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Journals / Turkish Journal of Analytical Chemistry / 2020 / Cilt: 2 - Sayı: 1

The new tetra substituted metallophthalocyanines bearing four Schiff bases on periphery: Synthesis, spectroscopic properties and investigation of the effect of various central metals on aggregation properties

Halise YALAZAN
Ayşe AKTAŞ KAMİLOĞLU
Halit KANTEKİN
Ümmühan OCAK
Pages
29–36
Publication Date
2020-06-23
DOI
—
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AI Summary & Key Takeaways

AI Insight
⚡ TL;DR(Too Long; Didn't Read)

Aggregation properties of the obtained metallophthalocyanines were researched in polar and apolar solvents.

📌 3 Key Takeaways

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Objective & Hypothesis:In the present study, new Schiff base compound (Z)-4-((quinolin-2-ylmethyleneamino)methyl)phenol (3), its phthalonitrile derivative (Z)-4-(4-((quinolin-2-ylmethyleneamino)methyl)phenoxy)phthalonitrile (4) were synthesized in the first step.
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Key Findings & Data:Then, zinc(II) (Pc‒5), cobalt(II) (Pc‒6) and copper(II) (Pc‒7) phthalocyanines containing Schiff base group with quinolin moiety on peripheral positions were synthesized.
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Conclusion & Impact:Aggregation properties of the obtained metallophthalocyanines were researched in polar and apolar solvents.
🔬Design:Research Article
📍Scope:Comprehensive Sample
⚙️Variables:Aggregation · Metallophthalocyanine · Phthalocyanine

Abstract

In the present study, new Schiff base compound (Z)-4-((quinolin-2-ylmethyleneamino)methyl)phenol (3), its phthalonitrile derivative (Z)-4-(4-((quinolin-2-ylmethyleneamino)methyl)phenoxy)phthalonitrile (4) were synthesized in the first step. Then, zinc(II) (Pc‒5), cobalt(II) (Pc‒6) and copper(II) (Pc‒7) phthalocyanines containing Schiff base group with quinolin moiety on peripheral positions were synthesized. All new compounds were characterized by general spectroscopic techniques. Aggregation properties of the obtained metallophthalocyanines were researched in polar and apolar solvents.

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Cite This Article

YALAZAN, H., KAMİLOĞLU, A. A., KANTEKİN, H., OCAK, Ü. (2020). The new tetra substituted metallophthalocyanines bearing four Schiff bases on periphery: Synthesis, spectroscopic properties and investigation of the effect of various central metals on aggregation properties. Turkish Journal of Analytical Chemistry, Cilt: 2 - Sayı: 1, 29–36. https://ajindex.com/articles/808293

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