Journals / Textile and Apparel / 2026 / Volume: 27 Issue: 1

PLASMA INDUCED GRAFT POLYMERIZATION OF A FLUOROCARBON MONOMER ON POLYAMIDE 6,6 FABRICS

Pages
—
Publication Date
2017-03-31
DOI
—
🏛️Bibliographic metadata and full text access for this article are provided via DergiPark.
DergiPark Record ↗
✨

AI Summary & Key Takeaways

AI Insight
⚡ TL;DR(Too Long; Didn't Read)

FT-IR spectra also confirmed the high fluorocarbon content on the fabric surface after acetone extraction and  after home laundering.

📌 3 Key Takeaways

🎯
Objective & Hypothesis:2-(perfluorohexyl) ethyl acrylate, a fluorocarbon based monomer was graft polymerized on polyamide 6,6 fabrics with the aid of an  atmospheric pressure plasma reactor to obtain a water repellent surface.
📊
Key Findings & Data:Di(ethylene glycol) diacrylate crosslinker was used to improve  the graft yield of the polymerized layer.
💡
Conclusion & Impact:FT-IR spectra also confirmed the high fluorocarbon content on the fabric surface after acetone extraction and  after home laundering.
🔬Design:Research Article
📍Scope:Comprehensive Sample
⚙️Variables:Hydrophobic · plasma · textile

Abstract

2-(perfluorohexyl) ethyl acrylate, a fluorocarbon based monomer was graft polymerized on polyamide 6,6 fabrics with the aid of an  atmospheric pressure plasma reactor to obtain a water repellent surface. Di(ethylene glycol) diacrylate crosslinker was used to improve  the graft yield of the polymerized layer. Two sets of experiments were conducted to understand the effects of variables on aqueous  liquid repellency of fabrics. Plasma post exposure time and the presence of a crosslinker at high levels led to higher aqueous liquid  repellency values and lower surface tension values. Static water contact angles were measured for the fabrics and values as high as 158  degrees were observed. FT-IR spectra also confirmed the high fluorocarbon content on the fabric surface after acetone extraction and  after home laundering.

🔖

Cite This Article

Dinçmen, M. G., Hauser, P. J., Gürsoy, N. Ç. (2017). PLASMA INDUCED GRAFT POLYMERIZATION OF A FLUOROCARBON MONOMER ON POLYAMIDE 6,6 FABRICS. Textile and Apparel, Volume: 27 Issue: 1. https://ajindex.com/articles/1640274

📄 Full Text PDF Viewer

📄

PDF görüntüleyici hazırlanıyor...

References (19)

  1. Shishoo, R., 2007, “Introduction – The potential of plasma technology in the textile industry”, Plasma Technologies In Textiles, Shishoo, R.,Woodhead publishing limited, Cambridge, xv-xxx.
  2. Ramamoorthy, A., El-Shafei, A. and Hauser, P., 2013, “Plasma induced graft polymerization of C6 fluorocarbons on cotton fabrics for sustainable finishing applications”, Plasma Processes and Polymers, 10, 430–443.
  3. El-Shafei, A., Helmy, H., Ramamoorthy, A. and Hauser, P., 2015, “Nanolayer atmospheric pressure plasma graft polymerization of durable repellent finishes on cotton”, J. Coat. Technol. Res., 12(4), 681–691.
  4. Sun, D. and Stylios, G.K., 2006, “Fabric surface properties affected by low temperature plasma treatment”, Journal of Materials Processing Technology, 173, 172–177.
  5. Mazloumpour, M., Malshe, P., El-Shafei, A., Hauser, P., 2013, “Conferring durable antimicrobial properties on nonwoven polypropylene via plasma-assisted graft polymerization of DADMAC”, Surface and Coatings Technology, 224, 1-7.
  6. Malshe, P., Mazloumpour, M., El-Shafei, A. and Hauser, P., 2012, “Functional military textile: plasma-induced graft polymerization of DADMAC for antimicrobial treatment on nylon-cotton blend fabric”, Plasma Chemistry and Plasma Processing, 32(4), 833-843.
  7. Gul Dincmen, M., Hauser, P.J., Gursoy, N.Ç., 2016, “Plasma induced graft polymerization of three hydrophilic monomers on nylon 6,6 fabrics for enhancing antistatic property”, Plasma Chemistry and Plasma Processing. DOI:10.1007/s11090-016-9722-5
  8. Gul Dincmen, M., Hauser, P.J., Gursoy, N.Ç., 2016, “Atmospheric pressure plasma treatment of nylon 6,6 and polyester fabrics for enhancing antistatic properties”, AATCC Journal of Research, 3(4)., 36-46.
  9. Armagan, O. G., Karaguzel Kayaoglu, B., Canbaz Karakas, H. and Guner, F. S., 2014, “Adhesion strength behaviour of plasma pre-treated and laminated polypropylene nonwoven fabrics using acrylic and polyurethane-based adhesives”, Journal of Industrial Textiles, Volume 43(3), pp: 396–414.
  10. Ozdogan, E., 2006, “The effect of plasma treatment over the adhesion property of polyamide 6 fabrics”, Tekstil ve Konfeksiyon, Volume 16(2), pp: 128-133.
  11. Yaman, N., Ozdogan, E., and Seventekin, N., 2012, “Improving physical properties of polyamide fibers by using atmospheric plasma treatments”, Tekstil ve Konfeksiyon, 22(2), 102-105.
  12. Shahidi, S., Ghoranneviss, M., Ilali, R., Karami, M. and Miladi, M., 2016, “Dyeing properties of the atmospheric pressure plasma-treated polypropylene fabric subjected to butane tetra carboxylic acid.” The Journal of The Textile Institute, 107 (5), 636-644.
  13. Labay, C., Canal, C., Rodrigueza, C., Caballeroa, G., Canal, J.M., 2013, “Plasma surface functionalization and dyeing kinetics of Pan-Pmma copolymers.” Applied Surface Science, 283, 269–275.
  14. Schindler, W. D. and Hauser, P. J., 2004, “Repellent Finishes”, Chemical finishing of textiles, Woodhead Publishing Ltd, Cambridge, 74-86.
  15. Fung, W. and Hardcastle, M., 2001, “Introductory Survey”, Textiles in automotive Engineering, Woodhead publishing limited, Cambridge, 1-23.
  16. AATCC Test Method 193-2007, 2011, Aqueous Liquid Repellency: Water/Alcohol Solution Resistance Test.
  17. AATCC Test Method 135-2010, 2011, Dimensional Changes of Fabrics after Home Laundering.
  18. Characteristic IR Absorption Frequencies of Organic Functional Groups (2015) http://www2.ups.edu/faculty/hanson/Spectroscopy/IR/IRfrequencies.html, Accessed 9 December 2015.
  19. Table of IR Absorptions (2015) http://www.chem.ucla.edu/~webspectra/irtable.html, Accessed 9 December 2015.