Oxidation of crotyl alcohol by N-chloro-4-methylbenzene sulphonamide in acidic medium and in alkaline media in the presence of os(VIII) catalyst-a kinetic pathway

Amaç & Hipotez:The kinetic pathway of oxidation of crotyl alcohol by sodium salt of N-chloro-4-methylbenzene sulphonamide (chloramine-T) in acidic and alkaline medium has been studied.

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Temel Bulgular & Veri:The speciation of chloramine-T has been made to suggest a proper and reasonable reaction mechanism.

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Sonuç & Katkı:An anticipated reaction mechanism has been suggested.

🔬Tür:Araştırma Makalesi

📍Kapsam:Genişletilmiş Akademik Örneklem

⚙️Değişkenler:transfer reaction · reaction kinetics · mechanism

Abstract

The kinetic pathway of oxidation of crotyl alcohol by sodium salt of N-chloro-4-methylbenzene sulphonamide (chloramine-T) in acidic and alkaline medium has been studied. The speciation of chloramine-T has been made to suggest a proper and reasonable reaction mechanism. The thermodynamic quantities such as activation energy and activation entropy are evaluated in acidic as well as in catalysed alkaline medium. An anticipated reaction mechanism has been suggested.

Anahtar kelimeler

transfer reaction reaction kinetics mechanism osmium(VIII) catalysis crotyl alcohol chloramine- T

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Bu Makaleye Atıf Yap

SHARMA, P., SAİLANİ, R., MEENA, A., KHANDELWAL, C. L. (2020). Oxidation of crotyl alcohol by N-chloro-4-methylbenzene sulphonamide in acidic medium and in alkaline media in the presence of os(VIII) catalyst-a kinetic pathway. Turkish Journal of Chemistry, Cilt: 44 - Sayı: 4, 950–970. https://ajindex.com/articles/214919

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Kaynakça (5)

Bansal S, 2001, J CHEM RES, V6. Bishop E., 1958,
TALANTA, V1, P197, DOI DOI 10.1016/0039-9140(58)80034-X CAMPBELL MM, 1978, CHEM REV, V78, P65, DOI 10.1021/cr60311a005 Davies LJ, 2001, J MOL CATAL A-CHEM, V165, P243, DOI 10.1016/S1381-1169(00)00430-1 Dikshitulu LSA, 2009, PROGR REACTION KINET, V34, P97126, DOI [10.3184/146867809X452587s, DOI 10.3184/146867809X452587S] Friedrich HB, 2000, TETRAHEDRON LETT, V41, P3971, DOI 10.1016/S0040-4039(00)00531-1 GRIFFITH WP, 1964, J CHEM SOC, P245, DOI 10.1039/jr9640000245 HIGUCHI T, 1968, J CHEM SOC B, P1031, DOI 10.1039/j29680001031 HUSSAIN J, 1991, J CHEM SOC DALTON, P89, DOI 10.1039/dt9910000089 Jagadeesh RV, 2008, J PHYS ORG CHEM, V21, P844, DOI 10.1002/poc.1379 Kambo N, 2004, INDIAN J CHEM A, V43. Kolthoff IM, 1957, VOLUMETRIC ANAL, V3. Latshaw M., 1925, J AM CHEM SOC, V47. Lee AF, 2007, J PHYS CHEM C, V111, P18844, DOI 10.1021/jp709944c Low K, 2018, CHEM COMMUN, V54, DOI 10.1039/c8cc02012d Meenakshi KM, 2009, E-J CHEM, V6, P545, DOI 10.1155/2009/149032 Mohan K, 2008, INDIAN J CHEM A, V47, P1226 MORRIS JC, 1948, J AM CHEM SOC, V70, P2036, DOI 10.1021/ja01186a016 Nagaraju P, 2008, CATAL COMMUN, V9, P1389, DOI 10.1016/j.catcom.2007.11.038 Puttaswamy, 2006, IND ENG CHEM RES, V45, P1563, DOI 10.1021/ie0509746 Rangappa KS, 2002, INT J CHEM KINET, V34, P49, DOI 10.1002/kin.10011 RAO VRS, 1970,
TALANTA, V17, P770, DOI 10.1016/0039-9140(70)80166-7 Rosch F., 2011, RADIOCHEMISTRY RADIO. Sailani R, 2014, B KOREAN CHEM SOC, V35, P111, DOI 10.5012/bkcs.2014.35.1.111 SAUERBRUNN RD, 1953, J AM CHEM SOC, V75, P4170, DOI 10.1021/ja01113a012 Senger HGS, 1966, J INDIAN CHEM SOC, V43 SHARMA N, 1990,
TETRAHEDRON, V46, P2845. SHARMA N, 1992, B CHEM SOC JPN, V65, P1125, DOI 10.1246/bcsj.65.1125 Sharma P, 2020, J CHEM RES, V44, P295, DOI 10.1177/1747519819900622 Sharma P, 2018, INT J CHEM KINET, V50, P335, DOI 10.1002/kin.21162 Sharma P, 2018, TURK J CHEM, V42, P158, DOI 10.3906/kim-1701-32 Shetty M, 2004, Z NATURFORSCH A, V59, P6368 Singh G, 2011, INT J CURRENT CHEM, V2. Sopper FG, 1924,
J CHEM SOC, DOI 10.1039/CT9242501899 Wu GM, 2006, J MEMBRANE SCI, V275, P127, DOI 10.1016/j.memsci.2005.09.012