Journals / International Journal of Agriculture Forestry and Life Sciences / 2020 / Cilt: 4 - Sayı: 1

Rapid detection of green pea adulteration in ground pistachio nuts using near and mid-infrared spectroscopy

Pages
71–78
Publication Date
2020-06-23
DOI
—
🏛️Bibliographic metadata and full text access for this article are provided via DergiPark.
DergiPark Record ↗
✨

AI Summary & Key Takeaways

AI Insight
⚡ TL;DR(Too Long; Didn't Read)

These results showed that the NIR-based models provided a distinct advantage over MIR-ATR-based models in accurately estimating the ratio of the dried green pea seeds in binary mixtures.

📌 3 Key Takeaways

🎯
Objective & Hypothesis:Near-infrared (NIR) diffuse reflectance and Mid-infrared-attenuated total reflectance (MIR-ATR) spectroscopy were evaluated to determine the dried green pea seed adulteration in ground pistachio nuts.
📊
Key Findings & Data:Sixty-three samples (51 for calibration and 12 for external validation sets) of ground pistachio nuts were deliberately adulterated with varying levels of dried green pea seeds (ranging from 0 to 50% (w/w)).
💡
Conclusion & Impact:These results showed that the NIR-based models provided a distinct advantage over MIR-ATR-based models in accurately estimating the ratio of the dried green pea seeds in binary mixtures.
🔬Design:Modeling & Simulation
📍Scope:Comprehensive Sample
⚙️Variables:Adulteration · chemometrics · green pea

Abstract

Near-infrared (NIR) diffuse reflectance and Mid-infrared-attenuated total reflectance (MIR-ATR) spectroscopy were evaluated to determine the dried green pea seed adulteration in ground pistachio nuts. Sixty-three samples (51 for calibration and 12 for external validation sets) of ground pistachio nuts were deliberately adulterated with varying levels of dried green pea seeds (ranging from 0 to 50% (w/w)). Subsequently, both NIR and MIR-ATR spectra of the samples were collected separately. The quantitative predictions of green pea ratio in the samples were achieved using PLSR (Partial Least Squares Regression). Based on the PLSR models, SEP (Standard error of prediction) values of the models were 2.55 and 9.14% for NIR and MIR-ATR, respectively. The rPred (Correlation coefficient of prediction) values of the models were 0.99 and 0.80 for NIR and MIR-ATR, respectively. Additionally, the nondimensional values of RPD (Residual Predictive Deviation) for NIR and MIR-ATR spectra were calculated as 5.7 and 1.6, respectively. These results showed that the NIR-based models provided a distinct advantage over MIR-ATR-based models in accurately estimating the ratio of the dried green pea seeds in binary mixtures. Therefore, NIR spectroscopy has the potential and could be implemented in the routine applications of green pea detection in ground pistachio nuts.

🔖

Cite This Article

TEMİZKAN, R., DOĞAN, M. A., ATAKAN, O., NAZLIM, B. A., AYVAZ, H. (2020). Rapid detection of green pea adulteration in ground pistachio nuts using near and mid-infrared spectroscopy. International Journal of Agriculture Forestry and Life Sciences, Cilt: 4 - Sayı: 1, 71–78. https://ajindex.com/articles/765485

📄 Full Text PDF Viewer

📄

PDF görüntüleyici hazırlanıyor...

References (11)

  1. Aboul-Enein, Y., Bunaciu, A., & Fleschin, S. (2014). Evaluation of the protein secondary structures using Fourier Transform Infrared Spectroscopy. Gazi University Journal of Science, 27(1), 637-644.
  2. Asensio, L., González, I., García, T., & Martín, R. (2008). Determination of food authenticity by enzyme-linked immunosorbent assay (ELISA). Food Control, 19(1), 1-8.
  3. Barth, A. (2007). Infrared spectroscopy of proteins. Biochimica et Biophysica Acta (BBA)-Bioenergetics, 1767(9), 1073-1101. Bulló, M., Juanola-Falgarona, M., Hernández-Alonso, P., & Salas-Salvadó, J. (2015). Nutrition attributes and health effects of pistachio nuts. British Journal of Nutrition, 113(S2), S79-S93. Cautela, D., Laratta, B., Santelli, F., Trifirò, A., Servillo, L., & Castaldo, D. (2008). Estimating bergamot juice adulteration of lemon juice by high-performance liquid chromatography (HPLC) analysis of flavanone glycosides. Journal of Agricultural and Food Chemistry, 56(13), 5407-5414.
  4. Çağlar, A., Tomar, O., Vatansever, H., & Ekmekçi, E. (2017). Antepfıstığı (Pistacia vera L.) ve insan sağlığı üzerine etkileri. Akademik Gıda, 15(4), 436-447.
  5. Çavuş, F., Us, M. F., & Güzelsoy, N. A. Assesing Pistachio Nut (Pistacia vera L.) Adulteration with Green Pea (Pisum sativum L.) by Untargeted Liquid Chromatography-(quadrupole-time of flight)-Mass Spectrometry Method and Chemometrics. Gıda ve Yem Bilimi Teknolojisi Dergisi, (19), 34-41.
  6. Chavan, U. D., Shahidi, F., Bal, A. K., & McKenzie, D. B. (1999). Physico-chemical properties and nutrient composition of beach pea (Lathyrus maritimus L.). Food Chemistry, 66(1), 43-50.
  7. Cuadrado, M. U., De Castro, M. L., Juan, P. P., & Gómez-Nieto, M. A. (2005). Comparison and joint use of near infrared spectroscopy and Fourier transform mid infrared spectroscopy for the determination of wine parameters. Talanta, 66(1), 218-224.
  8. Dreher, M. L. (2012). Pistachio nuts: composition and potential health benefits. Nutrition reviews, 70(4), 234-240.
  9. Eksi-Kocak, H., Mentes-Yilmaz, O., & Boyaci, I. H. (2016). Detection of green pea adulteration in pistachio nut granules by using Raman hyperspectral imaging. European Food Research and Technology, 242(2), 271-277.
  10. Guo, H., Kimura, T., & Furutani, Y. (2013). Distortion of the amide-I and-II bands of an α-helical membrane protein, pharaonis halorhodopsin, depends on thickness of gold films utilized for surface-enhanced infrared absorption spectroscopy. Chemical Physics, 419, 8-16.
  11. Htoon, A., Shrestha, A. K., Flanagan, B. M., L