Journals / Black Sea Journal of Engineering and Science / 2026 / Cilt: 9 Sayı: 5

A Sustainable Act for Concrete Debris Disposal by Using the Alkaline Fusion Technique for the Synthesis of SBA-15 to Use in Dye Removal

Nevin Karamahmut Mermer(Kalekim Construction Chemicals Co.)0000-0001-6645-4724
Pages
2783–2794
Publication Date
2026-09-15
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AI Summary & Key Takeaways

AI Insight
⚡ TL;DR(Too Long; Didn't Read)

Ultimately, the synthesized SBA-15 material was employed for dye removal.

📌 3 Key Takeaways

🎯
Objective & Hypothesis:The cement industry contributes to 8% of total carbon emissions, primarily due to the high temperatures required for production and the use of natural raw materials.
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Key Findings & Data:Cement is the second most utilized industrial raw material globally due to its ability to be molded in liquid state and gradually increase in strength.
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Conclusion & Impact:Ultimately, the synthesized SBA-15 material was employed for dye removal.
🔬Design:Araştırma Makalesi
📍Scope:Comprehensive Sample
⚙️Variables:Concrete debris · Alkaline fusion · SBA-15

Abstract

The cement industry contributes to 8% of total carbon emissions, primarily due to the high temperatures required for production and the use of natural raw materials. Cement is the second most utilized industrial raw material globally due to its ability to be molded in liquid state and gradually increase in strength. In addition to carbon emissions, the appropriate disposal of concrete debris is also a substantial concern. The quantity of debris remaining after natural disasters such as earthquakes poses a substantial obstacle. Currently, concrete waste is utilized for the purpose of filling diverse construction sites. The alkali fusion method has been employed in scientific study to recover a silicon solution from various industrial waste materials, such as fly ash, bottom ash, slag, and gold mine tailing slurry. The hydrated cement phases display elevated levels of calcium and silicon content. The objective of the study was to apply alkali treatment to the debris to extract silicon from the hydrated cement stages of construction debris using the alkali fusion method, which involves heat treatment. The silicon solution obtained was assessed in the synthesis of SBA-15, a material characterized by its mesoporous structure. Ultimately, the synthesized SBA-15 material was employed for dye removal.

Özet

The cement industry contributes to 8% of total carbon emissions, primarily due to the high temperatures required for production and the use of natural raw materials. Cement is the second most utilized industrial raw material globally due to its ability to be molded in liquid state and gradually increase in strength. In addition to carbon emissions, the appropriate disposal of concrete debris is also a substantial concern. The quantity of debris remaining after natural disasters such as earthquakes poses a substantial obstacle. Currently, concrete waste is utilized for the purpose of filling diverse construction sites. The alkali fusion method has been employed in scientific study to recover a silicon solution from various industrial waste materials, such as fly ash, bottom ash, slag, and gold mine tailing slurry. The hydrated cement phases display elevated levels of calcium and silicon content. The objective of the study was to apply alkali treatment to the debris to extract silicon from the hydrated cement stages of construction debris using the alkali fusion method, which involves heat treatment. The silicon solution obtained was assessed in the synthesis of SBA-15, a material characterized by its mesoporous structure. Ultimately, the synthesized SBA-15 material was employed for dye removal.

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Cite This Article

Mermer, N. K. (2026). A Sustainable Act for Concrete Debris Disposal by Using the Alkaline Fusion Technique for the Synthesis of SBA-15 to Use in Dye Removal. Black Sea Journal of Engineering and Science, Cilt: 9 Sayı: 5, 2783–2794. https://doi.org/10.34248/bsengineering.1842781

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References (55)

  1. Abd El-Aleem, S., Heikal, M., & Morsi, W. M. (2014). Hydration characteristics, thermal expansion and microstructure of cement containing nano-silica. Construction and Building Materials, 59, 151–160.
  2. Abdel-Khalek, M. A., Abdel Rahman, M. K., & Francis, A. A. (2017). Exploring the adsorption behavior of cationic and anionic dyes on industrial waste egg shells. Journal of Environmental Chemical Engineering, 5, 319–327.
  3. Ahmad, A. L., Harris, W. A., & Ooi, B. S. (2002). Removal of dye from textile wastewater using membrane technology. Jurnal Teknologi, 36, 31–44.
  4. Balonis, M., & Glasser, F. P. (2009). The density of cement phases. Cement and Concrete Research, 39, 733–739.
  5. Barcelo, L., Kline, J., Walenta, G., & Gartner, E. (2014). Cement and carbon emissions. Materials and Structures, 47, 1055–1065.
  6. Bhagiyalakshmi, M., Yun, L. J., Anuradha, R., & Jang, H. T. (2010). Synthesis of chloropropylamine grafted mesoporous MCM-41, MCM-48 and SBA-15 from rice husk ash: Their application to CO2 chemisorption. Journal of Porous Materials, 17, 475–484.
  7. Chandler, W., Schaeffer, R., Dadi, Z., Shukla, P., Tudela, F., Davidson, O., & Al-Azhar, S. (2002). Climate change mitigation in developing countries: Brazil, China, India, Mexico, South Africa, and Turkey. World Resources Institute.
  8. Environmental Protection Agency. (2020). Portland cement manufacturing. EPA.
  9. Fierro, J. J., Escudero-Atehortua, A., Nieto-Londoño, C., Giraldo, M., Jouhara, H., & Wrobel, L. C. (2020). Evaluation of waste heat recovery technologies for the cement industry. International Journal of Thermofluids, 7–8, Article 100040.
  10. Ganiron, T. U. (2015). Recycling concrete debris from construction and demolition waste. International Journal of Advanced Science and Technology, 77, 7–24.
  11. Gawwad, H. A. A., El-Aleem, S. A., & Ouda, A. S. (2015). Preparation and characterization of one-part non-Portland cement. Ceramics International, 41, 1–9.
  12. Hendriks, C. A., Worrell, E., De Jager, D., Blok, K., & Riemer, P. (2003). Emission reduction of greenhouse gases from the cement industry. In Greenhouse Gas Control Technologies (pp. 1–11).
  13. Hewlett, P., & Liska, M. (1988). Lea’s chemistry of cement and concrete. Elsevier.
  14. Hills, T., Leeson, D., Florin, N., & Fennell, P. (2016). Carbon capture in the cement industry: Technologies, progress, and retrofitting. Environmental Science & Technology, 50, 368–377.
  15. HSN, M. I., Panatarani, C., Faizal, F., Mulyana, C., & Joni, I. M. (2023). Synthesis of mesoporous silica SBA-15 from geothermal sludge. Materialia, 27, Article 101637.
  16. İnceoğlu, F., Mermer, N. K., Kırmızı, V. & Tombaş, G. (2021). Influence of cement with different calcium sulfate phases on cementitious tile adhesive mortars. International Journal of Adhesion and Adhesives, 104, Article 102740
  17. Islam, M. A., Ali, I., Karim, S. M. A., Hossain Firoz, M. S., Chowdhury, A. N., Morton, D. W., & Angove, M. J. (2019). Removal of dye from polluted water using novel nano manganese oxide-based materials. Journal of Water Process Engineering, 32, Article 100911.
  18. Izumi, Y., Iizuka, A., & Ho, H. J. (2021). Calculation of greenhouse gas emissions for a carbon recycling system using mineral carbon capture and utilization technology in the cement industry. Journal of Cleaner Production, 312, Article 127618.
  19. Kabir, S., Al-Shayeb, A., & Khan, I. M. (2016). Recycled construction debris as concrete aggregate for sustainable construction materials. Procedia Engineering, 145, 1518–1525.
  20. Kaplan, E., & Soyluk, A. (2023). Deprem sonrası atık yönetimi: Atık betonun geri dönüşümü ve mimaride kullanımı için öneriler. Mimarlık Bilimleri ve Uygulamaları Dergisi, 140–162.
  21. Karamahmut Mermer, N., İnceoğlu, F., & Ünlü Pınar, E. (2024). Effect of the moisture content of sand used in cement-based ceramic tile adhesives on their microstructure and performance. International Journal of Adhesion and Adhesives. Advance online publication.
  22. Karamahmut Mermer, N., Sari Yilmaz, M., Dere Ozdemir, O., & Pişkin, M. B. (2017). The synthesis of silica-based aerogel from gold mine waste for thermal insulation. Journal of Thermal Analysis and Calorimetry, 129, 1807–1812.
  23. Karellas, S., Leontaritis, A. D., Panousis, G., Bellos, E., & Kakaras, E. (2013). Energetic and exergetic analysis of waste heat recovery systems in the cement industry. Energy, 58, 147–156.
  24. Kokunešoski, M., Gulicovski, J., Matović, B., Logar, M., Milonjić, S. K., & Babić, B. (2010). Synthesis and surface characterization of ordered mesoporous silica SBA-15. Materials Chemistry and Physics, 124, 1248–1252.
  25. Lakshmi, M., & Nivetdhitha, R. R. (2015). Effect of partial replacement of aggregates by recycled concrete debris on strength of concrete. International Journal of Civil Engineering and Technology, 27, 250–259.
  26. Laskowski, Ł., Laskowska, M., Walcarius, A., Doskocz, M., Vila, N., Karczmarska, A., Pawlik, P., Goraus, J., Balin, K., & Dulski, M. (2024). Synthesis and characterization of SBA-15 silica containing cyclam inside pores for capturing iron chloride. Microporous and Mesoporous Materials, 378, Article 112980.
  27. Lau, Y. Y., Wong, Y. S., Teng, T. T., Morad, N., Rafatullah, M., & Ong, S. A. (2015). Degradation of cationic and anionic dyes in coagulation–flocculation process using bi-functionalized silica hybrid with aluminum-ferric as auxiliary agent. RSC Advances, 5, 34206–34215.
  28. Lee, Y. J., Lee, K. W., Min, B. Y., Hwang, D. S., & Moon, J. K. (2015). Characterization of cement waste form for final disposal of decommissioning concrete wastes. Annals of Nuclear Energy, 77, 294–299.
  29. Li, Y., Le Pape, Y. M., Tajuelo Rodriguez, E., Torrence Moore, C. E., Arregui Mena, J. D., Rosseel, T. M., & Sircar, M. (2020). Microstructural characterization and assessment of mechanical properties of concrete. Construction and Building Materials, 257, Article 119540.
  30. Liang, B., Zhu, P., Gu, J., Yuan, W., Xiao, B., Hu, H., & Rao, M. (2024). Advancing adsorption and separation with modified SBA-15: A comprehensive review and future perspectives. Molecules, 29, Article 3543.
  31. Lin, Y., & Du, H. (2020). Graphene reinforced cement composites: A review. Construction and Building Materials, 265, Article 120312.
  32. Masood, A., Ahmad, T., Arif, M., & Mahdi, F. (2001). Waste management strategies for concrete. Environmental Engineering and Policy, 3, 15–18.
  33. Mavroulis, S., Mavrouli, M., Vassilakis, E., Argyropoulos, I., Carydis, P., & Lekkas, E. (2023). Debris management in Turkey provinces affected by the 6 February 2023 earthquakes. Applied Sciences, 13, Article 4582.
  34. McKay, G., Porter, J. F., & Prasad, G. R. (1999). The removal of dye colours from aqueous solutions by adsorption on low-cost materials. Water, Air, and Soil Pollution, 114, 423–438.
  35. Mermer, N. K., & Pişkin, S. (2018). Silica-based aerogel synthesis from fly ash and bottom ash. Main Group Chemistry, 17, 63–77.
  36. Mermer, N. K., & Pişkin, S. (2019). Aerogel synthesis using sand by ultrasonically assisted sol–gel method. Journal of the Faculty of Engineering and Architecture of Gazi University, 34, 1253–1263.
  37. Naqi, A., & Jang, J. G. (2019). Recent progress in green cement technology utilizing low-carbon emission fuels and raw materials: A review. Sustainability, 11, Article 537.
  38. Olfs, H. W., Torres-Dorante, L. O., Eckelt, R., & Kosslick, H. (2009). Comparison of different synthesis routes for Mg–Al layered double hydroxides (LDH): Characterization of the structural phases and anion exchange properties. Applied Clay Science, 43, 459–464.
  39. Oliveira, A. N. de, Cardoso, R. S., Ferreira, I. M., Silva, L. S., Costa, A. A. F., Pires, L. H. O., Rocha Filho, G. N., Luque, R., Noronha, R. C. R., & Nascimento, L. A. S. (2023). Valorization of silica-based residues for the synthesis of ordered mesoporous silicas and their applications. Microporous and Mesoporous Materials, 354, Article 112520.
  40. Phair, J. W. (2006). Green chemistry for sustainable cement production and use. Green Chemistry, 8, 763–780.
  41. Sari Yilmaz, M. (2022). Graphene oxide/hollow mesoporous silica composite for selective adsorption of methylene blue. Microporous and Mesoporous Materials, 330, Article 111570.
  42. Sari Yilmaz, M., & Pişkin, S. (2015). Removal of template from SBA-15 samples synthesized from different silica sources. Journal of Thermal Analysis and Calorimetry, 121, 1255–1262.
  43. Schneider, M. (2015). Process technology for efficient and sustainable cement production. Cement and Concrete Research, 78, 14–23.
  44. Schneider, M., Romer, M., Tschudin, M., & Bolio, H. (2011). Sustainable cement production—Present and future. Cement and Concrete Research, 41, 642–650.
  45. Scientific and Technological Research Council of Türkiye (TÜBİTAK). (2024, April 5). TÜBİTAK provided active support in the fight against earthquake. https://tubitak.gov.tr/en/news/tubitak-provided-active-support-fight-against-earthquake
  46. Shigemoto, N., Hayashi, H., & Miyaura, K. (1993). Selective formation of Na-X zeolite from coal fly ash by fusion with sodium hydroxide prior to hydrothermal reaction. Journal of Materials Science, 28, 4781–4786.
  47. Simonin, J.-P. (2016). On the comparison of pseudo-first order and pseudo-second order rate laws in the modeling of adsorption kinetics. Chemical Engineering Journal, 300, 254–263.
  48. Singh Kashyap, V., Agrawal, U., Arora, K., & Sancheti, G. (2021). FTIR Analysis of Nanomodified Cement Concrete Incorporating Nano Silica and Waste Marble Dust IOP Conference Series: Earth and Environmental Science, 796, Article 012012.
  49. Summerbell, D. L., Barlow, C. Y., & Cullen, J. M. (2016). Potential reduction of carbon emissions by performance improvement: A cement industry case study. Journal of Cleaner Production, 135, 1327–1339.
  50. Turkish Standards Institute. (2018). TS EN 197-1: Composition, specification and conformity criteria for common cements. TSE.
  51. Ucol-Ganiron, T. (2012). Concrete debris as alternative fine aggregate for architectural finishing mortar. Architectural Research, 2, 111–114.
  52. Yagub, M. T., Sen, T. K., Afroze, S., & Ang, H. M. (2014). Dye and its removal from aqueous solution by adsorption: A review. Advances in Colloid and Interface Science, 209, 172–184.
  53. Yilmaz, M. S., & Mermer, N. K. (2015). Preparation of silicon and aluminum extracts from fly ashes by alkali fusion. International Journal of Chemical Engineering and Applications, 9, 512–515.
  54. Yu, H., & Zhai, Q. Z. (2009). Mesoporous SBA-15 molecular sieve as a carrier for controlled release of nimodipine. Microporous and Mesoporous Materials, 123, 298–305.
  55. Shigemoto, N., Hayashi, H., & Miyaura, K. (1993). Selective formation of Na-X zeolite from coal fly ash by fusion with sodium hydroxide prior to hydrothermal reaction. Journal of Materials Science, 28, 4781–4786.