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Dergiler / Turkish Journal of Chemistry / 2011 / Cilt: 35 - Sayı: 5

In situ catalytic activities of 1,3-dialkyltetrahydropyrimidinium salts/[$RuCl_2(p-cymene)]_2$ system for transfer hydrogenation reactions

Nevin GÜRBÜZ
İsmail ÖZDEMİR
Engin ÇETİNKAYA
Bekir ÇETİNKAYA
Emine Özge ÖZCAN
Deniz MERCAN
Sayfa
699–709
Yayın Tarihi
2022-11-05
DOI
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⚡ TL;DR(1 Cümlede Hızlı Çıkarım)

The in situ prepared 3 component 1,3- dialkyltetrahydropyrimidinium salts (LHX)/[$RuCl_2(p-cymene)]_2$ and KOH catalyzed quantitatively the transfer hydrogenation of ketones under mild reaction conditions in 2-propanol.

📌 3 Maddede Bu Makale

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Amaç & Hipotez:Hydrogen-transfer reduction processes are attracting increasing interest from synthetic chemists in view of their operational simplicity.
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Temel Bulgular & Veri:In the present study novel ruthenium carbene complexes were generated in situ and tested for their transfer hydrogenation reactions.
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Sonuç & Katkı:The in situ prepared 3 component 1,3- dialkyltetrahydropyrimidinium salts (LHX)/[$RuCl_2(p-cymene)]_2$ and KOH catalyzed quantitatively the transfer hydrogenation of ketones under mild reaction conditions in 2-propanol.
🔬Tür:Araştırma Makalesi
📍Kapsam:Genişletilmiş Akademik Örneklem
⚙️Değişkenler:Alan Parametreleri

Abstract

Hydrogen-transfer reduction processes are attracting increasing interest from synthetic chemists in view of their operational simplicity. In the present study novel ruthenium carbene complexes were generated in situ and tested for their transfer hydrogenation reactions. The in situ prepared 3 component 1,3- dialkyltetrahydropyrimidinium salts (LHX)/[$RuCl_2(p-cymene)]_2$ and KOH catalyzed quantitatively the transfer hydrogenation of ketones under mild reaction conditions in 2-propanol.

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Bu Makaleye Atıf Yap

GÜRBÜZ, N., ÖZDEMİR, İ., ÇETİNKAYA, E., ÇETİNKAYA, B., ÖZCAN, E. Ö., MERCAN, D. (2022). In situ catalytic activities of 1,3-dialkyltetrahydropyrimidinium salts/[$RuCl_2(p-cymene)]_2$ system for transfer hydrogenation reactions. Turkish Journal of Chemistry, Cilt: 35 - Sayı: 5, 699–709. https://ajindex.com/articles/602103

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