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Dergiler / Turkish Journal of Chemistry / 2007 / Cilt: 31 - Sayı: 1

A new and convenient method of generating alkyl isocyanates from alcohols, thiols, and trimethylsilyl ethers using a 2,4,6-trichloro [1,3,5] triazine/n-$Bu_4NOCN$

Batool AKHLAGHINIA
Sima SAMIEI
Sayfa
35–43
Yayın Tarihi
2022-11-05
DOI
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Yapay Zeka Hızlı Bakış & Çıkarımlar

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⚡ TL;DR(1 Cümlede Hızlı Çıkarım)

This method is highly selective for conversion of 1° alcohols to alkyl isocyanates in the presence of 2° and 3° alcohols, thiols, and trimethylsilyl ethers.

📌 3 Maddede Bu Makale

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Amaç & Hipotez:Alkyl isocyanates are prepared in good to excellent yields by treatment of alcohols, thiols, and trimethylsilyl ethers with 2,4,6-trichloro[l,3,5] triazine/n-Bu4NOCN in acetonitrile.
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Temel Bulgular & Veri:Alkyl isocyanates are prepared in good to excellent yields by treatment of alcohols, thiols, and trimethylsilyl ethers with 2,4,6-trichloro[l,3,5] triazine/n-Bu4NOCN in acetonitrile.
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Sonuç & Katkı:This method is highly selective for conversion of 1° alcohols to alkyl isocyanates in the presence of 2° and 3° alcohols, thiols, and trimethylsilyl ethers.
🔬Tür:Araştırma Makalesi
📍Kapsam:Genişletilmiş Akademik Örneklem
⚙️Değişkenler:Alan Parametreleri

Abstract

Alkyl isocyanates are prepared in good to excellent yields by treatment of alcohols, thiols, and trimethylsilyl ethers with 2,4,6-trichloro[l,3,5] triazine/n-Bu4NOCN in acetonitrile. This method is highly selective for conversion of 1° alcohols to alkyl isocyanates in the presence of 2° and 3° alcohols, thiols, and trimethylsilyl ethers.

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Bu Makaleye Atıf Yap

AKHLAGHINIA, B., SAMIEI, S. (2022). A new and convenient method of generating alkyl isocyanates from alcohols, thiols, and trimethylsilyl ethers using a 2,4,6-trichloro [1,3,5] triazine/n-$Bu_4NOCN$. Turkish Journal of Chemistry, Cilt: 31 - Sayı: 1, 35–43. https://ajindex.com/articles/602180

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