Dergiler / Turkish Journal of Chemistry / 2018 / Cilt: 42 - Sayı: 1

Kinetics of silver(I)-catalyzed oxidation of allyl alcohol by peroxodiphosphate in acetate buffers

Sayfa
158–169
Yayın Tarihi
2018-02-01
DOI
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The energy and entropy of activation have also been evaluated by employing Eyring plots.

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Amaç & Hipotez:The kinetics and mechanism of silver(I)-catalyzed oxidation of allyl alcohol with peroxodiphosphate in acetate buffers have been studied.
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Temel Bulgular & Veri:The rate is independent of allyl alcohol concentration.
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Sonuç & Katkı:The energy and entropy of activation have also been evaluated by employing Eyring plots.
🔬Tür:Araştırma Makalesi
📍Kapsam:Genişletilmiş Akademik Örneklem
⚙️Değişkenler:Kinetics · mechanism · oxidation

Abstract

The kinetics and mechanism of silver(I)-catalyzed oxidation of allyl alcohol with peroxodiphosphate in acetate buffers have been studied. The rate is independent of allyl alcohol concentration. The effect of other reaction parameters such as hydrogen and acetate ions has also been studied. The rate law accounting for all experimental observations corresponds to the proposed mechanism. The energy and entropy of activation have also been evaluated by employing Eyring plots.

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Bu Makaleye Atıf Yap

SHARMA, P., SAILANI, R., PAREEK, D., KHANDELWAL, C. L. (2018). Kinetics of silver(I)-catalyzed oxidation of allyl alcohol by peroxodiphosphate in acetate buffers. Turkish Journal of Chemistry, Cilt: 42 - Sayı: 1, 158–169. https://ajindex.com/articles/184513

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