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Journals / Turkish Journal of Chemistry / 2006 / Cilt: 30 - Sayı: 2

Synthesis and Crystal Structure of 1,3-Bis(5-formylpyrrol-2-yl)benzene and Its Conversion to a Macrocyclic Derivative

M. Kasım ŞENER
David SANCHEZ-GARCIA
Mehmet AKKURT
Pages
243–251
Publication Date
2006-02-01
DOI
—
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AI Summary & Key Takeaways

AI Insight
⚡ TL;DR(Too Long; Didn't Read)

The present bisformylpyrrole derivative 2 provides a new precursor that may be useful in the synthesis of new, functional macrocyclic systems.

📌 3 Key Takeaways

🎯
Objective & Hypothesis:This report details the synthesis and characterization of a new diformyl pyrrole derivative 2 and its macrocyclic derivative 3.
📊
Key Findings & Data:The new compounds were characterized by FT-IR, 13C NMR, and 1H NMR spectroscopies and via mass spectrometric analysis.
💡
Conclusion & Impact:The present bisformylpyrrole derivative 2 provides a new precursor that may be useful in the synthesis of new, functional macrocyclic systems.
🔬Design:Research Article
📍Scope:Comprehensive Sample
⚙️Variables:Schiff Base · Bisformylpyrrole · Macrocycle

Abstract

This report details the synthesis and characterization of a new diformyl pyrrole derivative 2 and its macrocyclic derivative 3. The new compounds were characterized by FT-IR, 13C NMR, and 1H NMR spectroscopies and via mass spectrometric analysis. The structure of 2 in the solid state was determined using X-ray diffraction methods (monoclinic, P21/c, a = 17.3760(7), b = 4.9719(2), c = 15.5374(5) Å, b = 105.892(2) °, V = 1291.00(9) Å3, and Z = 4). The molecular structure is stabilized by N-H...O and C-H...O intermolecular hydrogen bonds. The present bisformylpyrrole derivative 2 provides a new precursor that may be useful in the synthesis of new, functional macrocyclic systems.

Özet

This report details the synthesis and characterization of a new diformyl pyrrole derivative 2 and its macrocyclic derivative 3. The new compounds were characterized by FT-IR, 13C NMR, and 1H NMR spectroscopies and via mass spectrometric analysis. The structure of 2 in the solid state was determined using X-ray diffraction methods (monoclinic, P21/c, a = 17.3760(7), b = 4.9719(2), c = 15.5374(5) Å, b = 105.892(2) °, V = 1291.00(9) Å3, and Z = 4). The molecular structure is stabilized by N-H...O and C-H...O intermolecular hydrogen bonds. The present bisformylpyrrole derivative 2 provides a new precursor that may be useful in the synthesis of new, functional macrocyclic systems.

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Cite This Article

ŞENER, M. K., SANCHEZ-GARCIA, D., AKKURT, M. (2006). Synthesis and Crystal Structure of 1,3-Bis(5-formylpyrrol-2-yl)benzene and Its Conversion to a Macrocyclic Derivative. Turkish Journal of Chemistry, Cilt: 30 - Sayı: 2, 243–251. https://ajindex.com/articles/220578

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