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Journals / International Journal of Chemistry and Technology / 2020 / Cilt: 4 - Sayı: 1

Eco-friendly synthesis of nano copper and its use in fenton-like reactions for methylene blue degradation

Demet Demirci GÜLTEKİN
Azize ALAYLI
Hayrunnisa NADAROGLU
Pages
71–78
Publication Date
2020-06-30
DOI
—
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AI Summary & Key Takeaways

AI Insight
⚡ TL;DR(Too Long; Didn't Read)

Moreover, this study showed that reagents were reusable, inexpensive, biocompatible, easy to prepare, harmless (CuO NPs, H2O2), and Fenton-like reaction conditions were created.

📌 3 Key Takeaways

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Objective & Hypothesis:Copper oxide nanoparticles (CuO NPs) were produced using green synthesis method with Cimin grape extract (Vitis vinifera cv.).
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Key Findings & Data:Experimental parameters for MB removal were selected as: pH: 3 – 11; Temp: 20 - 80°C; initial MB concentration (15 - 50 ml-1), and CuO NPs concentrations (25 - 800 mg ml-1).
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Conclusion & Impact:Moreover, this study showed that reagents were reusable, inexpensive, biocompatible, easy to prepare, harmless (CuO NPs, H2O2), and Fenton-like reaction conditions were created.
🔬Design:Research Article
📍Scope:Comprehensive Sample
⚙️Variables:Copper oxide nanoparticles · fenton-like · methylene blue

Abstract

Copper oxide nanoparticles (CuO NPs) were produced using green synthesis method with Cimin grape extract (Vitis vinifera cv.). The produced CuO NPs were used to remove methylene blue (MB) from water by degradation with Fenton-like reactions. The surface properties of the CuO NPs were determined by FT-IR, SEM and XRD techniques. Experimental parameters for MB removal were selected as: pH: 3 – 11; Temp: 20 - 80°C; initial MB concentration (15 - 50 ml-1), and CuO NPs concentrations (25 - 800 mg ml-1). The best reaction conditions were found to be pH: 7 - 11, temperature: 40 - 45C, interaction time: 120 min, initial MB concentration: 3.125 mg ml-1 and CuO NPs concentration: 25 mg ml-1. Under these conditions, CuO NPs showed a 97.80% efficacy for the removal of MB from wastewater with Fenton-like process. Moreover, this study showed that reagents were reusable, inexpensive, biocompatible, easy to prepare, harmless (CuO NPs, H2O2), and Fenton-like reaction conditions were created.

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Cite This Article

GÜLTEKİN, D. D., ALAYLI, A., NADAROGLU, H. (2020). Eco-friendly synthesis of nano copper and its use in fenton-like reactions for methylene blue degradation. International Journal of Chemistry and Technology, Cilt: 4 - Sayı: 1, 71–78. https://ajindex.com/articles/765681

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References (24)

  1. Sen, T. Int. J. Environ. Pollut. Control Manage. 2011, 3 (1), 1-10
  2. Bombardelli, E.; Morazzoni, P. Fitoterapia (Milano). 1995, 66 (4), 291-317
  3. Fan, P.; Lou, H.; Yu, W.; Ren, D.; Ma, B.; Ji, M. Tetrahedron Lett. 2004, 45 (15), 3163-3166
  4. Królikowska, A.; Kudelski, A.; Michota, A.; Bukowska. J. Surf. Sci. 2003, 532, 227-232
  5. Catauro, M.; Raucci, M. G.; De Gaetano, F.; Marotta, A. J. Mater. Sci-Mater. M. 2004, 15 (7), 831-837
  6. Crabtree, J. H.; Burchette, R. J.; Siddiqi, R. A.; Huen I. T.; Hadnott, L. L.; Fishman, A. Periton. Dialysis Int. 2003, 23 (4), 368-374
  7. Sharma, V. K.; Yngard, R. A.; Lin, Y. Adv. Colloid Interfac. 2009, 145 (1-2), 83-96
  8. Balantrapu, K.; Goia, D. V. J. Mater. Res. 2009, 24 (9), 2828-2836
  9. Taleb, A.; Petit, C.; Pileni, M. P. Chem. Mater. 1997, 9 (4), 950-959
  10. Begum, N. A.; Mondal, S.; Basu, S.; Laskar, R. A.; Mandal, D. Colloid Surface B. 2009, 71 (1), 113-118
  11. He, S.; Guo, Z.; Zhang, Y.; Zhang, S.; Wang, J.; Gu, N. Mater. Lett. 2007, 61 (18), 3984-3987
  12. Roy, K. Green’Synthesis of Silver Nanoparticles by using Grape (Vitis Vinifera) Fruit Extract: Characterization of the Particles and Study of Antibacterial Activity. PhD Dissertation, Indian Institute of Technology, Kharagpur, 2012
  13. Robinson, T.; Chandran, B.; Nigam, P. Enzyme Microb. Tech. 2001, 29 (8-9), 575-579. 14. de Campos Ventura-Camargo B.; Marin-Morales, M. A. Text. Light Ind. Sci. Technol. 2013, 2 (2), 85-103
  14. Correia, V. M.; Stephenson, T.; Judd, S. J. Environ. Technol. 1994, 15 (10), 917-929
  15. Wesenberg, D.; Kyriakides I.; Agathos, S. N. Biotechnol. Adv. 2003, 22 (1-2), 161-187
  16. De Moraes, S. G.; Freire, R. S.; Duran, N. Chemosphere 2000, 40 (4), 369-373
  17. Celebi, N.; Nadaroglu, H.; Kalkan, E.; Kotan R. Arch. Environ. Prot. 2016, 42 (4), 58-69
  18. Hoffmann, M. R.; Martin, S. T.; Choi, W.; Bahnemann DW. Chem. Rev. 1995, 95 (1), 69-96
  19. Pérez, M.; Torrades, F.; Garcı́a-Hortal, J. A.; Domènech, X.; Peral, J. Appl. Catal. B- Environ. 2002, 36 (1), 63-74
  20. Nadaroglu, H.; Kalkan, E.; Celik, H. Inter. J. Environ. Sci. Technol. 2015, 12 (6), 2079-2090
  21. Alaton, I. A.; Balcioglu, I. A.; Bahnemann, D. W. Water Res. 2002, 36 (5), 1143-1154
  22. Neamtu, M.; Siminiceanu, I.; Yediler, A.; Kettrup, A. Dyes Pigments 2002, 53 (2), 93-99
  23. Solmaz, S. K.; Birgül, A.; Üstün, G. E.; Yonar, T. Color. Technol. 2006, 122 (2), 102-109
  24. Deng, J.; Jiang, J.; Zhang, Y.; Lin, X.; Du, C.; Xiong, Y. Appl. Catal. B- Environ. 2008, 84