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AI Summary & Key Takeaways
AI Insight⚡ TL;DR(Too Long; Didn't Read)
Compounds 4b and 4c were proved to be excellent catalysts for Suzuki and Heck cross-coupling reactions.
📌 3 Key Takeaways
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Objective & Hypothesis:A series of new aminophosphines [Ph 2 PHN-C 6 H 4 -R, where R = o -SH ( 4a ), m -SH ( 4b) or p -SH ( 4c )] were readily synthesized from cheap starting materials by the phosphorylation reaction of o , m , and p -aminothiophenols with Ph 2 PCl in the presence of triethyl amine.
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Key Findings & Data:The new compounds were characterized by NMR and IR spectroscopy and microanalysis.
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Conclusion & Impact:Compounds 4b and 4c were proved to be excellent catalysts for Suzuki and Heck cross-coupling reactions.
🔬Design:Research Article
📍Scope:Comprehensive Sample
⚙️Variables:Domain Parameters
Abstract
A series of new aminophosphines [Ph 2 PHN-C 6 H 4 -R, where R = o -SH ( 4a ), m -SH ( 4b) or p -SH ( 4c )] were readily synthesized from cheap starting materials by the phosphorylation reaction of o , m , and p -aminothiophenols with Ph 2 PCl in the presence of triethyl amine. The new compounds were characterized by NMR and IR spectroscopy and microanalysis. In addition, aminophosphine ligands{palladium systems were investigated as precatalysts in C{C coupling reactions. Compounds 4b and 4c were proved to be excellent catalysts for Suzuki and Heck cross-coupling reactions.
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Cite This Article
BİRİCİK, N., MERİÇ, N., KAYAN, C., GÜMGÜM, B., ÖZGEN, Z., AZİZOĞLU, S. Ş. (2022). Synthesis of new thiol-derivatized aminophosphines and their catalytic activities in C{C coupling reactions. Turkish Journal of Chemistry, Cilt: 39 - Sayı: 6, 1257–1264. https://ajindex.com/articles/588844