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Journals / Adıyaman Üniversitesi Eğitim Bilimleri Dergisi / 2013 / Cilt: 3 - Sayı: 2

Synthesis and Characterization of Mononuclear Metallo Phthalocyanines with Geranioxy Substituents

Geranioksi Sübstitüentli Mononükleer Metalli Ftalosiyaninlerin Sentezi ve Karakterizasyonu

Ayşegül YAZICI
Ezgi YILMAZER
Pages
71–78
Publication Date
2013-05-01
DOI
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AI Summary & Key Takeaways

AI Insight
⚡ TL;DR(Too Long; Didn't Read)

The synthesized compounds were characterized by FT-IR, 1H NMR and UV/VIS spectroscopic data.

📌 3 Key Takeaways

🎯
Objective & Hypothesis:A new disubstituted phthalonitrile derivative 3 was prepared by the reaction of 4-5-dichloro-1,2-dicyanobenzene and gereniol in dry DMF as solvent, in the presence K2CO3 as base, by nucleophilic displacement reaction of activated chloride groups in an aromatic ring.
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Key Findings & Data:The tetramerization of compound 3 gave a mononuclear metallophthalocyanines 4 and 5 (M=Co and Cu).
💡
Conclusion & Impact:The synthesized compounds were characterized by FT-IR, 1H NMR and UV/VIS spectroscopic data.
🔬Design:Research Article
📍Scope:Comprehensive Sample
⚙️Variables:Simetrik ftalosiyaninler · Sentezler · Kobalt ftalosiyanin

Abstract

A new disubstituted phthalonitrile derivative 3 was prepared by the reaction of 4-5-dichloro-1,2-dicyanobenzene and gereniol in dry DMF as solvent, in the presence K2CO3 as base, by nucleophilic displacement reaction of activated chloride groups in an aromatic ring. The tetramerization of compound 3 gave a mononuclear metallophthalocyanines 4 and 5 (M=Co and Cu). The synthesized compounds were characterized by FT-IR, 1H NMR and UV/VIS spectroscopic data.

Özet

Yeni disübstitüe ftalonitril türevi 3; geraniol ile 4,5-dikloro-1,2-disiyano benzenin kuru DMF çözücülü ve K2CO3 bazlı ortamda aromatik halkadaki aktif klor gruplarının nükleofilik yerdeğiştirme reaksiyonuyla hazırlandı. Ftalonitrilin 3 tetramerizasyonu mononükleer metalli ftalosiyaninleri 4 ve 5 (M = Co ve Cu) sentezlendi. Sentezlenen bileşikler FT-IR, 1H-NMR ve UV/VIS spektrumları ile karakterize edildi.

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Cite This Article

YAZICI, A., YILMAZER, E. (2013). Synthesis and Characterization of Mononuclear Metallo Phthalocyanines with Geranioxy Substituents. Adıyaman Üniversitesi Eğitim Bilimleri Dergisi, Cilt: 3 - Sayı: 2, 71–78. https://ajindex.com/articles/450985

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