Journals / Hittite Journal of Science and Engineering / 2017 / Cilt: 4 - Sayı: 2

Biosorption Behaviour of an Arid Land Plant, Euphorbia Rigida, Towards to Heavy Metals: Equilibrium, Kinetic and Thermodynamic Studies

Pages
105–115
Publication Date
2022-10-18
DOI
—
🏛️Bibliographic metadata and full text access for this article are provided via DergiPark.
DergiPark Record ↗
✨

AI Summary & Key Takeaways

AI Insight
⚡ TL;DR(Too Long; Didn't Read)

Experimental results showed that E. rigida can be used as an alternative and effective low cost biosorbent for the removal of heavy metals from aqueous solutions

📌 3 Key Takeaways

🎯
Objective & Hypothesis:T he potential of an arid-land plant, Euphorbia rigida E. rigida , for the removal of heavy metals [Pb II , Zn II , Cu II , Cd II , Ni II ] from aqueous solutions was studied in the current work.
📊
Key Findings & Data:The affinities of metal ions onto E. rigida decreased as Pb II > Zn II > Cd II > Cu II > Ni II in single metal biosorption.
💡
Conclusion & Impact:Experimental results showed that E. rigida can be used as an alternative and effective low cost biosorbent for the removal of heavy metals from aqueous solutions
🔬Design:Modeling & Simulation
📍Scope:Comprehensive Sample
⚙️Variables:Euphorbia rigida · Single-multi heavy metal biosorption · Equilibrium

Abstract

T he potential of an arid-land plant, Euphorbia rigida E. rigida , for the removal of heavy metals [Pb II , Zn II , Cu II , Cd II , Ni II ] from aqueous solutions was studied in the current work. Batch sorption experiments were conducted to investigate the effects of pH, particle size, initial metal ion concentration, contact time and temperature. Besides, biosorption data was analysed by different isotherm and kinetic models. Equilibrium studies showed that the biosorption closely follows the Langmuir and Freundlich isotherms. From the kinetic point of view, pseudo-second order model gave the best fitting with the experimental results. The evaluated thermodynamic parameters showed that biosorption onto E. rigida was a feasible, spontaneous and endothermic process. The affinities of metal ions onto E. rigida decreased as Pb II > Zn II > Cd II > Cu II > Ni II in single metal biosorption. Besides, binary and ternary metal sorption studies were conducted to investigate the co-ion effect. Experimental results showed that E. rigida can be used as an alternative and effective low cost biosorbent for the removal of heavy metals from aqueous solutions

🔖

Cite This Article

KILIÇ, M., ÖZSİN, G., PÜTÜN, A. E., APAYDIN-VAROL, E. (2022). Biosorption Behaviour of an Arid Land Plant, Euphorbia Rigida, Towards to Heavy Metals: Equilibrium, Kinetic and Thermodynamic Studies. Hittite Journal of Science and Engineering, Cilt: 4 - Sayı: 2, 105–115. https://ajindex.com/articles/538080

📄 Full Text PDF Viewer

📄

PDF görüntüleyici hazırlanıyor...

References (13)

  1. Runtti H, Tuomikoski S, Kangas T, Lassi U, Kuokkanen T, Rämö J. Chemically activated carbon residue from biomass gasification as a sorbent for iron(II), copper(II) and nickel(II) ions. Journal of Water Process Engineering 4 (2014) 12-24
  2. Uzun I, Güzel F. Adsorption of some heavy metal ions from aqueous solution by activated carbon and comparison of percent adsorption results of activated carbon with those of some other adsorbents. Turkish Journal of Chemisty 24 (3) (2000) 291-298
  3. Xing Y, Yang P, Yu J. Biosorption of Pb (II) by the shell of vivipaird snail: Implications for heavy metal bioremediation. Separation Science and Technology 51(17) (2016) 2756- 2761
  4. Al-Shannag M, Al-Qodah Z, Bani-Melhem K, Qtaishat MR, Alkasrawi M. Heavy metal ions removal from metal plating wastewater using electrocoagulation: Kinetic study and process performance. Chemical Engineering Journal 260 (2015) 749-756
  5. Arpa Ç, Say R, Şatıroğlu N, Bektaş S, Yürüm Y, Genç Ö. Heavy metal removal from aquatic systems by northern Anatolian smectites. Turkish Journal of Chemisty 24 (2) (2000) 209- 215
  6. Hankins N, Hilal N, Ogunbiyi OO, Azzopardi B. Inverted polarity micellar enhanced ultrafiltration for the treatment of heavy metal polluted wastewater. Desalination 185 (1) (2005) 185-202
  7. Demiral İ, Şamdan CA. Removal of Methylene Blue with Activated Carbon Obtained from Pumpkin Seed Shell. Journal of Turkish Chemical Society Section A: Chem. 2 (3) (2015) 25-28
  8. Oladoja NA, Ahmad A. Gastropod shell as a precursor for the synthesis of binary alkali-earth and transition metal oxide for Cr(VI) abstraction from aqua system. Separation and Purification Technology 116 (2013) 230-239
  9. Khan ASA. Evaluation of thermodynamic parameters of cadmium adsorption on sand from Temkin adsorption isotherm. Turkish Journal of Chemisty 36 (3) (2012) 437- 443
  10. Machado RM, Correia MJN, Carvalho JMR. Integrated process for biosorption of copper from liquid effluents using grape stalks. Separation Science and Technology 38 (10) (2003) 2237-2254
  11. Reddy DHK, Lee SM, Seshaiah K. Biosorption of toxic heavy metal ions from water environment using honeycomb biomass-an industrial waste material. Water, Air, & Soil Pollution 223 (9) (2012) 5967-5982
  12. Jacques RA, Lima EC, Dias SLP, Mazzocato AC, Pavan FA. Yellow passion-fruit shell as biosorbent to remove Cr(III) and Pb(II) from aqueous solution. Separation and Purification Technology 57(1) (2007) 193-198
  13. Semerjian L.