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Journals / Turkish Journal of Chemistry / 2007 / Cilt: 31 - Sayı: 1

A new and convenient method of generating alkyl isocyanates from alcohols, thiols, and trimethylsilyl ethers using a 2,4,6-trichloro [1,3,5] triazine/n-$Bu_4NOCN$

Batool AKHLAGHINIA
Sima SAMIEI
Pages
35–43
Publication Date
2022-11-05
DOI
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AI Summary & Key Takeaways

AI Insight
⚡ TL;DR(Too Long; Didn't Read)

This method is highly selective for conversion of 1° alcohols to alkyl isocyanates in the presence of 2° and 3° alcohols, thiols, and trimethylsilyl ethers.

📌 3 Key Takeaways

🎯
Objective & Hypothesis:Alkyl isocyanates are prepared in good to excellent yields by treatment of alcohols, thiols, and trimethylsilyl ethers with 2,4,6-trichloro[l,3,5] triazine/n-Bu4NOCN in acetonitrile.
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Key Findings & Data:Alkyl isocyanates are prepared in good to excellent yields by treatment of alcohols, thiols, and trimethylsilyl ethers with 2,4,6-trichloro[l,3,5] triazine/n-Bu4NOCN in acetonitrile.
💡
Conclusion & Impact:This method is highly selective for conversion of 1° alcohols to alkyl isocyanates in the presence of 2° and 3° alcohols, thiols, and trimethylsilyl ethers.
🔬Design:Research Article
📍Scope:Comprehensive Sample
⚙️Variables:Domain Parameters

Abstract

Alkyl isocyanates are prepared in good to excellent yields by treatment of alcohols, thiols, and trimethylsilyl ethers with 2,4,6-trichloro[l,3,5] triazine/n-Bu4NOCN in acetonitrile. This method is highly selective for conversion of 1° alcohols to alkyl isocyanates in the presence of 2° and 3° alcohols, thiols, and trimethylsilyl ethers.

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Cite This Article

AKHLAGHINIA, B., SAMIEI, S. (2022). A new and convenient method of generating alkyl isocyanates from alcohols, thiols, and trimethylsilyl ethers using a 2,4,6-trichloro [1,3,5] triazine/n-$Bu_4NOCN$. Turkish Journal of Chemistry, Cilt: 31 - Sayı: 1, 35–43. https://ajindex.com/articles/602180

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