Dergiler / International Journal of Chemistry and Technology / 2018 / Cilt: 2 - Sayı: 1

Synthesis and characterization of alkyd resin based on soybean oil and glycerin using zirconium octoate as catalyst

Sayfa
34–43
Yayın Tarihi
2018-05-12
DOI
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The prepared resin was formulated in white lacqure and yellowing resistance tested with commercial resins.

📌 3 Maddede Bu Makale

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Amaç & Hipotez:A one pot synthesis of alkyd resins based on the soybean oil and glycerin with the zirconium octoate (zirconium 2-ethyl hexanoate) as a new renewable raw material was performed.
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Temel Bulgular & Veri:The alkyd resin was obtained from polycondensation of the alcoholysis products with phthalic anhydrid at 250 °C.
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Sonuç & Katkı:The prepared resin was formulated in white lacqure and yellowing resistance tested with commercial resins.
🔬Tür:Araştırma Makalesi
📍Kapsam:Genişletilmiş Akademik Örneklem
⚙️Değişkenler:Phthalic anhydride · soybean oil · zirconium ocotate

Abstract

A one pot synthesis of alkyd resins based on the soybean oil and glycerin with the zirconium octoate (zirconium 2-ethyl hexanoate) as a new renewable raw material was performed. The alcoholysis reaction of soybean oil and glycerin carried out in absence of nitrogen gas inlet in the presence of zirconium octoate. The alkyd resin was obtained from polycondensation of the alcoholysis products with phthalic anhydrid at 250 °C. The structure confirmed by FT-IR and H1-NMR spectroscopy. Flexibility, drying time, hardness, adhesion test, impact resistance, gloss test and chemical resistance of synthesized alkyd resins was invesitigated. The prepared resin was formulated in white lacqure and yellowing resistance tested with commercial resins.

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Bu Makaleye Atıf Yap

ELBA, M. E., REHİM, E. M. A., Ashery, R. E. (2018). Synthesis and characterization of alkyd resin based on soybean oil and glycerin using zirconium octoate as catalyst. International Journal of Chemistry and Technology, Cilt: 2 - Sayı: 1, 34–43. https://ajindex.com/articles/765717

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Kaynakça (26)

  1. Gandini, A. Green Chem. 2011, 13 (5), 1061-1083
  2. European Coutings Handbook, Brock., T.; Groteklaes, M.; Mischke, P. 2000, 16-85
  3. Erhan, S.Z.Indnstrial uses of vegetable oil. AOCS publishing, 2005
  4. Tuck, N. Wiley, CV. \sit A ser. Technol. 2000
  5. Gaykar, D.V. Paint India 7. 2001, 55-60
  6. Pramanik, S.; Sagar, K.; Konwar, B.K.; Karak, N. Prog. Org. Coat.2012, 75 (4), 569-578
  7. Turner, G.P.A. Introduction to paint chemistry and principles of paint technology, 3rd ed.; Champman and Hall, London, 1988
  8. Kyenge, B.A.; Anhwange, B.A.; Ageh, J.T.; Igbum, G.O. Int.J. Mod. Org Chem. 2012, 1 (2), 66-71
  9. Solomon, D.H.; Swift, J.D. J. Oil Colour Chem. Assoc. 1966, 49, 915-927
  10. Aydin, S.; Akcay, H.; Evren, O.; Seniha Guner, F.; Tuncer Erciyes, A. Prog. Org. Coats. 2004, 51(4), 273-279
  11. Wholf, R.H. Coconut oil modified alkyd reirns and copolymers There of witl an alkyl acrylate. U.S. Patent 3, 374, 194, Mar. 19, 1968
  12. Wicks, Z.; Jones, F.; Pappas, S.P. Organic Coating Science and Technology. John Wiley & Sons, New York, 1999
  13. Taft Jr, R.W.; Newman, M.S.; Verhoek, F.H.J. Am. Chem. Soc. 1950, 72, 4511-4519
  14. Lazzari, M.; Chiantore, O. Polym. Degrad. Stabil. 1999, 65 (2), 303-313
  15. Köckritz, A.; Martin, A. Eur. J. Lipid Sci. Tecnol. 2008, 110, 812-824
  16. Warwel, S. Rusch gen Klass, M. Lipid Technol. 1997, 9, 10-14
  17. Dobson, G.; Christie, W.W.; Sebedio, J.L. J. Chromatogr. 1996, 723, 349-354
  18. Asemani, H.R.; Ahmadi, P.; Sarabi, A.A.; Eivaz Mohammadloo, H. Prog. Org. Coat. 2016, 94, 18-27
  19. Singha Mahapatra, S.; Karak, N. Prog. Org. Coat. 2004, 51, 103-108
  20. Deligny, P.K.T.; Tuck, N. Alkyds and polyesters. In Resins for Surface Coatings; Oldring, P.K.T., Ed.; John Wiley & Sons, New York, 2000. Vol 2, p. 15
  21. Sharma, B.; Dolui, S.K.; Sharma, A.K. J. Sci. Ind. Res. 2001, 60, 153-158
  22. Privett, O.S. J. Am. Oil Chem. Soc. 1959, 36 (10), 507-512
  23. Porter, N.A.; Wujek, D.G. J. Am. Chem. Soc. 1984, 106 (9), 2626-2629
  24. R usina, A.; Vlcek, A.A. Nature 1965, 206, 295-296
  25. Stenberg, C.; Svensson, M.; Johansson, M. Ind. Crop. Prod.2005, 21 (2), 263-272
  26. Russell, G.A. J.Am. Chem. Soc. 1957, 79 (14), 3871-3877.