Dergiler / Turkish Journal of Chemistry / 2001 / Cilt: 25 - Sayı: 1

Electrorheological properties of suspensions prepared from polystyrene-block-polyisoprene copolymer

Sayfa
19–32
Yayın Tarihi
2022-11-04
DOI
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Further, the effects of solid particle concentration, shear rate ($dotgamma$), electric field strength, addition of a polar promoter and high temperature on ER activities of colloidal suspensions were investigated, and excess shear stresses were determined.

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Amaç & Hipotez:Considerable scientific and industrial interest is currently being focused on a class of materials known as electrorheological (ER) fluids, which display remarkable rheological behaviour, being able to convert rapidly and repeatedly from a liquid to solid when an electric field (E) is applied or removed.
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Temel Bulgular & Veri:The block copolymer was characterized by GPC, viscosity measurements, 1 H-NMR and FTIR spectroscopies, particle size measurements, and elemental analysis.
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Sonuç & Katkı:Further, the effects of solid particle concentration, shear rate ($dotgamma$), electric field strength, addition of a polar promoter and high temperature on ER activities of colloidal suspensions were investigated, and excess shear stresses were determined.
🔬Tür:Araştırma Makalesi
📍Kapsam:Genişletilmiş Akademik Örneklem
⚙️Değişkenler:Alan Parametreleri

Abstract

Considerable scientific and industrial interest is currently being focused on a class of materials known as electrorheological (ER) fluids, which display remarkable rheological behaviour, being able to convert rapidly and repeatedly from a liquid to solid when an electric field (E) is applied or removed. In this article, the synthesis, characterization, partial hydrolysis and ER properties of polystyrene- block}-polyisoprene copolymer (COP) were investigated. The block copolymer was characterized by GPC, viscosity measurements, 1 H-NMR and FTIR spectroscopies, particle size measurements, and elemental analysis. The polystyrene block of the copolymer was partially hydrolyzed by a series of chemical reactions and then converted to a lithium salt by washing with a lithium hydroxide solution. Colloidal suspensions of this polymeric salt were prepared in silicone oil, at a series of concentrations (5-33% m/m). Colloidal stabilities of these suspensions were determined at 20oC and 80oC. Flow times of suspensions we re measured under no electric field (E = 0) , and under an applied electric field (E $neq$ 0) , and ER activity was observed. Further, the effects of solid particle concentration, shear rate ($dotgamma$), electric field strength, addition of a polar promoter and high temperature on ER activities of colloidal suspensions were investigated, and excess shear stresses were determined.

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Bu Makaleye Atıf Yap

YAVUZ, M., YILDIRIR, Y., ÜNAL, H. İ. (2022). Electrorheological properties of suspensions prepared from polystyrene-block-polyisoprene copolymer. Turkish Journal of Chemistry, Cilt: 25 - Sayı: 1, 19–32. https://ajindex.com/articles/602377

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