Journals / Gazi Üniversitesi Mühendislik Mimarlık Fakültesi Dergisi / 2018 / Cilt: 33 - Sayı: 4

Preparation of polyvinyl alcohol composite nanofibers and solid-phase photocatalytic degradation of polyvinyl alcohol

Polivinil alkol kompozit nanoliflerin hazırlanması ve katı-faz polivinil alkolün fotokatalitik bozunması

Pages
1411–1418
Publication Date
2022-10-18
DOI
—
🏛️Bibliographic metadata and full text access for this article are provided via DergiPark.
DergiPark Record ↗
✨

AI Summary & Key Takeaways

AI Insight
⚡ TL;DR(Too Long; Didn't Read)

In addition, the solid-phase photocatalytic degradation efficiency of the composite nanofibers was significantly higher than that of pure PVA nanofibers under UV irradiation.

📌 3 Key Takeaways

🎯
Objective & Hypothesis:In this study, polyvinyl alcohol (PVA) nanofibers including titanium dioxide (TiO2) and carbon nanotubes (CNT) nanoparticles were prepared using the electrospinning process.
📊
Key Findings & Data:TiO2 and CNT nanoparticles were confirmed to be introduced in the PVA nanofibers through FTIR spectroscopy and thermogravimetric analysis (TGA).
💡
Conclusion & Impact:In addition, the solid-phase photocatalytic degradation efficiency of the composite nanofibers was significantly higher than that of pure PVA nanofibers under UV irradiation.
🔬Design:Research Article
📍Scope:Comprehensive Sample
⚙️Variables:Domain Parameters

Abstract

In this study, polyvinyl alcohol (PVA) nanofibers including titanium dioxide (TiO2) and carbon nanotubes (CNT) nanoparticles were prepared using the electrospinning process. The solid-phase photocatalytic degradation of the composite nanofibers under UV light irradiation was investigated and compared with that of the pure PVA nanofibers with the aid of weight loss measurements. TiO2 and CNT nanoparticles were confirmed to be introduced in the PVA nanofibers through FTIR spectroscopy and thermogravimetric analysis (TGA). According to SEM analysis, PVA nanofibers showed tendency to decrease in diameter with TiO2 and CNT contributions. In addition, the solid-phase photocatalytic degradation efficiency of the composite nanofibers was significantly higher than that of pure PVA nanofibers under UV irradiation.

Özet

Bu çalışmada, titanium dioksit (TiO2) ve karbon nanotüp (CNT) nanopartikülleri içeren polivinil alkol (PVA)nanolifler, elektroeğirme yöntemi ile hazırlanmıştır. Kompozit nanoliflerin UV radyasyonu altındaki katıfazfotokatalitik bozunma özelliği, ağırlık kaybı ölçümleri ile incelenmiştir ve saf PVA nanoliflerinfotokatalitik özelliği ile karşılaştırılmıştır. FTIR spektroskopi ve termogravimetrik analizleri kullanılarak,TiO2 and CNT nanopartiküllerinin PVA nanolif yapısına katıldığı tespit edilmiştir. SEM analizine göre, TiO2and CNT katkısı ile PVA nanoliflerin çaplarında incelme eğilimi görülmüştür. Ayrıca, PVA nanolifler ilekarşılaştırıldığında, kompozit nanoliflerin UV radyasyonu altındaki katı-faz fotokatalitik bozunma verimidaha yüksektir.

🔖

Cite This Article

KÖYSÜREN, Ö., KÖYSÜREN, H. N. (2022). Preparation of polyvinyl alcohol composite nanofibers and solid-phase photocatalytic degradation of polyvinyl alcohol. Gazi Üniversitesi Mühendislik Mimarlık Fakültesi Dergisi, Cilt: 33 - Sayı: 4, 1411–1418. https://ajindex.com/articles/523527

📄 Full Text PDF Viewer

📄

PDF görüntüleyici hazırlanıyor...

References (12)

  1. Barakat A.M., Kumar R., Photocatalytic Activity Enhancement of Titanium Dioxide Nanoparticles Degradation of Pollutants in Wastewater, Springer, New York, A.B.D., 2016.
  2. He C.H., Gong J., The preparation of PVA–Pt/TiO2 composite nanofiber aggregate and the photocatalytic degradation of solid-phase polyvinyl alcohol, Polym. Degrad. Stabil., 81 (1), 117-124, 2003.
  3. Zan L., Fa W., Wang S., Novel Photodegradable LowDensity Polyethylene-TiO2 Nanocomposite Film, Environ. Sci. Technol., 40 (5), 1681-1685, 2006.
  4. Ajmi K., Vismara E., Manai I., Haddad M., Hamdi M., Bouallagui H., Polyvinyl acetate processing wastewater treatment using combined Fenton's reagent and fungal consortium: Application of central composite design for conditions optimization, J. Hazard. Mater., 358, 243- 255, 2018.
  5. Madaeni S.S., Ghaemi N., Rajabi H., Advances in Polymeric membranes for water treatment, Advances in Membrane Technologies for Water Treatment: Materials, Processes and Applications, Editör: Basile A., Cassano A., Rastogi N.K., Elsevier, Cambridge, UK, 2015.
  6. Karaca G., Taşdemir Y., Removal of Polycyclic Aromatic Hydrocarbons (PAHs) from Organized Industry District Treatment Sludges with Photochemical Degradation: Ambient Air Applications, Journal of the Faculty of Engineering and Architecture of Gazi University, 30 (4), 557-565, 2015.
  7. Saez M.R., Jaramillo L.Y., Saravanan R., Benito N., Pabon E., Mosquera E., Gracia F., Notable photocatalytic activity of TiO2-polyethylene nanocomposites for visible light degradation of organic pollutants, Express Poly. Lett., 11 (11), 899-909, 2017.
  8. Yew S.P., Tang H.Y., Sudesh K., Photocatalytic activity and biodegradation of polyhydroxybutyrate films containing titanium dioxide, Polym. Degrad. Stabil., 91 (8), 1800-1807, 2006.
  9. Cantarella M., Sanz R., Buccheri M.A., Ruffino F., Rappazzo G., Scalese S., Impellizzeri G., Romano L., Privitera V., Immobilization of nanomaterials in PMMA composites for photocatalytic removal of dyes, phenols and bacteria from water, J. Photoch. Photobio. A, 321, 1–11, 2016.
  10. Yang L., Zhou S., Wu L., Preparation of waterborne self-cleaning nanocomposite coatings based on TiO2/PMMA latex, Prog. Org. Coat., 85, 208–215, 2015.
  11. Piewnuan C., Wootthikanokkhan J., Ngaotrakanwiwat P., Meeyoo V., Chiarakorn S., Preparation of TiO2/(TiO2–V2O5)/polypyrrole nanocomposites and a study on catalytic activities of the hybrid materials under UV/Visible light and in the dark, Superlattice. Microst., 75, 105–117, 2014.
  12. Zan L., Tian L., Liu Z.