Dergiler / Turkish Journal of Chemistry / 1999 / Cilt: 23 - Sayı: 2

An investigation of the formation mechanism of allene or alkyne in the 6, 7-benzobicyclo (3.2.1) octane system by deuterium labeling experiments

Sayfa
115–122
Yayın Tarihi
2022-11-04
DOI
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⚡ TL;DR(1 Cümlede Hızlı Çıkarım)

Reaction of 10 with potassium tert-butoxide yielded butoxyl ether 18 in which proton-deuterium exchange has occured.

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Amaç & Hipotez:In order to reveal the real intermediate in the base-promoted reaction of 1,3-bromo-4,4-dideuterio-6,7-benzobicyclo[3.2.1]octa-2,6-diene 10 was synthesized and its HBr elimination reaction studied.
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Temel Bulgular & Veri:In order to reveal the real intermediate in the base-promoted reaction of 1,3-bromo-4,4-dideuterio-6,7-benzobicyclo[3.2.1]octa-2,6-diene 10 was synthesized and its HBr elimination reaction studied.
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Sonuç & Katkı:Reaction of 10 with potassium tert-butoxide yielded butoxyl ether 18 in which proton-deuterium exchange has occured.
🔬Tür:Araştırma Makalesi
📍Kapsam:Genişletilmiş Akademik Örneklem
⚙️Değişkenler:Alan Parametreleri

Abstract

In order to reveal the real intermediate in the base-promoted reaction of 1,3-bromo-4,4-dideuterio-6,7-benzobicyclo[3.2.1]octa-2,6-diene 10 was synthesized and its HBr elimination reaction studied. Reaction of 10 with potassium tert-butoxide yielded butoxyl ether 18 in which proton-deuterium exchange has occured.

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Bu Makaleye Atıf Yap

TAŞKESENLİGİL, Y., BALCI, M., TÜMER, F., KAZAZ, C. (2022). An investigation of the formation mechanism of allene or alkyne in the 6, 7-benzobicyclo (3.2.1) octane system by deuterium labeling experiments. Turkish Journal of Chemistry, Cilt: 23 - Sayı: 2, 115–122. https://ajindex.com/articles/602512

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