In 1, 1 opsp ligand acts in a bidentate mode with 2 nitrogen atoms from a pyridine ring and a pyrimidine ring coordinating to 2 Ag(I) atoms, and the Ag(I) center is 2-coordinated by 2 nitrogen atoms showing linear coordination geometry.
📌 3 Maddede Bu Makale
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Amaç & Hipotez:The new silver(I) complexe $[Ag_2(opsp_2](NO_3)_2$ (1) was synthesized by the self-assembly of AgX (X = $NO_3^-$) with the versatile multidentate ligand opsp (opsp = 2-[(o-pyridyl)-sulfanylmethyl]- pyrimidine).
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Temel Bulgular & Veri:X-ray single-crystal diffraction analyses show that 1 is dinuclear molecule.
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Sonuç & Katkı:In 1, 1 opsp ligand acts in a bidentate mode with 2 nitrogen atoms from a pyridine ring and a pyrimidine ring coordinating to 2 Ag(I) atoms, and the Ag(I) center is 2-coordinated by 2 nitrogen atoms showing linear coordination geometry.
🔬Tür:Araştırma Makalesi
📍Kapsam:Genişletilmiş Akademik Örneklem
⚙️Değişkenler:Alan Parametreleri
Abstract
The new silver(I) complexe $[Ag_2(opsp_2](NO_3)_2$ (1) was synthesized by the self-assembly of AgX (X = $NO_3^-$) with the versatile multidentate ligand opsp (opsp = 2-[(o-pyridyl)-sulfanylmethyl]- pyrimidine). X-ray single-crystal diffraction analyses show that 1 is dinuclear molecule. In 1, 1 opsp ligand acts in a bidentate mode with 2 nitrogen atoms from a pyridine ring and a pyrimidine ring coordinating to 2 Ag(I) atoms, and the Ag(I) center is 2-coordinated by 2 nitrogen atoms showing linear coordination geometry.
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Bu Makaleye Atıf Yap
LI, M., WEN, L., ZNAO, G., PINGKAI, O., ZHANG, S., LI, X. (2022). Synthesis and structural characterization of the 2-[(o-pyridyl)-sulfanylmethyl]-pyrimidine-silver(I) complex $[Ag_2(opsp_2](NO_3)_2$. Turkish Journal of Chemistry, Cilt: 29 - Sayı: 2, 193–197. https://ajindex.com/articles/602212
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