Journals / Turkish Journal of Chemistry / 1999 / Cilt: 23 - Sayı: 2

An investigation of the formation mechanism of allene or alkyne in the 6, 7-benzobicyclo (3.2.1) octane system by deuterium labeling experiments

Pages
115–122
Publication Date
2022-11-04
DOI
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AI Summary & Key Takeaways

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⚡ TL;DR(Too Long; Didn't Read)

Reaction of 10 with potassium tert-butoxide yielded butoxyl ether 18 in which proton-deuterium exchange has occured.

📌 3 Key Takeaways

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Objective & Hypothesis:In order to reveal the real intermediate in the base-promoted reaction of 1,3-bromo-4,4-dideuterio-6,7-benzobicyclo[3.2.1]octa-2,6-diene 10 was synthesized and its HBr elimination reaction studied.
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Key Findings & Data:In order to reveal the real intermediate in the base-promoted reaction of 1,3-bromo-4,4-dideuterio-6,7-benzobicyclo[3.2.1]octa-2,6-diene 10 was synthesized and its HBr elimination reaction studied.
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Conclusion & Impact:Reaction of 10 with potassium tert-butoxide yielded butoxyl ether 18 in which proton-deuterium exchange has occured.
🔬Design:Research Article
📍Scope:Comprehensive Sample
⚙️Variables:Domain Parameters

Abstract

In order to reveal the real intermediate in the base-promoted reaction of 1,3-bromo-4,4-dideuterio-6,7-benzobicyclo[3.2.1]octa-2,6-diene 10 was synthesized and its HBr elimination reaction studied. Reaction of 10 with potassium tert-butoxide yielded butoxyl ether 18 in which proton-deuterium exchange has occured.

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Cite This Article

TAŞKESENLİGİL, Y., BALCI, M., TÜMER, F., KAZAZ, C. (2022). An investigation of the formation mechanism of allene or alkyne in the 6, 7-benzobicyclo (3.2.1) octane system by deuterium labeling experiments. Turkish Journal of Chemistry, Cilt: 23 - Sayı: 2, 115–122. https://ajindex.com/articles/602512

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