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Journals / International Journal of Thermodynamics / 2026 / Volume: 16 Issue: 1

Estimation of Thermodynamic Properties of Binary Liquid Mixtures on the Basis of Statistical Mechanical Theories

J. D. Pandey
Prakash Chandra
Rupali Sethi
Vinay Sanguri
Pages
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Publication Date
2012-12-14
DOI
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AI Summary & Key Takeaways

AI Insight
⚡ TL;DR(Too Long; Didn't Read)

The calculated values are compared with the experimental findings collected from literature and quite satisfactory results are obtained.

📌 3 Key Takeaways

🎯
Objective & Hypothesis:Thermodynamic properties of liquids and liquid mixtures play very important role in understanding the nature of molecular interactions occurring in the system.
📊
Key Findings & Data:In the present work different thermodynamic properties of 15 pure liquids and 34 equimolar binary liquid mixtures of benzene, toluene, p-xylene, chlorobenzene and 1-chloronaphthalene with linear and branched alkanes have been computed with the help of Flory’s statistical theory (FST), Hard sphere equation of state (HSE) and Hole theory (HT) simultaneously.
💡
Conclusion & Impact:The calculated values are compared with the experimental findings collected from literature and quite satisfactory results are obtained.
🔬Design:Article
📍Scope:Comprehensive Sample
⚙️Variables:Flory statistical theory · hard sphere equation of state · hole theory

Abstract

Thermodynamic properties of liquids and liquid mixtures play very important role in understanding the nature of molecular interactions occurring in the system. In the present work different thermodynamic properties of 15 pure liquids and 34 equimolar binary liquid mixtures of benzene, toluene, p-xylene, chlorobenzene and 1-chloronaphthalene with linear and branched alkanes have been computed with the help of Flory’s statistical theory (FST), Hard sphere equation of state (HSE) and Hole theory (HT) simultaneously. The calculated values are compared with the experimental findings collected from literature and quite satisfactory results are obtained.

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Cite This Article

Pandey, J. D., Chandra, P., Sethi, R., Sanguri, V. (2012). Estimation of Thermodynamic Properties of Binary Liquid Mixtures on the Basis of Statistical Mechanical Theories. International Journal of Thermodynamics, Volume: 16 Issue: 1. https://ajindex.com/articles/1415163

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