SavedAdd your journal

Journals / Gazi Üniversitesi Fen Bilimleri Enstitüsü Dergisi / 2001 / Cilt: 14 - Sayı: 2

Synthesis and crystal structure of a heterobinuclear Ni-Cd complex, { Bis-N, N-dimethylformamide-$mu$- [ N, N-bis(salicylidene)1,3-propanedi amine ] nickel (II) } dichloro cadmium (II)

Sefa DURMUŞ
Orhan ATAKOL
Leyla TATAR
Zehra DURMUŞ
Kaan C. EMREGÜL
Pages
541–551
Publication Date
2022-10-18
DOI
—
🏛️Bibliographic metadata and full text access for this article are provided via DergiPark.
DergiPark Record ↗
✨

AI Summary & Key Takeaways

AI Insight
⚡ TL;DR(Too Long; Didn't Read)

Two symmetrical identical units in the unit cell were observed as one molecule.

📌 3 Key Takeaways

🎯
Objective & Hypothesis:In this study, N,N'-bis(salicylidene)-l,3propanediamine was used as ligand and its Ni(II) complexes were prepared.
📊
Key Findings & Data:Non-aqueous Ni(lI)-Cd(II) heterodinuclear complexes with cadmium chloride were also prepared in non-aqueous media.
💡
Conclusion & Impact:Two symmetrical identical units in the unit cell were observed as one molecule.
🔬Design:Research Article
📍Scope:Comprehensive Sample
⚙️Variables:Domain Parameters

Abstract

In this study, N,N'-bis(salicylidene)-l,3propanediamine was used as ligand and its Ni(II) complexes were prepared. Non-aqueous Ni(lI)-Cd(II) heterodinuclear complexes with cadmium chloride were also prepared in non-aqueous media. The structure of the complexes were investigated using x-ray diffaction and some analytical spectroscopic methods. Two symmetrical identical units in the unit cell were observed as one molecule.

Özet

Çalışmada, N,N'-bis(salisiliden)-l,3-propandiamin ligand olarak kullanıldı ve nikel(II) ile kompleksi hazırlandı. Sonra kadmiyum klorür ile susuz ortamlarda Ni(II)-Cd(II) heterodinükleer kompleksi sentezlendi. X-ışınları diffraksiyonu yöntemleri ve spektroskopik bazı yöntemlerle yapısı aydınlatıldı. Birim hücrede iki simetrik molekül bulunmakta ve tek bir molekül gibi gözlenmektedir.

🔖

Cite This Article

DURMUŞ, S., ATAKOL, O., TATAR, L., DURMUŞ, Z., EMREGÜL, K. C. (2022). Synthesis and crystal structure of a heterobinuclear Ni-Cd complex, { Bis-N, N-dimethylformamide-$mu$- [ N, N-bis(salicylidene)1,3-propanedi amine ] nickel (II) } dichloro cadmium (II). Gazi Üniversitesi Fen Bilimleri Enstitüsü Dergisi, Cilt: 14 - Sayı: 2, 541–551. https://ajindex.com/articles/522417

References (1)

  1. C.Kalbach and F.M. Mann. Phys. Rev. C, 23, 112(1981) 2.M.Blann,Phys. Rev. Lett., vol. 27, No:6 337 (1971) 3.M;Blann,Phys. Rev. Lett., vol. 28, No: 12 757 (1972) 4.M.Blann,and J. Bisplinghoff,''Code ALICE/LIVERMORE 82,"UCİD-19614,Lawrance Livermore National Laboratory (Nov. 5 1982) 5.V. McLane, CSISRS experimental nuclear data file,National Nuclear Data Center, Brookhaven National Laboratory (1997). 6.J.R. Wu, C. C. Chang.and H.D. Holmgren, Phys. Rev. C, 19 698(1979) 7.F.E. Bertrand and K.W. Peele, Rev., 8, 1045 (1973) 8.M.Lambert, S.Benckj I.Slypen, V. Corcalciuc, and J. P. Meulders,"Comparison of Fast Neutron Induced Light Charged Particle Production Cross Sections for Science and technology,Trieste,Italy, May 19-24, 1997, p. 1516, G. RefFo, Ed., ENEA, Bologna, Italy (1997) 9.W. A. Richter, A.A. Cowley, R. Lindsay, J. J. Lawrie, S. V. Fortsch, J. V. Pilcher, R. Bonetti, and P. E. Hodgson, Phys. Rev. C, 46, 1030 (1992