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Journals / Hacettepe Journal of Biology and Chemistry / 2017 / Cilt: 45 - Sayı: 4

Chemical Oxidation of 5-Amino Quinoline with (NH4)2S2O8: Synthesis and Characterization

5-Amino Kinolinin (NH4)2 S2 O8 ile Kimyasal Oksidasyonu: Sentez ve Karakterizasyon

Ali BİLİCİ
Pages
563–571
Publication Date
2022-10-17
DOI
—
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AI Summary & Key Takeaways

AI Insight
⚡ TL;DR(Too Long; Didn't Read)

Spectral analysis results indicated the formation of phenazine like units in the oxidation product and C3, C6, C8 positions of quinoline ring were suggested as a possible polymerization sites.

📌 3 Key Takeaways

🎯
Objective & Hypothesis:5-amino quinoline (AQ) was chemically oxidized in (NH4)2S2O8/HCI system, whose structure was identified by UV-vis, FTIR, 1 HNMR and 13CNMR analysis.
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Key Findings & Data:Spectral analysis results indicated the formation of phenazine like units in the oxidation product and C3, C6, C8 positions of quinoline ring were suggested as a possible polymerization sites.
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Conclusion & Impact:OAQ was thermally stable and half of its mass was decomposed at 1000ºC.
🔬Design:Research Article
📍Scope:Comprehensive Sample
⚙️Variables:Domain Parameters

Abstract

5-amino quinoline (AQ) was chemically oxidized in (NH4)2S2O8/HCI system, whose structure was identified by UV-vis, FTIR, 1 HNMR and 13CNMR analysis. Spectral analysis results indicated the formation of phenazine like units in the oxidation product and C3, C6, C8 positions of quinoline ring were suggested as a possible polymerization sites. Size exclusion chromatography indicated the oxidation product (OAQ) consisted of oligomeric units (1200 g/mol). OAQ was thermally stable and half of its mass was decomposed at 1000ºC.

Özet

5-amino kinolin monomeri (NH4)2S2O8/HCI varlığında kimyasal olarak yükseltgendi. Elde edilen oksidasyon ürününün (OAQ) yapısı, UV-vis, FTIR, 1 HNMR ve 13CNMR analizleri ile aydınlatıldı. Spektral analizler sonucunda oksidasyon ürünün yapısında fenazin birimlerinin bulunduğu ve momomerik birimlerin birbirleri ile 3,6 ve 8 pozisyonları ile birleştiği belirlendi. Büyüklükçe ayırma tekniği, ürünün oligomerik birimlerden oluştuğunu gösterdi. OAQ ısısal bozunmaya karşı dayanıklıdır. Yarı bozunma sıcaklığının 1000ºC olduğu belirlendi.

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Cite This Article

BİLİCİ, A. (2022). Chemical Oxidation of 5-Amino Quinoline with (NH4)2S2O8: Synthesis and Characterization. Hacettepe Journal of Biology and Chemistry, Cilt: 45 - Sayı: 4, 563–571. https://ajindex.com/articles/529096

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