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Journals / Turkish Journal of Chemistry / 2011 / Cilt: 35 - Sayı: 5

In situ catalytic activities of 1,3-dialkyltetrahydropyrimidinium salts/[$RuCl_2(p-cymene)]_2$ system for transfer hydrogenation reactions

Nevin GÜRBÜZ
İsmail ÖZDEMİR
Engin ÇETİNKAYA
Bekir ÇETİNKAYA
Emine Özge ÖZCAN
Deniz MERCAN
Pages
699–709
Publication Date
2022-11-05
DOI
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AI Summary & Key Takeaways

AI Insight
⚡ TL;DR(Too Long; Didn't Read)

The in situ prepared 3 component 1,3- dialkyltetrahydropyrimidinium salts (LHX)/[$RuCl_2(p-cymene)]_2$ and KOH catalyzed quantitatively the transfer hydrogenation of ketones under mild reaction conditions in 2-propanol.

📌 3 Key Takeaways

🎯
Objective & Hypothesis:Hydrogen-transfer reduction processes are attracting increasing interest from synthetic chemists in view of their operational simplicity.
📊
Key Findings & Data:In the present study novel ruthenium carbene complexes were generated in situ and tested for their transfer hydrogenation reactions.
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Conclusion & Impact:The in situ prepared 3 component 1,3- dialkyltetrahydropyrimidinium salts (LHX)/[$RuCl_2(p-cymene)]_2$ and KOH catalyzed quantitatively the transfer hydrogenation of ketones under mild reaction conditions in 2-propanol.
🔬Design:Research Article
📍Scope:Comprehensive Sample
⚙️Variables:Domain Parameters

Abstract

Hydrogen-transfer reduction processes are attracting increasing interest from synthetic chemists in view of their operational simplicity. In the present study novel ruthenium carbene complexes were generated in situ and tested for their transfer hydrogenation reactions. The in situ prepared 3 component 1,3- dialkyltetrahydropyrimidinium salts (LHX)/[$RuCl_2(p-cymene)]_2$ and KOH catalyzed quantitatively the transfer hydrogenation of ketones under mild reaction conditions in 2-propanol.

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Cite This Article

GÜRBÜZ, N., ÖZDEMİR, İ., ÇETİNKAYA, E., ÇETİNKAYA, B., ÖZCAN, E. Ö., MERCAN, D. (2022). In situ catalytic activities of 1,3-dialkyltetrahydropyrimidinium salts/[$RuCl_2(p-cymene)]_2$ system for transfer hydrogenation reactions. Turkish Journal of Chemistry, Cilt: 35 - Sayı: 5, 699–709. https://ajindex.com/articles/602103

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