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Dergiler / Turkish Journal of Chemistry / 2018 / Cilt: 42 - Sayı: 3

Synthesis of some ketones via nano-nickel oxide catalyzed acylation of arylzinc reagents; strategy involving the use of mixed (methyl)(aryl)zincs

Melike KALKAN
Özgen ÖMÜR PEKEL
Ender ERDİK
Sayfa
759–767
Yayın Tarihi
2022-11-05
DOI
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⚡ TL;DR(1 Cümlede Hızlı Çıkarım)

This procedure alsoprovides a supplement to Cu and Pd catalyzed acylation of diorganozincs.

📌 3 Maddede Bu Makale

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Amaç & Hipotez:Nano-NiO catalyzed acylation of mixed (methyl)(aryl)zincs with aromatic acyl halides in THF at roomtemperature provides a new facile route for aryl–aroyl coupling.
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Temel Bulgular & Veri:Among NiCl 2 .L2 and NiCl 2 .L (L = monodentateand bidentate phosphine ligand) catalysts, the lower catalyst loading of NiCl 2 (dppf) may seem attractive; however,nano-NiO, being the lowest cost catalyst, is more favorable for aroylation of (methyl)(aryl)zincs.
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Sonuç & Katkı:This procedure alsoprovides a supplement to Cu and Pd catalyzed acylation of diorganozincs.
🔬Tür:Araştırma Makalesi
📍Kapsam:Genişletilmiş Akademik Örneklem
⚙️Değişkenler:Alan Parametreleri

Abstract

Nano-NiO catalyzed acylation of mixed (methyl)(aryl)zincs with aromatic acyl halides in THF at roomtemperature provides a new facile route for aryl–aroyl coupling. Among NiCl 2 .L2 and NiCl 2 .L (L = monodentateand bidentate phosphine ligand) catalysts, the lower catalyst loading of NiCl 2 (dppf) may seem attractive; however,nano-NiO, being the lowest cost catalyst, is more favorable for aroylation of (methyl)(aryl)zincs. This procedure alsoprovides a supplement to Cu and Pd catalyzed acylation of diorganozincs.

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Bu Makaleye Atıf Yap

KALKAN, M., PEKEL, Ö. Ö., ERDİK, E. (2022). Synthesis of some ketones via nano-nickel oxide catalyzed acylation of arylzinc reagents; strategy involving the use of mixed (methyl)(aryl)zincs. Turkish Journal of Chemistry, Cilt: 42 - Sayı: 3, 759–767. https://ajindex.com/articles/601758

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