Journals / Turkish Journal of Chemistry / 2002 / Cilt: 26 - Sayı: 6

Bromination of Benzonorbornadiene Using a Mixture of Sodium Bromide and Sodium Perborate at High Temperatures

Pages
939–946
Publication Date
2002-06-01
DOI
—
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AI Summary & Key Takeaways

AI Insight
⚡ TL;DR(Too Long; Didn't Read)

However, at high temperatures, bromination resulted predominantly in the formation of rearranged solvolytic products whose formation mechanisms are discussed.

📌 3 Key Takeaways

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Objective & Hypothesis:Bromination of benzonorbornadiene (1) with sodium bromide in the presence of sodium perborate at room temperature gave only one product, the dibromide 2 produced via Wagner-Meerwein rearrangement.
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Key Findings & Data:Bromination of benzonorbornadiene (1) with sodium bromide in the presence of sodium perborate at room temperature gave only one product, the dibromide 2 produced via Wagner-Meerwein rearrangement.
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Conclusion & Impact:However, at high temperatures, bromination resulted predominantly in the formation of rearranged solvolytic products whose formation mechanisms are discussed.
🔬Design:Research Article
📍Scope:Comprehensive Sample
⚙️Variables:Bromination · benzonorbornadiene · high temperature bromination

Abstract

Bromination of benzonorbornadiene (1) with sodium bromide in the presence of sodium perborate at room temperature gave only one product, the dibromide 2 produced via Wagner-Meerwein rearrangement. However, at high temperatures, bromination resulted predominantly in the formation of rearranged solvolytic products whose formation mechanisms are discussed.

Özet

Bromination of benzonorbornadiene (1) with sodium bromide in the presence of sodium perborate at room temperature gave only one product, the dibromide 2 produced via Wagner-Meerwein rearrangement. However, at high temperatures, bromination resulted predominantly in the formation of rearranged solvolytic products whose formation mechanisms are discussed.

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Cite This Article

ŞENOCAK, E., TAŞKESENLİGİL, Y. (2002). Bromination of Benzonorbornadiene Using a Mixture of Sodium Bromide and Sodium Perborate at High Temperatures. Turkish Journal of Chemistry, Cilt: 26 - Sayı: 6, 939–946. https://ajindex.com/articles/393442

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