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Dergiler / Turkish Journal of Chemistry / 2006 / Cilt: 30 - Sayı: 2

Synthesis and Crystal Structure of 1,3-Bis(5-formylpyrrol-2-yl)benzene and Its Conversion to a Macrocyclic Derivative

M. Kasım ŞENER
David SANCHEZ-GARCIA
Mehmet AKKURT
Sayfa
243–251
Yayın Tarihi
2006-02-01
DOI
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⚡ TL;DR(1 Cümlede Hızlı Çıkarım)

The present bisformylpyrrole derivative 2 provides a new precursor that may be useful in the synthesis of new, functional macrocyclic systems.

📌 3 Maddede Bu Makale

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Amaç & Hipotez:This report details the synthesis and characterization of a new diformyl pyrrole derivative 2 and its macrocyclic derivative 3.
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Temel Bulgular & Veri:The new compounds were characterized by FT-IR, 13C NMR, and 1H NMR spectroscopies and via mass spectrometric analysis.
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Sonuç & Katkı:The present bisformylpyrrole derivative 2 provides a new precursor that may be useful in the synthesis of new, functional macrocyclic systems.
🔬Tür:Araştırma Makalesi
📍Kapsam:Genişletilmiş Akademik Örneklem
⚙️Değişkenler:Schiff Base · Bisformylpyrrole · Macrocycle

Özet

This report details the synthesis and characterization of a new diformyl pyrrole derivative 2 and its macrocyclic derivative 3. The new compounds were characterized by FT-IR, 13C NMR, and 1H NMR spectroscopies and via mass spectrometric analysis. The structure of 2 in the solid state was determined using X-ray diffraction methods (monoclinic, P21/c, a = 17.3760(7), b = 4.9719(2), c = 15.5374(5) Å, b = 105.892(2) °, V = 1291.00(9) Å3, and Z = 4). The molecular structure is stabilized by N-H...O and C-H...O intermolecular hydrogen bonds. The present bisformylpyrrole derivative 2 provides a new precursor that may be useful in the synthesis of new, functional macrocyclic systems.

Abstract

This report details the synthesis and characterization of a new diformyl pyrrole derivative 2 and its macrocyclic derivative 3. The new compounds were characterized by FT-IR, 13C NMR, and 1H NMR spectroscopies and via mass spectrometric analysis. The structure of 2 in the solid state was determined using X-ray diffraction methods (monoclinic, P21/c, a = 17.3760(7), b = 4.9719(2), c = 15.5374(5) Å, b = 105.892(2) °, V = 1291.00(9) Å3, and Z = 4). The molecular structure is stabilized by N-H...O and C-H...O intermolecular hydrogen bonds. The present bisformylpyrrole derivative 2 provides a new precursor that may be useful in the synthesis of new, functional macrocyclic systems.

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Bu Makaleye Atıf Yap

ŞENER, M. K., SANCHEZ-GARCIA, D., AKKURT, M. (2006). Synthesis and Crystal Structure of 1,3-Bis(5-formylpyrrol-2-yl)benzene and Its Conversion to a Macrocyclic Derivative. Turkish Journal of Chemistry, Cilt: 30 - Sayı: 2, 243–251. https://ajindex.com/articles/220578

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Kaynakça (15)

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