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Dergiler / Turkish Journal of Chemistry / 2015 / Cilt: 39 - Sayı: 6

Synthesis of new thiol-derivatized aminophosphines and their catalytic activities in C{C coupling reactions

Nermin BİRİCİK
Nermin MERİÇ
Cezmi KAYAN
Bahattin GÜMGÜM
Zeynep ÖZGEN
Sevil ŞEKER AZİZOĞLU
Sayfa
1257–1264
Yayın Tarihi
2022-11-05
DOI
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Yapay Zeka Hızlı Bakış & Çıkarımlar

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⚡ TL;DR(1 Cümlede Hızlı Çıkarım)

Compounds 4b and 4c were proved to be excellent catalysts for Suzuki and Heck cross-coupling reactions.

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Amaç & Hipotez:A series of new aminophosphines [Ph 2 PHN-C 6 H 4 -R, where R = o -SH ( 4a ), m -SH ( 4b) or p -SH ( 4c )] were readily synthesized from cheap starting materials by the phosphorylation reaction of o , m , and p -aminothiophenols with Ph 2 PCl in the presence of triethyl amine.
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Temel Bulgular & Veri:The new compounds were characterized by NMR and IR spectroscopy and microanalysis.
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Sonuç & Katkı:Compounds 4b and 4c were proved to be excellent catalysts for Suzuki and Heck cross-coupling reactions.
🔬Tür:Araştırma Makalesi
📍Kapsam:Genişletilmiş Akademik Örneklem
⚙️Değişkenler:Alan Parametreleri

Abstract

A series of new aminophosphines [Ph 2 PHN-C 6 H 4 -R, where R = o -SH ( 4a ), m -SH ( 4b) or p -SH ( 4c )] were readily synthesized from cheap starting materials by the phosphorylation reaction of o , m , and p -aminothiophenols with Ph 2 PCl in the presence of triethyl amine. The new compounds were characterized by NMR and IR spectroscopy and microanalysis. In addition, aminophosphine ligands{palladium systems were investigated as precatalysts in C{C coupling reactions. Compounds 4b and 4c were proved to be excellent catalysts for Suzuki and Heck cross-coupling reactions.

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Bu Makaleye Atıf Yap

BİRİCİK, N., MERİÇ, N., KAYAN, C., GÜMGÜM, B., ÖZGEN, Z., AZİZOĞLU, S. Ş. (2022). Synthesis of new thiol-derivatized aminophosphines and their catalytic activities in C{C coupling reactions. Turkish Journal of Chemistry, Cilt: 39 - Sayı: 6, 1257–1264. https://ajindex.com/articles/588844

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Kaynakça (25)

  1. Dewana, A.; Buragohaina, Z.; Mondala, M.; Sarmaha, G.; Boraha, G.; Bora, U. Appl. Organometal. Chem. 2014, 28, 230{233
  2. Pongracz, P.; Kostas, I. D.; Kollar, L. J. Organomet. Chem. 2013, 723, 149{153
  3. Priyaa, S.; Balakrishna, M. S.; Mobin, S. M.; McDonald, R. J. Organomet. Chem. 2003, 688, 227{235
  4. Dolinsky, M. C. B.; Lin, W. O.; Dias, M. L. J. Mol. Catal. A: Chem. 2006, 258, 267{274
  5. Ly, T. Q.; Woollins, J. D. Coord. Chem. Rev. 1998, 176, 451{481
  6. Fei, Z.; Dyson, P. J. Coord. Chem. Rev. 2005, 249, 2056{2074
  7. Ghisol, A.; Fliedel, C.; Rosa, V.; Monakhov, K. Y.; Braunstein, P. Organometallics 2014, 33, 2523{2534
  8. Nakajima, T.; Fukushima, Y.; Tsuji, M.; Hamada, N.; Kure, B.; Tanase, T. Organometallics 2013, 32, 7470{7477
  9. Cimarelli, C.; Fratoni, D.; Palmieri, G. Tetrahedron: Asymmetry 2009, 20, 2234{2239
  10. Saikia, B.; Boruah, P. R.; Ali, A. A.; Sarma, D. Tetrahedron Lett. 2015, 6, 633{635 11. Naik, S.; Kumaravel, M.; Mague, J. T.; Balakrishna, M. S. Dalton Trans. 2014, 43, 1082{1095
  11. Gaw, K. G.; Smith, M. B.; Wright, J. B.; Slawin, A. M. Z.; Coles, S. J.; Hursthouse, M. B.; Tizzard, G. J. J. Organomet. Chem. 2012, 699, 39{47
  12. Lamblin, M.; Nassar-Hardy, L.; Hierso, J. C.; Fouquet, E.; Felpin, F. X. Adv. Synth. Catal. 2010, 352, 33{79
  13. Bolliger, J. L.; Frech, C. M. Adv. Synth. Catal. 2010, 352, 1075{1080
  14. Bolliger, J. L.; Frech, C. M. Chima 2009, 63, 23{28
  15. Miyaruna, N.; Suzuki, A. Chem. Rev. 1995, 95, 2457{2483
  16. Whitcombe, N. J.; Hii, K. K.; Gibson, S. E. Tetrahedron 2001, 57, 7449{7476
  17. Seechurn, C. C. C. J.; Kitching, M. O.; Colacot, T. J.; Snieckus, V. Angew. Chem. Int. Ed. 2012, 51, 5062{5085. 19
  18. Fei, Z.; Scopelliti, R.; Dyson, P. J. Dalton Trans. 2003, 2772{2279
  19. Fei, Z.; Paunescu, E.; Ang, W. H.; Scopelliti, R.; Dyson, P. J. Eur. J. Inorg. Chem. 2014, 1745{1750
  20. Biricik, N.; Durap, F.; Kayan, C.; Gumgum, B. Heteroatom Chem. 2007, 18, 613{616
  21. Biricik, N.; Durap, F.; Gumgum, B; Fei, Z.; Scopelliti, R. Trans. Met. Chem. 2007, 32, 877{883
  22. Zhao, D.; Fei, Z.; Ang, W. H. Cent. Eur. J. Chem. 2008, 6, 93{98
  23. Biricik, N.; Kayan, C.; Gumgum, B.; Fei, Z.; Scopelliti, R.; Dyson, P. J.; Gurbuz, N.; Ozdemir, I. Inorg. Chim. Acta 2010, 363, 1039{1047
  24. Kayan, C.; Biricik, N.; Aydemir, M.; Scopelliti, R. Inorg. Chim. Acta 2012, 385, 164{169
  25. Gaw, K. G.; Smith, M. B.; Slawin, A. M. Z. New J. Chem. 2000, 24, 429{435. 27.