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Dergiler / Ata-Kimya Dergisi / 2026 / Cilt: 6 Sayı: 1

Yeni Bor İçerikli Aromatik Ditiyofosfonato Nikel(II) Kompleksi: Sentez ve Yapı Aydınlatılması

New Boron-containing Aromatic Dithiophosphonato Nickel(II) Complex: Synthesis and Structure Elucidation

Elif Bulat(MARMARA ÜNİVERSİTESİ)0000-0002-2164-3641
İrem Aldemir(MARMARA ÜNİVERSİTESİ)0009-0000-4316-2876
Ertuğrul Gazi Sağlam(MARMARA ÜNİVERSİTESİ, FEN FAKÜLTESİ, KİMYA BÖLÜMÜ)0000-0002-7719-3934
Sayfa
21–27
Yayın Tarihi
2026-06-14
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⚡ TL;DR(1 Cümlede Hızlı Çıkarım)

Yeni kompleksin yapısı element analizi, FTIR ve 31P NMR analiz yöntemleriyle açıklandı.

📌 3 Maddede Bu Makale

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Amaç & Hipotez:Bilinen bir trans-[O-1-fenil-1-propil-(4-metoksifenil)ditiyofosfonato] nikel(II) dört koordinasyonlu kompleksinin difenilfosfino etanla (dppe), kovalent yapıdaki kompleksi sentezlendi ([(dppe)Ni(L)]). [(dppe)Ni(L)] ara ürünün, tetrafenilborat anyonuyla iyonik yapıda, yeni bor içerikli aromatik ditiyofosfonato Ni(II) kompleksi sentezlendi ([(dppe)Ni(L)]+[BPh4]-).
📊
Temel Bulgular & Veri:Bilinen bir trans-[O-1-fenil-1-propil-(4-metoksifenil)ditiyofosfonato] nikel(II) dört koordinasyonlu kompleksinin difenilfosfino etanla (dppe), kovalent yapıdaki kompleksi sentezlendi ([(dppe)Ni(L)]). [(dppe)Ni(L)] ara ürünün, tetrafenilborat anyonuyla iyonik yapıda, yeni bor içerikli aromatik ditiyofosfonato Ni(II) kompleksi sentezlendi ([(dppe)Ni(L)]+[BPh4]-).
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Sonuç & Katkı:Yeni kompleksin yapısı element analizi, FTIR ve 31P NMR analiz yöntemleriyle açıklandı.
🔬Tür:Araştırma Makalesi
📍Kapsam:Genişletilmiş Akademik Örneklem
⚙️Değişkenler:Ditiyofosfonik asitler · Fosfonoditiyoato Ni(II) kompleksleri · Bor Kompleksleri

Özet

Bilinen bir trans-[O-1-fenil-1-propil-(4-metoksifenil)ditiyofosfonato] nikel(II) dört koordinasyonlu kompleksinin difenilfosfino etanla (dppe), kovalent yapıdaki kompleksi sentezlendi ([(dppe)Ni(L)]). [(dppe)Ni(L)] ara ürünün, tetrafenilborat anyonuyla iyonik yapıda, yeni bor içerikli aromatik ditiyofosfonato Ni(II) kompleksi sentezlendi ([(dppe)Ni(L)]+[BPh4]-). Yeni kompleksin yapısı element analizi, FTIR ve 31P NMR analiz yöntemleriyle açıklandı.

Abstract

Trans-[O-1-phenyl-1-propyl-(4-methoxyphenyl)dithiophosphonato] nickel(II) four-coordination complex which is known previously with diphenylphosphino ethane (dppe) was synthesised ([(dppe)Ni(L)], covalent structure). A new boron-containing aromatic dithiophosphonato Ni(II) complex of the [(dppe)Ni(L)] intermediate product with tetraphenylborate anion was synthesised ([(dppe)Ni(L)]+[BPh4]-) as ionic form. The structure of the new complex was elucidated by elemental analysis, FTIR and 31P NMR analysis methods.

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Bu Makaleye Atıf Yap

Bulat, E., Aldemir, İ., Sağlam, E. G. (2026). Yeni Bor İçerikli Aromatik Ditiyofosfonato Nikel(II) Kompleksi: Sentez ve Yapı Aydınlatılması. Ata-Kimya Dergisi, Cilt: 6 Sayı: 1, 21–27. https://doi.org/10.62425/atakim.1916651

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