Journals / Ordu Üniversitesi Bilim ve Teknoloji Dergisi / 2026 / Cilt: 8 Sayı: 1

Electrochemical Synthesis of Prussian Blue in Conducting Poly (Vinylferrocene) Film

İletken Poli (Vinilferrosen) Filmi İçerisinde Prusya Mavisinin Elektrokimyasal Sentezi

Pages
31–37
Publication Date
2018-06-15
DOI
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AI Summary & Key Takeaways

AI Insight
⚡ TL;DR(Too Long; Didn't Read)

Furthermore, experimental studies showed that the modified PGE had electrocatalytic activity towards hydrogen peroxide (H 2 O 2 ) reduction and thus can be used for fabrication of an amperometric H 2 O 2 biosensor

📌 3 Key Takeaways

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Objective & Hypothesis:In this study, preparation of prussion blue (PB) and poly(vinylferrocene) PVF modified disposable pencil graphite electrode (PGE) by formation of PB directly inside the iron-containing PVF is described.
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Key Findings & Data:The modified electrode has the potential to be used for biosensor studies combining the advantages of PB and PVF mediators.
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Conclusion & Impact:Furthermore, experimental studies showed that the modified PGE had electrocatalytic activity towards hydrogen peroxide (H 2 O 2 ) reduction and thus can be used for fabrication of an amperometric H 2 O 2 biosensor
🔬Design:Araştırma Makalesi
📍Scope:Comprehensive Sample
⚙️Variables:Medyatör · Prusya mavisi · Poli (vinilferrosen)

Abstract

In this study, preparation of prussion blue (PB) and poly(vinylferrocene) PVF modified disposable pencil graphite electrode (PGE) by formation of PB directly inside the iron-containing PVF is described. The modified electrode has the potential to be used for biosensor studies combining the advantages of PB and PVF mediators. Formation of PB inside the polymer has been confirmed by cyclic voltammetry. Furthermore, experimental studies showed that the modified PGE had electrocatalytic activity towards hydrogen peroxide (H 2 O 2 ) reduction and thus can be used for fabrication of an amperometric H 2 O 2 biosensor

Özet

Bu çalışmada, doğrudan doğruya demir içeren poli (vinilferrosen) (PVF) içerisinde prusya mavisi (PB) oluşturularak PB ve PVF ile modifiye edilmiş tek kullanımlık kalem grafit (KGE) elektrotun hazırlanması anlatılmıştır. Modifiye elektrotun PB ve PVF’in avantajlarını birleştirerek biyosensör çalışmalarında kullanılma potansiyeli bulunmaktadır. PB’nin polimerin içerisinde oluştuğu dönüşümlü voltametri ile gösterilmiştir. Dahası, deneysel çalışmalar modifiye KGE’un hidrojen peroksitin (H 2 O 2 ) indirgenmesine karşı elektrokatalitik aktivite gösterdiğini ve bundan dolayı amperometrik bir H 2 O 2 sensörünün geliştirilmesi için kullanılabileceğini ortaya koymuştur

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Cite This Article

Kurt, N. C., Çelebi, M. S. (2018). Electrochemical Synthesis of Prussian Blue in Conducting Poly (Vinylferrocene) Film. Ordu Üniversitesi Bilim ve Teknoloji Dergisi, Cilt: 8 Sayı: 1, 31–37. https://ajindex.com/articles/1279444

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References (12)

  1. Abbaspour A & Kamyabi M A (2005). Electrochemical formation of Prussian blue films with a single ferricyanide solution on gold electrode. J Electroanal Chem 584: 117-123
  2. Itaya K, Ataka T, Toshima S & Shlnohara T (1982). Electrochemistry of Prussian Blue. An in Situ Móssbauer Effect Measurement. J Phys Chem 86: 2415-2418
  3. Jiang Y, Zhang X, Shan C, Hua S, Zhang Q, Bai X, Dan L & Niu L (2011). Functionalization of graphene with electrodeposited Prussian blue towards amperometric sensing application. Talanta 85: 76-81
  4. Karyakin A A (2001). Prussian Blue and Its Analogues: Electrochemistry and Analytical Applications. Electroanalysis 13(10): 813-819
  5. Kuralay F, Özyörük H & Yıldız A (2006). Amperometric enzyme electrode for urea determination using immobilized urease in poly (vinylferrocenium) film. Sens Actuators B Chem 114: 500-506.
  6. Özer BC, Özyörük H, Çelebi SS & Yıldız A (2007). Amperometric enzyme electrode for free cholesterol determination prepared with cholesterol oxidase immobilized in poly (vinylferrocenium) film. Enzyme Microb Technol 40: 262-265.
  7. Ricci F & Palleschi G (2005). Sensor and biosensor preparation, optimisation and applications of Prussian Blue modified electrodes. Biosens Bioelectron 21: 389-407
  8. Saleem M, Yu H, Wang L, Abdin Z, Khalid H, Akram M, Abbasi N M & Huang J (2015). Review on synthesis of ferrocene-based redox polymers and derivatives and their application in glucose sensing. Anal Chim Acta 876: 9-25
  9. Türkmen E, Baş SZ, Gülce H & Yıldız S (2014). Glucose biosensor based on immobilization of glucose oxidase in electropolymerized poly(o-phenylenediamine) film on platinum nanoparticles-polyvinylferrocenium modified electrode. Electrochim Acta 123: 93-102.
  10. Vishnu N & Kumar A S (2017). Development of Prussian Blue and Fe(bpy)32+ hybrid modified pencil graphite electrodes utilizing its intrinsic iron for electroanalytical applications. J Electroanal Chem 786: 145-153
  11. Zen J M, Kumar A S & Chen H W (2000). Electrochemical Formation of Prussian Blue in Natural Iron-Intercalated Clay and Cinder Matrixes. Electroanalysis 12(7): 542-545
  12. Zhang Y, Sun X, Zhu L, Shen H & Jia N (2011). Electrochemical sensing based on graphene oxide/Prussian blue hybrid film modified electrode. Electrochim Acta 56: 1239-1245