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Journals / International Journal of Chemistry and Technology / 2026 / Volume: 2 Issue: 1

Synthesis and characterization of alkyd resin based on soybean oil and glycerin using zirconium octoate as catalyst

Mohamed E. Elba(Damanhour University)
Elsayed M. Abdel Rehim(Damanhour university)
Ramadan E. Ashery(Damanhour university)
Pages
—
Publication Date
2018-05-12
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AI Summary & Key Takeaways

AI Insight
⚡ TL;DR(Too Long; Didn't Read)

The prepared resin was formulated in white lacqure and yellowing resistance tested with commercial resins.

📌 3 Key Takeaways

🎯
Objective & Hypothesis:A one pot synthesis of alkyd resins based on the soybean oil and glycerin with the zirconium octoate (zirconium 2-ethyl hexanoate) as a new renewable raw material was performed.
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Key Findings & Data:The alkyd resin was obtained from polycondensation of the alcoholysis products with phthalic anhydrid at 250 °C.
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Conclusion & Impact:The prepared resin was formulated in white lacqure and yellowing resistance tested with commercial resins.
🔬Design:Research Article
📍Scope:Comprehensive Sample
⚙️Variables:Phthalic anhydride · soybean oil · zirconium ocotate

Abstract

A one pot synthesis of alkyd resins based on the soybean oil and glycerin with the zirconium octoate (zirconium 2-ethyl hexanoate) as a new renewable raw material was performed. The alcoholysis reaction of soybean oil and glycerin carried out in absence of nitrogen gas inlet in the presence of zirconium octoate. The alkyd resin was obtained from polycondensation of the alcoholysis products with phthalic anhydrid at 250 °C. The structure confirmed by FT-IR and H 1 -NMR spectroscopy. Flexibility, drying time, hardness, adhesion test, impact resistance, gloss test and chemical resistance of synthesized alkyd resins was invesitigated. The prepared resin was formulated in white lacqure and yellowing resistance tested with commercial resins.

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Cite This Article

Elba, M. E., Rehim, E. M. A., Ashery, R. E. (2018). Synthesis and characterization of alkyd resin based on soybean oil and glycerin using zirconium octoate as catalyst. International Journal of Chemistry and Technology, Volume: 2 Issue: 1. https://doi.org/10.32571/ijct.347670

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References (32)

  1. Gandini, A. Green Chem. 2011, 13 (5), 1061-1083.
  2. European Coutings Handbook, Brock., T.; Groteklaes, M.; Mischke, P. 2000, 16-85.
  3. Erhan, S.Z.Indnstrial uses of vegetable oil. AOCS publishing, 2005.
  4. Tuck, N. Wiley, CV. \sit A ser. Technol. 2000.
  5. Gaykar, D.V. Paint India 7. 2001, 55-60.
  6. Pramanik, S.; Sagar, K.; Konwar, B.K.; Karak, N. Prog. Org. Coat.2012, 75 (4), 569-578.
  7. Turner, G.P.A. Introduction to paint chemistry and principles of paint technology, 3rd ed.; Champman and Hall, London, 1988.
  8. Kyenge, B.A.; Anhwange, B.A.; Ageh, J.T.; Igbum, G.O. Int.J. Mod. Org Chem. 2012, 1 (2), 66-71.
  9. Solomon, D.H.; Swift, J.D. J. Oil Colour Chem. Assoc. 1966, 49, 915-927.
  10. Aydin, S.; Akcay, H.; Evren, O.; Seniha Guner, F.; Tuncer Erciyes, A. Prog. Org. Coats. 2004, 51(4), 273-279.
  11. Wholf, R.H. Coconut oil modified alkyd reirns and copolymers There of witl an alkyl acrylate. U.S. Patent 3, 374, 194, Mar. 19, 1968.
  12. Wicks, Z.; Jones, F.; Pappas, S.P. Organic Coating Science and Technology. John Wiley & Sons, New York, 1999.
  13. Taft Jr, R.W.; Newman, M.S.; Verhoek, F.H.J. Am. Chem. Soc. 1950, 72, 4511-4519.
  14. Lazzari, M.; Chiantore, O. Polym. Degrad. Stabil. 1999, 65 (2), 303-313.
  15. Köckritz, A.; Martin, A. Eur. J. Lipid Sci. Tecnol. 2008, 110, 812-824.
  16. Warwel, S. Rusch gen Klass, M. Lipid Technol. 1997, 9, 10-14.
  17. Dobson, G.; Christie, W.W.; Sebedio, J.L. J. Chromatogr. 1996, 723, 349-354.
  18. Asemani, H.R.; Ahmadi, P.; Sarabi, A.A.; Eivaz Mohammadloo, H. Prog. Org. Coat. 2016, 94, 18-27.
  19. Singha Mahapatra, S.; Karak, N. Prog. Org. Coat. 2004, 51, 103-108.
  20. Deligny, P.K.T.; Tuck, N. Alkyds and polyesters. In Resins for Surface Coatings; Oldring, P.K.T., Ed.; John Wiley & Sons, New York, 2000. Vol 2, p. 15. 22. Sharma, B.; Dolui, S.K.; Sharma, A.K. J. Sci. Ind. Res. 2001, 60, 153-158.
  21. Privett, O.S. J. Am. Oil Chem. Soc. 1959, 36 (10), 507-512.
  22. Porter, N.A.; Wujek, D.G. J. Am. Chem. Soc. 1984, 106 (9), 2626-2629.
  23. R usina, A.; Vlcek, A.A. Nature 1965, 206, 295-296.
  24. Stenberg, C.; Svensson, M.; Johansson, M. Ind. Crop. Prod.2005, 21 (2), 263-272.
  25. Russell, G.A. J.Am. Chem. Soc. 1957, 79 (14), 3871-3877.
  26. Erhan, S.Z.Indnstrial uses of vegetable oil. AOCS publishing, 2005.
  27. Pramanik, S.; Sagar, K.; Konwar, B.K.; Karak, N. Prog. Org. Coat.2012, 75 (4), 569-578.
  28. Kyenge, B.A.; Anhwange, B.A.; Ageh, J.T.; Igbum, G.O. Int.J. Mod. Org Chem. 2012, 1 (2), 66-71.
  29. Taft Jr, R.W.; Newman, M.S.; Verhoek, F.H.J. Am. Chem. Soc. 1950, 72, 4511-4519.
  30. Deligny, P.K.T.; Tuck, N. Alkyds and polyesters. In Resins for Surface Coatings; Oldring, P.K.T., Ed.; John Wiley & Sons, New York, 2000. Vol 2, p. 15. 22. Sharma, B.; Dolui, S.K.; Sharma, A.K. J. Sci. Ind. Res. 2001, 60, 153-158.
  31. Stenberg, C.; Svensson, M.; Johansson, M. Ind. Crop. Prod.2005, 21 (2), 263-272.
  32. Russell, G.A. J.Am. Chem. Soc. 1957, 79 (14), 3871-3877.