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Dergiler / Turkish Journal of Analytical Chemistry / 2020 / Cilt: 2 - Sayı: 1

The new tetra substituted metallophthalocyanines bearing four Schiff bases on periphery: Synthesis, spectroscopic properties and investigation of the effect of various central metals on aggregation properties

Halise YALAZAN
Ayşe AKTAŞ KAMİLOĞLU
Halit KANTEKİN
Ümmühan OCAK
Sayfa
29–36
Yayın Tarihi
2020-06-23
DOI
—
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⚡ TL;DR(1 Cümlede Hızlı Çıkarım)

Aggregation properties of the obtained metallophthalocyanines were researched in polar and apolar solvents.

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Amaç & Hipotez:In the present study, new Schiff base compound (Z)-4-((quinolin-2-ylmethyleneamino)methyl)phenol (3), its phthalonitrile derivative (Z)-4-(4-((quinolin-2-ylmethyleneamino)methyl)phenoxy)phthalonitrile (4) were synthesized in the first step.
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Temel Bulgular & Veri:Then, zinc(II) (Pc‒5), cobalt(II) (Pc‒6) and copper(II) (Pc‒7) phthalocyanines containing Schiff base group with quinolin moiety on peripheral positions were synthesized.
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Sonuç & Katkı:Aggregation properties of the obtained metallophthalocyanines were researched in polar and apolar solvents.
🔬Tür:Araştırma Makalesi
📍Kapsam:Genişletilmiş Akademik Örneklem
⚙️Değişkenler:Aggregation · Metallophthalocyanine · Phthalocyanine

Abstract

In the present study, new Schiff base compound (Z)-4-((quinolin-2-ylmethyleneamino)methyl)phenol (3), its phthalonitrile derivative (Z)-4-(4-((quinolin-2-ylmethyleneamino)methyl)phenoxy)phthalonitrile (4) were synthesized in the first step. Then, zinc(II) (Pc‒5), cobalt(II) (Pc‒6) and copper(II) (Pc‒7) phthalocyanines containing Schiff base group with quinolin moiety on peripheral positions were synthesized. All new compounds were characterized by general spectroscopic techniques. Aggregation properties of the obtained metallophthalocyanines were researched in polar and apolar solvents.

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Bu Makaleye Atıf Yap

YALAZAN, H., KAMİLOĞLU, A. A., KANTEKİN, H., OCAK, Ü. (2020). The new tetra substituted metallophthalocyanines bearing four Schiff bases on periphery: Synthesis, spectroscopic properties and investigation of the effect of various central metals on aggregation properties. Turkish Journal of Analytical Chemistry, Cilt: 2 - Sayı: 1, 29–36. https://ajindex.com/articles/808293

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