, Toppare L.Electrochromic properties of a soluble conducting polymer: Poly(1-(4-fluorophenyl)-2,5-di(thiophen-2-yl)-1H-pyrrole. Mater. Chem. Phys. 2007;104:410-416
  39. Alvarez-Romero GA, Garfias-Garcia E, Ramirez-Silva MT, Galan-Vidal C, Romero-Romo M, Palomar-Pardave M. Electrochemical and AFM characterization of the electropolimerization of pyrrole over a graphite–epoxy resin solid composite electrode, in the presence of different anions. Appl. Surf. Sci. 2006; 252:5783–5792
  40. Jiang Y, Xu J, Yu J. Conducting polymeric nanoparticles synthesized in reverse micelles and their gas sensitivity based on quartz crystal microbalance. Polymer 2007;48:4459–4465
  41. Solmaz R. Electrochemical synthesis of poly-2-aminothiazole on mild steel and its corrosion inhibition performance. Prog. Org. Coat. 2011;70:122–126
  42. Diaz AF. Electrochemical preparation and characterization of conducting polymers. Chem. Scr., 1981;17:145-148
  43. Tourillon G, Garnier F. New Electrochemically generated organic conducting polymers. J. Electroanal. Chem.,1982;135:173-178
  44. Pringlea JM, Efthimiadisb J, Howletta PC, MacFarlanea DR, Chaplinc AB, Hallc SB, Officerc L, Wallaced GG, Forsyth M.Electrochemical synthesis of polypyrrole in ionic liquids. Polymer 2004;45:1447–1453
  45. Tüken T, Özyılmaz AT, Yazıcı B, Erbil M. Electrochemical synthesis of polyaniline on mild steel in acetonitrile–LiClO4 and corrosion performance. Appl. Surf. Sci. 2004;236:292–305
  46. Lakard B, Herlem G, Fahys B. Electrochemical polymerization of 1,2-ethanedithiol as a new way to synthesize polyethylenedisulfide. Polymer 2008;49:1743-1747
  47. Inzelt G.Conducting Polymers: A New Erain Electrochemistry, Springer, Berlin, 1987 (Chapter4)
  48. Malinauskas A.Electrocatalysis at conducting polymers. Synth. Met 1999;107:75-83
  49. Inzelt G, Pineri M, Schultze JW, Vorotyntsev MA. Electron and proton conducting polymers: recent developments and prospects. Electrochim. Acta 2000;45:2403-2421
  50. Solmaz R, Kardaş G. Electrochemical synthesis and characterization of poly-2-aminothiazole. Prog. Org. Coat. 2009;64:81–88
  51. Kardaş G, Solmaz R.Electrochemical synthesis and characterization of a new conducting polymer: Polyrhodanine. Appl. Surf. Sci. 2007;253:3402–3407
  52. Cutshall NS, Oday C, Prezhdo M. Rhodanine derivatives as inhibitors of JSP-1 Bioorg. Med. Chem. Lett. 2005;15:3374-3379
  53. Mishra S, Srivastava SK, Srivastava SD. Synthesis of 5-arylidene-2-aryl-3-(phenothiazino/benzotriazoloacetamidyl)-1,3-thiazolidine-4-ones as antiinflammatory, anticonvulsant, analgesic and antimicrobial agents. Indian J. Chem. Sect. B 1997;36:826-830
  54. Foye WO, Tovivich P. N-Glucopyranosyl-5-aralkylidenerhodanines: Synthesis and antibacterial and antiviral activities. J. Pharm. Sci. 1977;66:1607-1611
  55. Momose Y, Meguro K, Ikeda H, Hatanaka C, Oi S, Sohda T. Studies On Antidiabetic Agents.10. Synthesis And Biological-Activities Of Pioglitazone And Related-Compounds. Chem. Pharm. Bull. 1991; 39:1440-1445
  56. Sudo K, Matsumoto Y, Matsushima M, Fujiwara M, Konno K, Shimotohno K, Shigeta S, Yokota T. Novel Hepatitis C Virus Protease Inhibitors: Thiazolidine Derivatives. Biochem. Biophys. Res. Commun. 1997;238:643-647
  57. Habib NS, Rida SM, Badawey EAM, Fahmy HTY, Ghozlan HA. Synthesis and antimicrobial activity of rhodanine derivatives. Eur. J. Med. Chem. 1997;32:759-762
  58. Chandrakant GB, Gaikwad NJ. Synthesis and preliminary evaluation of some pyrazine containing thiazolines and thiazolidinones as antimicrobial agents. Bioorgan. Med. Chem. 2004;12:2151-2161
  59. Vittoria DM, Mazzoni O, Piscopo E, Caligmano A, Bolognese A.Synthesis and antihistaminic activity of some thiazolidin-4-ones. J.Med. Chem. 1992;35:2910-2912
  60. Sing W, Lee T, Yeo SL, Lim S, Sim P. Arylalkylidene rhodanine with bulky and hydrophobic functional group as selective HCV NS3 protease inhibitor. Bioorgan. Med. Chem. Lett. 2001;11:91-93
  61. Cutshall NS, O’Day C.Prezhdo Rhodanine derivatives as inhibitors of JSP-1. M. Bioorgan Med. Chem. Lett. 2005;15:3374–3379
  62. Altunbas E¸ Solmaz R, Kardas G. Corrosion behaviour of polyrhodanine coated copper electrode in 0.1 M H2SO4 solution. Mater. Chem. Phys. 2010;121:354–358
  63. Jabeen S, Rex A, Palmer BS, Potter M, Trevor JD, Babur ZC. Low Temperature Crystal Structures of Two Rhodanine Derivatives, 3-Amino Rhodanine and 3-Methyl Rhodanine: Geometry of the Rhodanine Ring. J Chem Crystallogr 2009;39:151–156
  64. Wessling B, Skotheim TA, Elsenbaumer RL, Reynolds JR. Editors, Handbook of conducting polymers, 2nd ed. New York: Marcel Dekker, 1998;p. 467
  65. Menon R, Yoon CO, Moses D, Heeger AJ. In: Skotheim TA, Elsenbaumer RL, Reynolds JR, editors. Handbook of conducting polymers,2nd ed. New York: Marcel Dekker,. 1998;p. 27
  66. Yuehong P, He X, Xiaoyu L, Hongliu D, Yuxiao C, Guoyue S. Electrochemical synthesis, characterization, and electrochromic properties of poly(3-chlorothiophene) and its copolymer with 3-methylthiophene in a room temperature ionic liquid. Electrochem. Commun. 2006;8:1757–1763
  67. Casas J, Castellano E, Macias A, Playa N, Sanchez A, Sordo J, Varela J, Lopez E. Methyl- and phenylmercury(II) complexes of 5-(4′-dimethylaminobenzylidene)rhodanine (HDABRd) and 5-(2′-thiophenomethylene)rhodanine (HTRd). The crystal and molecular structure of [HgPh(DABRd)] and [HgMe(TRd)]. Polyhedron 2001;20:1845-1850