Dergiler / Turkish Journal of Chemistry / 2000 / Cilt: 24 - Sayı: 2

High fluorescence emissions of some natural benzofurane derivatives isolated from Styrax officinalis

Sayfa
199–207
Yayın Tarihi
2022-11-05
DOI
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It is concluded that the first excited singlet state of egonol molecule is a more efficient electron acceptor.

📌 3 Maddede Bu Makale

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Amaç & Hipotez:The fluorescent properties of several natural benzofuran derivatives, egonols, isolated from {\it Styrax officinalis}, were determined.
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Temel Bulgular & Veri:The studied egonol derivatives were found to be effective UV organic luminophores, with quantum yields of near to unity, \( jf \) = 0.92.
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Sonuç & Katkı:It is concluded that the first excited singlet state of egonol molecule is a more efficient electron acceptor.
🔬Tür:Araştırma Makalesi
📍Kapsam:Genişletilmiş Akademik Örneklem
⚙️Değişkenler:Fluorescence emission · Styrax officinalis · egonol

Özet

The fluorescent properties of several natural benzofuran derivatives, egonols, isolated from {\it Styrax officinalis}, were determined. The studied egonol derivatives were found to be effective UV organic luminophores, with quantum yields of near to unity, \( jf \) = 0.92. The fluorescence quenching experiments with electron donor molecules of aniline, N,N-dimethylaniline and carbazolocarbazole, presented very high efficiency of quenching at above diffusion quenching rates of 4.5\times10\( 10 \), 2.1\times10\( \times \) and 5.6\times10\( 12 \) s\( -1 \)mol\( -1 \), respectively. A strong electron acceptor molecule, tetranitrofluorenone, presented quenching rate of 2.6\times10\( 11 \) s\( -1 \)mol\( -1 \). It is concluded that the first excited singlet state of egonol molecule is a more efficient electron acceptor.

Abstract

The fluorescent properties of several natural benzofuran derivatives, egonols, isolated from {\it Styrax officinalis}, were determined. The studied egonol derivatives were found to be effective UV organic luminophores, with quantum yields of near to unity, \( jf \) = 0.92. The fluorescence quenching experiments with electron donor molecules of aniline, N,N-dimethylaniline and carbazolocarbazole, presented very high efficiency of quenching at above diffusion quenching rates of 4.5\times10\( 10 \), 2.1\times10\( \times \) and 5.6\times10\( 12 \) s\( -1 \)mol\( -1 \), respectively. A strong electron acceptor molecule, tetranitrofluorenone, presented quenching rate of 2.6\times10\( 11 \) s\( -1 \)mol\( -1 \). It is concluded that the first excited singlet state of egonol molecule is a more efficient electron acceptor.

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Bu Makaleye Atıf Yap

İÇLİ, S., ALP, S., DİNDAR, B., ANIL, H., ÇALIŞKAN, A. Ö., YAYLA, Y., DOROSHENKO, A. O. (2022). High fluorescence emissions of some natural benzofurane derivatives isolated from Styrax officinalis. Turkish Journal of Chemistry, Cilt: 24 - Sayı: 2, 199–207. https://ajindex.com/articles/602434

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