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Yapay Zeka Hızlı Bakış & Çıkarımlar
AI Insight⚡ TL;DR(1 Cümlede Hızlı Çıkarım)
This procedure also provides a supplement to Cu and Pd catalyzed acylation of diorganozincs.
📌 3 Maddede Bu Makale
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Amaç & Hipotez:Nano-NiO catalyzed acylation of mixed (methyl)(aryl)zincs with aromatic acyl halides in THF at room temperature provides a new facile route for aryl-aroyl coupling.
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Temel Bulgular & Veri:Among NiCl$_{2}$.L$_{2}$ and NiCl$_{2}$.L (L = monodentate and bidentate phosphine ligand) catalysts, the lower catalyst loading of NiCl$_{2}$ (dppf) may seem attractive; however, nano-NiO, being the lowest cost catalyst, is more favorable for aroylation of (methyl)(aryl)zincs.
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Sonuç & Katkı:This procedure also provides a supplement to Cu and Pd catalyzed acylation of diorganozincs.
🔬Tür:Araştırma Makalesi
📍Kapsam:Genişletilmiş Akademik Örneklem
⚙️Değişkenler:Mixed diorganozincs · acylation · nickel catalyst
Abstract
Nano-NiO catalyzed acylation of mixed (methyl)(aryl)zincs with aromatic acyl halides in THF at room temperature provides a new facile route for aryl-aroyl coupling. Among NiCl$_{2}$.L$_{2}$ and NiCl$_{2}$.L (L = monodentate and bidentate phosphine ligand) catalysts, the lower catalyst loading of NiCl$_{2}$ (dppf) may seem attractive; however, nano-NiO, being the lowest cost catalyst, is more favorable for aroylation of (methyl)(aryl)zincs. This procedure also provides a supplement to Cu and Pd catalyzed acylation of diorganozincs.
Anahtar kelimeler
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Bu Makaleye Atıf Yap
PEKEL, Ö. Ö., ERDİK, E., KALKAN, M. (2018). Synthesis of some ketones via nano-nickel oxide catalyzed acylation of arylzinc reagents; strategy involving the use of mixed (methyl)(aryl)zincs. Turkish Journal of Chemistry, Cilt: 42 - Sayı: 3, 759–767. https://ajindex.com/articles/184433